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2014 | OriginalPaper | Buchkapitel

1. Hydrogen Bonds and Specific Intermolecular Interactions of Nitrogenated and Bio-organic Compounds and the Methodology of their Investigation

verfasst von : Alexei K. Baev

Erschienen in: Specific Intermolecular Interactions of Nitrogenated and Bioorganic Compounds

Verlag: Springer Berlin Heidelberg

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Abstract

The hydrogen bond is caused by an additional interaction between a covalently bonded hydrogen atom and a more electronegative atom of the same group or any other molecule. Thus, the purely covalent bond leads to a situation of equal sharing of electrons by the interacting hydrogen atoms in an Н2 molecule; only in this case the degree of socialization is 50 % [1]. Preferential shifting of the electron density to the atom of the element interacting with the hydrogen atom, i.e. polarization, provides the molecule with an ionic component. Acting in the covalent bond, the electric forces of the nuclear electron interaction and the magnetic forces, together with electrostatic forces of atoms attractingwith opposite charges, correlate with interatomic distances of atoms in the molecule (in the X–H bond distance), and this is observed in the fundamental X–H stretching vibration frequencies [2]. A practically similar definition of the hydrogen bond is given in Pauling’s monograph titled “The Nature of the Chemical Bond” [3].

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Nächstes Kapitel Specific Intermolecular Interactions of Cyclic Alkylamines and Nitriles
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Metadaten
Titel
Hydrogen Bonds and Specific Intermolecular Interactions of Nitrogenated and Bio-organic Compounds and the Methodology of their Investigation
verfasst von
Alexei K. Baev
Copyright-Jahr
2014
Verlag
Springer Berlin Heidelberg
Buch
Specific Intermolecular Interactions of Nitrogenated and Bioorganic Compounds

Print ISBN: 978-3-642-37471-5

Electronic ISBN: 978-3-642-37472-2

Copyright-Jahr: 2014

DOI
https://doi.org/10.1007/978-3-642-37472-2_1