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2017 | OriginalPaper | Buchkapitel

24. Hydrogen Production

verfasst von : M. Andrew Crews, B. Gregory Shumake

Erschienen in: Springer Handbook of Petroleum Technology

Verlag: Springer International Publishing

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Abstract

Many petroleum refining processes require hydrogen. Some is generated as a by-product from other units, such as catalytic reformers, but additional on-purpose production is required to meet increasing demands to process heavier feeds and meet tighter fuel and lubricant base oil specifications. In this chapter, we describe technology for on-purpose H2 production, which is accomplished by four different processes – steam methane reforming (SMR), SMR with oxygen enrichment (SMR/O2R), autothermal reforming (ATR), and thermal partial oxidation (POX). Designs can be adjusted to produce hydrogen, pure carbon monoxide, or mixtures of H2 and CO (synthesis gas). All aspects of SMR, SMR/O2R, and ATR are described: chemistry and thermodynamics, process design parameters and options, hydrogen purification, environmental protection, operation, process monitoring, processes improvements, safety, and economics.

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Literatur
[1]
Zurück zum Zitat Tindall, B.M.; King, D.L.: Design steam reformers for hydrogen production, Hydrocarbon Process. 73(7), 69–75 (1994) Tindall, B.M.; King, D.L.: Design steam reformers for hydrogen production, Hydrocarbon Process. 73(7), 69–75 (1994)
[2]
Zurück zum Zitat Tindall, B.M.; Crews, M.A.: Alternative technologies to steam-methane reforming, Hydrocarbon Process. 74(11), 75–84 (1995) Tindall, B.M.; Crews, M.A.: Alternative technologies to steam-methane reforming, Hydrocarbon Process. 74(11), 75–84 (1995)
[3]
Zurück zum Zitat King, D.L.; Bochow, C.E.: What should and owner/operator know when choosing an SMR/PSA plant, Hydrocarbon Process. 79(5), 39–48 (2000) King, D.L.; Bochow, C.E.: What should and owner/operator know when choosing an SMR/PSA plant, Hydrocarbon Process. 79(5), 39–48 (2000)
[4]
Zurück zum Zitat Hoitsma, K.; Snelgrove, P.: Effective reformer design and erection, World Refining 0, 24–28 (2002) Hoitsma, K.; Snelgrove, P.: Effective reformer design and erection, World Refining 0, 24–28 (2002)
[5]
Zurück zum Zitat Tindall, B.M.; Crews, M.A.: Economics of export steam for hydrogen plants, Hydrocarbon Engineering 8(2), 39–41 (2003) Tindall, B.M.; Crews, M.A.: Economics of export steam for hydrogen plants, Hydrocarbon Engineering 8(2), 39–41 (2003)
[6]
Zurück zum Zitat Boyce, C.; Ritter, R.; Crews, M.A.: Is it time for a new hydrogen plant, Hydrocarbon Engineering 9(2), 68–70 (2004) Boyce, C.; Ritter, R.; Crews, M.A.: Is it time for a new hydrogen plant, Hydrocarbon Engineering 9(2), 68–70 (2004)
[7]
Zurück zum Zitat Ernst, W.S.; Venables, S.; Christensen, P.S.; Berthelsen, A.C.: Push syngas production limits, Hydrocarbon Process. 79(3), 100-C (2000) Ernst, W.S.; Venables, S.; Christensen, P.S.; Berthelsen, A.C.: Push syngas production limits, Hydrocarbon Process. 79(3), 100-C (2000)
