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Journal of Materials Science
Erschienen in: Journal of Materials Science 13/2018

06.04.2018 | Electronic materials

Improved cycle performance of nitrogen and phosphorus co-doped carbon coatings on lithium nickel cobalt aluminum oxide battery material

verfasst von: Peng Gao, Yunpeng Jiang, Yongming Zhu, Huili Hu

Erschienen in: Journal of Materials Science | Ausgabe 13/2018

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Abstract

Nitrogen–phosphorus co-doped nanoscale carbon coating (N/P–C) was constructed on the surface of LiNi0.8Co0.15Al0.05O2 (NCA). The coated material showed a shell–core structure, the core layer was NCA, the shell layer was N/P–C, and the coating was evenly distributed on the surface of the material. The coating improves electron transport path in the structure of NCA, increases conductivity, protects the electrode material, suppresses dissolution of the metal ions and improves stability. In this experiment, aniline (ani) was used as the carbon source and the nitrogen source, and phytic acid was used as the carbon source and the phosphorus source. They were mixed at a mass ratio of m (NCA)/m (C) = 100:0.5, 100:1.0 and 100:2.0, respectively, and then annealed to form a uniform coating. By comparison, it can be concluded that the coating has the best electrochemical performance when the coating mass fraction is 1.0%. At the current density of 1 C, the capacity retention rate was 90.7% after 200 cycles, higher than uncoated material (70%).
Vorheriger Artikel Synthesis and characterization of novel ferrite–piezoelectric multiferroic core–shell-type structure
Nächster Artikel Study of the alkali metal poisoning resistance of a Co-modified Mn/Ni foam catalyst in low-temperature flue gas SCR DeNO x

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Metadaten
Titel
Improved cycle performance of nitrogen and phosphorus co-doped carbon coatings on lithium nickel cobalt aluminum oxide battery material
verfasst von
Peng Gao
Yunpeng Jiang
Yongming Zhu
Huili Hu
Publikationsdatum
06.04.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 13/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2275-7

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