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2022 | OriginalPaper | Buchkapitel

2. Graphitic Carbon Nitrides: Synthesis, Properties, and Applications in Perovskite Solar Cells

verfasst von : Fareed Ahmad, Zishan H. Khan, Sundar Singh

Erschienen in: Nanomaterials for Innovative Energy Systems and Devices

Verlag: Springer Nature Singapore

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Abstract

The present chapter is devoted to the synthesis, properties, and applications of graphitic carbon nitrides in perovskite solar cells (PSCs). Graphitic carbon nitride (g-C₃N₄) is an organic semiconducting polymeric material that is analogous in structure to the two-dimensional sp²-hybridized graphene sheets. It is a metal-free polymer with a tunable bandgap of 1.8–2.7 eV. This makes it possible to absorb light in the visible spectrum of 460–698 nm thus converting 13 to 49% of solar energy to useful electrical energy. In PSCs, g-C₃N₄ acts as a photocatalyst embedded in the light-absorbing layer of the solar cell. Hence, g-C₃N₄ helps in improving the efficiency of PSCs by assisting in the charge absorption and generation at the light-absorbing layer. Due to their high photoabsorption and photoresponsiveness, semiconducting properties, high stability under physiological conditions, and good biocompatibility, graphitic carbon nitrides have won tremendous attention among researchers recently. Incorporation of g-C₃N₄ in perovskite absorber layers improves its crystallinity and passivates defects leading to reduced charge carrier recombination which ultimately results in higher power conversion efficiency of PSCs.

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Vorheriges Kapitel Nanomaterials for Perovskite Solar Cells

Nächstes Kapitel Transition Metal Dichalcogenides (TMDs) Nanocomposites-Based Supercapacitors

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Titel: Graphitic Carbon Nitrides: Synthesis, Properties, and Applications in Perovskite Solar Cells
verfasst von: Fareed Ahmad
Zishan H. Khan
Sundar Singh
Verlag: Springer Nature Singapore
Buch: Nanomaterials for Innovative Energy Systems and Devices
Print ISBN: 978-981-19-0552-0

Electronic ISBN: 978-981-19-0553-7

Copyright-Jahr: 2022
DOI: https://doi.org/10.1007/978-981-19-0553-7_2

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