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Topics in Catalysis

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25.01.2020 | Original Paper

Hydrogen Release from Decalin by Catalytic Dehydrogenation over Supported Platinum Catalysts

verfasst von: E. A. Martynenko, Al. A. Pimerzin, A. A. Savinov, S. P. Verevkin, A. A. Pimerzin

Erschienen in: Topics in Catalysis | Ausgabe 1-2/2020

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Abstract

Pt catalysts supported on the commonly used supports Al₂O₃, SiO₂ and on mesostructured silicates SBA-15 and MCM-48 were examined in the dehydrogenation of decalin, that is the promising liquid organic hydrogen carrier (LOHC). Synthesized catalysts were studied by low-temperature nitrogen adsorption, temperature programmed reduction, high-resolution transmission electron microscopy. The catalysts are characterized by various dispersion of platinum. The activity of catalysts in decalin dehydrogenation decreases in the following order Pt/MCM-48 > Pt/SBA-15 > Pt/SiO₂ > Pt/Al₂O₃. Pt/MCM-48 catalyst allows to release hydrogen in the decalin amount of 5.7 wt% and can be considered the promising LOHC hydrogen storage technology.

Graphic Abstract

Vorheriger Artikel Detailed Mechanism of Ethanol Transformation into Syngas on Catalysts Based on Mesoporous MgAl2O4 Support Loaded with Ru + Ni/(PrCeZrO or MnCr2O4) Active Components

Nächster Artikel Monoterpenoid Oximes Hydrogenation Over Platinum Catalysts

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Titel: Hydrogen Release from Decalin by Catalytic Dehydrogenation over Supported Platinum Catalysts
verfasst von: E. A. Martynenko
Al. A. Pimerzin
A. A. Savinov
S. P. Verevkin
A. A. Pimerzin
Publikationsdatum: 25.01.2020
Verlag: Springer US
Erschienen in: Topics in Catalysis / Ausgabe 1-2/2020
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-020-01228-9

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