[8]
Zurück zum Zitat de Wet, H.; Shaw, G.; Hohmann, F.: Commissioning of world’s largest oxygen blown secondary reformers. In: Ammonia Plant Safety & Related Facilities, Vol. 35 (American Institute of Chemical Engineers, New York 1995) pp. 315–335 de Wet, H.; Shaw, G.; Hohmann, F.: Commissioning of world’s largest oxygen blown secondary reformers. In: Ammonia Plant Safety & Related Facilities, Vol. 35 (American Institute of Chemical Engineers, New York 1995) pp. 315–335
[9]
Zurück zum Zitat Haldor Topsoe A/S: Autothermal Reforming (1995) 10-1–10-11 Haldor Topsoe A/S: Autothermal Reforming (1995) 10-1–10-11
[10]
Zurück zum Zitat Christensen, T.S.; Primdahl, I.L.: Improve syngas production using autothermal reforming, Hydrocarbon Process. 73(3), 39–46 (1994) Christensen, T.S.; Primdahl, I.L.: Improve syngas production using autothermal reforming, Hydrocarbon Process. 73(3), 39–46 (1994)
[11]
Zurück zum Zitat A. Lowson, I. Primdahl, D. Smith, S.-I. Wang: Carbon Monoxide Production by Oxygen Reforming, Air Products and Chemicals, Inc., 2-21 1475H (1990) A. Lowson, I. Primdahl, D. Smith, S.-I. Wang: Carbon Monoxide Production by Oxygen Reforming, Air Products and Chemicals, Inc., 2-21 1475H (1990)
[14]
Zurück zum Zitat Liebner, W.; Hauser, N.: The Shell Oil Gasification Process (SGP) and its Application for Production of Clean Power (Lurgi and Shell, PLACE 1990) Liebner, W.; Hauser, N.: The Shell Oil Gasification Process (SGP) and its Application for Production of Clean Power (Lurgi and Shell, PLACE 1990)
[15]
Zurück zum Zitat Texaco Development Corporation: Texaco Gasification Process for Gaseous or Liquid Feedstocks (Texaco Image Services, Tulsa 1993) Texaco Development Corporation: Texaco Gasification Process for Gaseous or Liquid Feedstocks (Texaco Image Services, Tulsa 1993)
[16]
Zurück zum Zitat Heaven, D.L.: Gasification converts a variety of problem feedstocks and wastes, Oil Gas J. 0, 49–54 (1996) Heaven, D.L.: Gasification converts a variety of problem feedstocks and wastes, Oil Gas J. 0, 49–54 (1996)
[17]
Zurück zum Zitat Fong, W.F.; O’Keefe, L.F.: Syngas generation from natural gas utilizing the Texaco gasification process, Proc. 1996 NPRA Annual Meeting (1996) paper AM-96-68 Fong, W.F.; O’Keefe, L.F.: Syngas generation from natural gas utilizing the Texaco gasification process, Proc. 1996 NPRA Annual Meeting (1996) paper AM-96-68
[18]
Zurück zum Zitat Stellaccio, R.J.: Partial oxidation process for slurries of solid fuel, U.S. Patent Ser., Vol. 4443230 (1984) Stellaccio, R.J.: Partial oxidation process for slurries of solid fuel, U.S. Patent Ser., Vol. 4443230 (1984)
[19]
Zurück zum Zitat Hauser, N.; Higman, C.: The use of the Shell gasification process (SGP) in refining heavy crude and tar sands, Proc. 6th UNITAR Int’l. Conference on Heavy Crude & Tar Sands, Houston (1995) Hauser, N.; Higman, C.: The use of the Shell gasification process (SGP) in refining heavy crude and tar sands, Proc. 6th UNITAR Int’l. Conference on Heavy Crude & Tar Sands, Houston (1995)
