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Erschienen in:
1989 | OriginalPaper | Buchkapitel
Highly Reactive π-Arene Iron Complexes and their use in Stoichiometric and Catalytic Cyclic Addition Reactions
verfasst von : Dongqi Hu, Hans Pritzkow, Hartmut Schäufele, Catherine Tolxdorff, Ulrich Zenneck
Erschienen in: Organometallics in Organic Synthesis 2
Verlag: Springer Berlin Heidelberg
Enthalten in: Professional Book Archive
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Cyclic addition reactions of unsaturated organic molecules in the coordination sphere of transition metals have already been observed for several different systems. Our own approach to this field of chemistry involves the use of highly reactive transition metal complexes, which can be obtained from metal atom ligand cocondensation techniques [1]. This allows one to do the cyclic additions at low temperatures, which should have a considerable impact on the direction and selectivity of the reactions.