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2019 | OriginalPaper | Buchkapitel

Hydrogen via Direct Solar Production

verfasst von : Shamindri M. Arachchige, Karen J. Brewer

Erschienen in: Fuel Cells and Hydrogen Production

Verlag: Springer New York

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A ligand that is located between two metals in a supramolecule, bridging ligand.

bpy

A bidentate terminal ligand, 2,2′-bipyridine.

CAT

The site of a reaction that occurs via catalysis, facilitated by the catalyst without the destruction of this subunit occurring multiple times in a cycle.

dmgBF₂

(Difluoroboryl) dimethylglyoximate.

dmgH

Dimethylglyoximate.

dpb

A bidentate bridging ligand, 2,3-bis(2-pyridyl) benzoquinoxaline.

dpgBF₂

(Difluoroboryl)diphenylglyoximate.

dpp

A bidentate bridging ligand, 2,3-bis(2-pyridyl) pyrazine.

dpq

A bidentate bridging ligand, 2,3-bis(2-pyridyl) quinoxaline.

A subunit that functions to accept an electron in a redox reaction, electron acceptor.

A subunit that functions to donate an electron in a redox reaction, electron donor.

Excited state electron transfer, oxidation or reduction reaction involving the loss or gain of an electron that occurs in an electronic excited state.

Electronic ground state of a molecule.

HOMO

Highest occupied molecular orbital for a molecule.

I_a

Intensity of incident light.

Internal conversion, a non-radiative process that allows conversion between two electronic states of the same spin multiplicity.

isc

Intersystem crossing, a non-radiative process that allows conversion between two electronic states of different spin multiplicity.

k _x

Rate constant of process “x.”

Ground electronic state of a light absorber.

^∗LA

Excited electronic state of a light absorber.

L-pyr

A monodentate terminal ligand, [(4-pyridine) oxazolo(4,5-f)phenanthroline].

LUMO

Lowest unoccupied molecular orbital for a molecule.

Me₂bpy

A bidentate terminal ligand, 4,4′-dimethy-2,2′-bipyridine.

Me₂phen

A bidentate terminal ligand, 4,7-dimethylphenanthroline.

MLCT

Metal-to-ligand charge-transfer, an electronic excited state.

MMCT

Metal-to-metal charge-transfer, an electronic excited state.

Non-radiative decay or movement between electronic states via processes that do not involve the absorption or emission of light.

phen

A bidentate terminal ligand, 1,10-phenanthroline.

ppy

A monodentate terminal ligand, 2-phenylpyridine.

A N containing aromatic ring, pyridyl.

Bimolecular deactivation, a reaction of an electronic excited state of a molecule which results in relaxation to the ground state via interaction with another molecule without transfer of electrons or generation of an excited state.

Quencher, a molecule that is engaged in a reaction with an electronic excited state of another molecule leading to generation of the ground state of the excited molecule.

rxn

Photochemical reaction from the electronic excited state of a molecule.

A ligand that is located at the end of a supramolecule and bound to only one metal center, terminal ligand.

tpy

A tridentate terminal ligand, 2,2′:6′,2′′-terpyridine.

λ_max^abs

Absorption maximum.

λ_max^em

Emission maximum.

Quantum yield or a process provides the number of events of interest that occur from an electronic excited state as related to the number of excited molecules.

Φ^em

Quantum yield of emission providing the number of photons emitted by an electronic excited state of a molecule divided by the number of photons absorbed.

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Vorheriges Kapitel Hydrogen Production from Photoelectrochemical Water Splitting

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Titel: Hydrogen via Direct Solar Production
verfasst von: Shamindri M. Arachchige
Karen J. Brewer
Verlag: Springer New York
Buch: Fuel Cells and Hydrogen Production
Print ISBN: 978-1-4939-7788-8

Electronic ISBN: 978-1-4939-7789-5

Copyright-Jahr: 2019
DOI: https://doi.org/10.1007/978-1-4939-7789-5_515