[20]
Zurück zum Zitat Lurgi Corporation: Integrated Gasification Combined Cycle Process (IGCC) (1995) Lurgi Corporation: Integrated Gasification Combined Cycle Process (IGCC) (1995)
[22]
Zurück zum Zitat Reed, C.L.; Kuhre, C.J.: Make syn gas by partial oxidation, Hydrocarbon Process. 58(9), 191–194 (1979) Reed, C.L.; Kuhre, C.J.: Make syn gas by partial oxidation, Hydrocarbon Process. 58(9), 191–194 (1979)
[23]
Zurück zum Zitat P.E.J. Abbott: Advanced Steam Reforming Technology in GTL Flowsheets, Synetix (ICI) (1999) P.E.J. Abbott: Advanced Steam Reforming Technology in GTL Flowsheets, Synetix (ICI) (1999)
[24]
Zurück zum Zitat T. Hicks: A Decade of Gas Heated Reforming, FINDS, Vol. XI, Number 3 (1996) T. Hicks: A Decade of Gas Heated Reforming, FINDS, Vol. XI, Number 3 (1996)
[25]
Zurück zum Zitat Abbishaw, J.B.; Cromarty, B.J.: The use of advanced steam reforming technology for hydrogen production, Proc. 1996 NPRA Annual Meeting (1996) paper AM-96-62 Abbishaw, J.B.; Cromarty, B.J.: The use of advanced steam reforming technology for hydrogen production, Proc. 1996 NPRA Annual Meeting (1996) paper AM-96-62
[26]
Zurück zum Zitat Farnell, P.W.: Commissioning and operation of ICI Katalco’s leading concept methanol process, Proc. AIChE Ammonia Safety Symposium (1995) Farnell, P.W.: Commissioning and operation of ICI Katalco’s leading concept methanol process, Proc. AIChE Ammonia Safety Symposium (1995)
[27]
Zurück zum Zitat Farnell, P.W.: Commissioning/operation of leading concept methanol process. In: Ammonia Plant Safety & Related Facilities, Vol. 36 (AIChE, New York 1996) pp. 268–277 Farnell, P.W.: Commissioning/operation of leading concept methanol process. In: Ammonia Plant Safety & Related Facilities, Vol. 36 (AIChE, New York 1996) pp. 268–277
[28]
Zurück zum Zitat E. Goudappel, A.H. Herfkens, T. Beishuizen: Gas Turbines for crude oil heating and cogeneration, PTQ 2000 Q2, pp. 99–109 E. Goudappel, A.H. Herfkens, T. Beishuizen: Gas Turbines for crude oil heating and cogeneration, PTQ 2000 Q2, pp. 99–109
[29]
Zurück zum Zitat Shahani, G.; Garodz, L.; Baade, B.; Murphy, K.; Sharma, P.: Hydrogen and utility supply optimization, Hydrocarbon Process. 77(9), 143–150 (1998) Shahani, G.; Garodz, L.; Baade, B.; Murphy, K.; Sharma, P.: Hydrogen and utility supply optimization, Hydrocarbon Process. 77(9), 143–150 (1998)
[30]
Zurück zum Zitat Hairston, D.: Hail hydrogen, Chemical Engineering 103(2), 59–62 (1996) Hairston, D.: Hail hydrogen, Chemical Engineering 103(2), 59–62 (1996)
[31]
Zurück zum Zitat Farnell, P.W.: Investigation and resolution of a secondary reformer burner failure, Proc. 45th Annual Safety In Ammonia Plants and Related Facilities Symposium (2000) Paper no. 1D Farnell, P.W.: Investigation and resolution of a secondary reformer burner failure, Proc. 45th Annual Safety In Ammonia Plants and Related Facilities Symposium (2000) Paper no. 1D
