Skip to main content
Erschienen in: Journal of Materials Science 12/2019

18.03.2019 | Polymers

Intrinsic self-healing and biocompatibility of carbon nitride coatings via inhibiting or degrading ethylene for fruit preservation

verfasst von: Hongyun Xuan, Yanxi Zhu, Jiaoyu Ren, Liqin Ge

Erschienen in: Journal of Materials Science | Ausgabe 12/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Intrinsic self-healing of C3N4 coatings based on host–guest interaction was achieved on fruit substrates via layer-by-layer assembly technique. The coatings were made of alternating layers of poly(ethylenimine)-β-cyclodextrin (PEI-βCD), poly(acrylic acid)-adamantanamine (PAA-AD), and carbon nitride (C3N4). The ultrasonic treatment was used to inhibit C3N4 agglomeration and to form a homogeneous suspension of PEI-βCD-C3N4. Then, PAA-AD and PEI-βCD-C3N4 were self-assembled to obtain the (PAA-AD/PEI-βCD-C3N4)*15 coatings. The photoactivity of the coatings was monitored using photodegradation of methylene blue dye under visible light. We hypothesized that the coatings could be applied to banana fresh-keeping packaging materials by inhibiting or degrading ethylene. The results verified that the coatings possessed excellent degradablility and fresh-keeping performances. Moreover, cell viability tests showed that the coatings exhibited good biocompatibility. In particular, the coatings exhibited excellent self-healing property due to the reversible nature of the host–guest interaction. The coatings show great potential for applications in multifunctional commercial supplies, such as packaging materials.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Zurück zum Zitat Diab T, Biliaderis CG, Gerasopoulos D (2001) Physicochemical properties and application of pullulan edible films and coatings in fruit preservation. J Sci Food Agric 81:988–1000CrossRef Diab T, Biliaderis CG, Gerasopoulos D (2001) Physicochemical properties and application of pullulan edible films and coatings in fruit preservation. J Sci Food Agric 81:988–1000CrossRef
2.
Zurück zum Zitat Santagata G, Mallardo S, Fasulo G, Lavermicocca P, Valerio F, Biase MD, Stasio MD, Malinconico M, Volpe G (2018) Pectin-honey coating as novel dehydrating bioactive agent for cut fruit: enhancement of the functional properties of coated dried fruits. Food Chem 258:104–110CrossRef Santagata G, Mallardo S, Fasulo G, Lavermicocca P, Valerio F, Biase MD, Stasio MD, Malinconico M, Volpe G (2018) Pectin-honey coating as novel dehydrating bioactive agent for cut fruit: enhancement of the functional properties of coated dried fruits. Food Chem 258:104–110CrossRef
3.
Zurück zum Zitat Mohammed FA, Balaji K, Girilal M (2009) Mycobased synthesis of silver nanoparticles and their incorporation into sodium alginate films for vegetable and fruit preservation. J Agric Food Chem 57:6246–6252CrossRef Mohammed FA, Balaji K, Girilal M (2009) Mycobased synthesis of silver nanoparticles and their incorporation into sodium alginate films for vegetable and fruit preservation. J Agric Food Chem 57:6246–6252CrossRef
4.
Zurück zum Zitat Yue TT, Li X, Wang XX, Yan X, Yu M, Ma JW, Zhou Y, Ramakrishna S, Long YZ (2018) Electrospinning of carboxymethyl chitosan/polyoxyethylene oxide nanofibers for fruit fresh-keeping. Nanoscale Res Lett 13:239CrossRef Yue TT, Li X, Wang XX, Yan X, Yu M, Ma JW, Zhou Y, Ramakrishna S, Long YZ (2018) Electrospinning of carboxymethyl chitosan/polyoxyethylene oxide nanofibers for fruit fresh-keeping. Nanoscale Res Lett 13:239CrossRef
5.
Zurück zum Zitat Blaiszik BJ, Kramer SLB, Olugebefola SC, Moore JS, Sottos NR, White SR (2010) Self-healing polymers and composites. Annu Rev Mater Res 40:179–211CrossRef Blaiszik BJ, Kramer SLB, Olugebefola SC, Moore JS, Sottos NR, White SR (2010) Self-healing polymers and composites. Annu Rev Mater Res 40:179–211CrossRef
6.