[32]
Zurück zum Zitat Shahani, G.H.; Gunardson, H.H.; Easterbrook, N.C.: Consider oxygen for hydrocarbon oxidations, Chem. Eng. Prog. 92(11), 66–71 (1996) Shahani, G.H.; Gunardson, H.H.; Easterbrook, N.C.: Consider oxygen for hydrocarbon oxidations, Chem. Eng. Prog. 92(11), 66–71 (1996)
[33]
Zurück zum Zitat Jung, C.S.; Noh, K.K.; Yi, S.; Kim, J.S.; Song, H.K.; Hyun, J.C.: MPC improves reformer control, Hydrocarbon Process. 74(4), 115–122 (1995) Jung, C.S.; Noh, K.K.; Yi, S.; Kim, J.S.; Song, H.K.; Hyun, J.C.: MPC improves reformer control, Hydrocarbon Process. 74(4), 115–122 (1995)
[34]
Zurück zum Zitat Baade, W.F.; Patel, N.; Jordan, R.; Sekhri, S.: Integrated hydrogen supply-extend your refinery’s enterprise, Proc. NPRA 2001 Annual Meeting (2001) paper AM-01-19 Baade, W.F.; Patel, N.; Jordan, R.; Sekhri, S.: Integrated hydrogen supply-extend your refinery’s enterprise, Proc. NPRA 2001 Annual Meeting (2001) paper AM-01-19
[35]
Zurück zum Zitat Grant, M.D.; Udengaard, N.R.; Vannby, R.; Cavote, C.P.: New advanced hydrogen plant in California refinery by the Topsoe process, Proc. NPRA 2001 Annual Meeting (2001) paper AM-01-27 Grant, M.D.; Udengaard, N.R.; Vannby, R.; Cavote, C.P.: New advanced hydrogen plant in California refinery by the Topsoe process, Proc. NPRA 2001 Annual Meeting (2001) paper AM-01-27
[36]
Zurück zum Zitat Howard, Weil, Labouisse, Friedrichs Inc., Fischer-Tropsch Technology: GAS-TO-LIQUIDS, SOLIDS-TO-LIQUIDS, LIQUIDS-TO-LIQUIDS (1998) Howard, Weil, Labouisse, Friedrichs Inc., Fischer-Tropsch Technology: GAS-TO-LIQUIDS, SOLIDS-TO-LIQUIDS, LIQUIDS-TO-LIQUIDS (1998)
[37]
Zurück zum Zitat D. Sanfilippo, E. Micheli, I. Miracca; L. Tagliabue: Oxygenated Synfuels from Natural Gas, PTQ 1998 Q2, pp. 87–95 D. Sanfilippo, E. Micheli, I. Miracca; L. Tagliabue: Oxygenated Synfuels from Natural Gas, PTQ 1998 Q2, pp. 87–95
[38]
Zurück zum Zitat Barba, J.J.; Hemmings, J.; Bailey, T.C.; Horne, N.: Advances in hydrogen production technology: The options available, Hydrocarbon Eng. 3(1), 48–54 (1997/98) Barba, J.J.; Hemmings, J.; Bailey, T.C.; Horne, N.: Advances in hydrogen production technology: The options available, Hydrocarbon Eng. 3(1), 48–54 (1997/98)
[39]
Zurück zum Zitat Dybkjaer, I.; Madsen, S.W.: Advanced reforming technologies for hydrogen production, Hydrocarbon Eng. 3(1), 56–65 (1997/98) Dybkjaer, I.; Madsen, S.W.: Advanced reforming technologies for hydrogen production, Hydrocarbon Eng. 3(1), 56–65 (1997/98)
[40]
Zurück zum Zitat DaPrato, P.L.; Gunardson, H.H.: Selection of optimum technology for CO rich syngas, Hydrocarbon Eng. 0, 34–40 (1996) DaPrato, P.L.; Gunardson, H.H.: Selection of optimum technology for CO rich syngas, Hydrocarbon Eng. 0, 34–40 (1996)
[41]
Zurück zum Zitat Hutchings, G.J.; Ross, J.R.H.; Kunchal, S.K.: TITLE, Methane Conversion 0, 1–81 (1994-97) Hutchings, G.J.; Ross, J.R.H.; Kunchal, S.K.: TITLE, Methane Conversion 0, 1–81 (1994-97)
[42]
Zurück zum Zitat ICI Group: ICI Catalysts for Steam Reforming Naphtha, ICI Group 72W/033/1/CAT46, pp. 1–19, 46. Series ICI Group: ICI Catalysts for Steam Reforming Naphtha, ICI Group 72W/033/1/CAT46, pp. 1–19, 46. Series
[43]
Zurück zum Zitat F.C. Brown: Alternative Uses for Methanol Plants, PTQ 2000 Q2, pp. 83–91 F.C. Brown: Alternative Uses for Methanol Plants, PTQ 2000 Q2, pp. 83–91
[44]
Zurück zum Zitat T. Mii, K. Hirotani: Economics of a World Class Methanol Plant, PTQ 2000 Q2, pp. 127–133 T. Mii, K. Hirotani: Economics of a World Class Methanol Plant, PTQ 2000 Q2, pp. 127–133
[45]
Zurück zum Zitat Carstensen, J.: Reduce methanol formation in your hydrogen plant, Hydrocarbon Process. 77(3), 100-C–100-D (1998) Carstensen, J.: Reduce methanol formation in your hydrogen plant, Hydrocarbon Process. 77(3), 100-C–100-D (1998)
[46]
Zurück zum Zitat LeBlanc, J.R.; Schneider III, R.V.; Strait, R.B.: Production of Methanol (Marcel Dekker, New York 1994) pp. 51–132 LeBlanc, J.R.; Schneider III, R.V.; Strait, R.B.: Production of Methanol (Marcel Dekker, New York 1994) pp. 51–132
[47]
Zurück zum Zitat Parks, S.B.; Schillmoller, C.M.: Improve alloy selection for ammonia furnaces, Hydrocarbon Process. 76(10), 93–98 (1997) Parks, S.B.; Schillmoller, C.M.: Improve alloy selection for ammonia furnaces, Hydrocarbon Process. 76(10), 93–98 (1997)
[48]
Zurück zum Zitat Cromarty, B.: Effective steam reforming of mixed and heavy hydrocarbon feedstocks for production of hydrogen, Proc. NPRA 1995 Annual Meeting (1995) Cromarty, B.: Effective steam reforming of mixed and heavy hydrocarbon feedstocks for production of hydrogen, Proc. NPRA 1995 Annual Meeting (1995)
[49]
Zurück zum Zitat Martin, R.P.: Nitrogen oxide formation and reduction in steam reformers, Proc. International Fertilizer Industry Association Conf. (1994) Martin, R.P.: Nitrogen oxide formation and reduction in steam reformers, Proc. International Fertilizer Industry Association Conf. (1994)
[51]
Zurück zum Zitat Garg, A.: Reducing NOx from fired heaters and boilers, Proc. Chemical Engineering Expo (2000) paper ESL-IE-00-04-46 Garg, A.: Reducing NOx from fired heaters and boilers, Proc. Chemical Engineering Expo (2000) paper ESL-IE-00-04-46
[52]
Zurück zum Zitat Kunz, R.G.; Smith, D.D.; Patel, N.M.; Thompson, G.P.; Patrick, G.S.; Air Products and Chemicals, Inc.: Control NOx from gas-fired hydrogen reformer furnaces, *+*PROCBEGIN*+*Proc. NPRA Annual Meeting*+*PROCEND*+* (1992) AM-92-56 Kunz, R.G.; Smith, D.D.; Patel, N.M.; Thompson, G.P.; Patrick, G.S.; Air Products and Chemicals, Inc.: Control NOx from gas-fired hydrogen reformer furnaces, *+*PROCBEGIN*+*Proc. NPRA Annual Meeting*+*PROCEND*+* (1992) AM-92-56
[54]
Zurück zum Zitat Harrell, G.: Boiler blowdown energy recovery, Energy Engineering 101(5), 32–42 (2005) Harrell, G.: Boiler blowdown energy recovery, Energy Engineering 101(5), 32–42 (2005)
Metadaten
Titel
Hydrogen Production
verfasst von
M. Andrew Crews
B. Gregory Shumake
Copyright-Jahr
2017
Verlag
Springer International Publishing
DOI
https://doi.org/10.1007/978-3-319-49347-3_24