Zurück zum Zitat Gu Y, Zacharia NS (2015) Self-healing actuating adhesive based on polyelectrolyte multilayers. Adv Funct Mater 25:3785–3792CrossRef Gu Y, Zacharia NS (2015) Self-healing actuating adhesive based on polyelectrolyte multilayers. Adv Funct Mater 25:3785–3792CrossRef
7.
Zurück zum Zitat Cong HP, Wang P, Yu SH (2013) Stretchable and self-healing graphene oxide-polymer composite hydrogels: a dual-network design. Chem Mater 25:3357–3362CrossRef Cong HP, Wang P, Yu SH (2013) Stretchable and self-healing graphene oxide-polymer composite hydrogels: a dual-network design. Chem Mater 25:3357–3362CrossRef
8.
Zurück zum Zitat Tee BCK, Wang C, Allen R, Bao Z (2012) An electrically and mechanically self-healing composite with pressure and flexion-sensitive properties for electronic skin applications. Nat Nanotechnol 7:825–832CrossRef Tee BCK, Wang C, Allen R, Bao Z (2012) An electrically and mechanically self-healing composite with pressure and flexion-sensitive properties for electronic skin applications. Nat Nanotechnol 7:825–832CrossRef
9.
Zurück zum Zitat Bode S, Zedler L, Schacher FH, Dietzek B, Schmitt M, Popp J, Hager MD, Schubert US (2013) Self-healing polymer coatings based on crosslinked metallosupramolecular copolymers. Adv Mater 25:1634–1638CrossRef Bode S, Zedler L, Schacher FH, Dietzek B, Schmitt M, Popp J, Hager MD, Schubert US (2013) Self-healing polymer coatings based on crosslinked metallosupramolecular copolymers. Adv Mater 25:1634–1638CrossRef
10.
Zurück zum Zitat Cromwell OR, Chung J, Guan Z (2015) Malleable self-healing covalent polymer networks through tunable dynamic boronic ester bonds. J Am Chem Soc 137:6492–6495CrossRef Cromwell OR, Chung J, Guan Z (2015) Malleable self-healing covalent polymer networks through tunable dynamic boronic ester bonds. J Am Chem Soc 137:6492–6495CrossRef
11.
Zurück zum Zitat Kuhl N, Bode S, Bose RK, Vitz J, Seifert A, Hoeppener S, Garcia SJ, Spange S, van der Zwaag S, Hager MD, Schubert US (2015) Acylhydrazones as reversible covalent crosslinkers for self-healing polymers. Adv Funct Mater 25:3295–3301CrossRef Kuhl N, Bode S, Bose RK, Vitz J, Seifert A, Hoeppener S, Garcia SJ, Spange S, van der Zwaag S, Hager MD, Schubert US (2015) Acylhydrazones as reversible covalent crosslinkers for self-healing polymers. Adv Funct Mater 25:3295–3301CrossRef
12.
Zurück zum Zitat Oehlenschlaeger KK, Mueller JO, Brandt J, Hilf S, Lederer A, Wilhelm M, Graf R, Coote ML, Schmidt FG, Barner-Kowollik C (2014) Adaptable hetero diels-alder networks for fast self-healing under mild conditions. Adv Mater 26:3561–3566CrossRef Oehlenschlaeger KK, Mueller JO, Brandt J, Hilf S, Lederer A, Wilhelm M, Graf R, Coote ML, Schmidt FG, Barner-Kowollik C (2014) Adaptable hetero diels-alder networks for fast self-healing under mild conditions. Adv Mater 26:3561–3566CrossRef
13.
Zurück zum Zitat Chen H, Ma X, Wu S, Tian H (2014) A Rapidly Self-healing supramolecular polymer hydrogel with photostimulated room-temperature phosphorescence responsiveness. Angew Chem Int Ed 53:14149–14152CrossRef Chen H, Ma X, Wu S, Tian H (2014) A Rapidly Self-healing supramolecular polymer hydrogel with photostimulated room-temperature phosphorescence responsiveness. Angew Chem Int Ed 53:14149–14152CrossRef
14.
Zurück zum Zitat Nakahata M, Takashima Y, Yamaguchi H, Harada A (2011) Redox-responsive self-healing materials formed from host–guest polymers. Nat Commun 2:511–516CrossRef Nakahata M, Takashima Y, Yamaguchi H, Harada A (2011) Redox-responsive self-healing materials formed from host–guest polymers. Nat Commun 2:511–516CrossRef
15.
Zurück zum Zitat Kang HS, Kim HT, Park JK, Lee S (2014) Light-powered healing of a wearable electrical conductor. Adv Funct Mater 24:7273–7283CrossRef Kang HS, Kim HT, Park JK, Lee S (2014) Light-powered healing of a wearable electrical conductor. Adv Funct Mater 24:7273–7283CrossRef
16.
Zurück zum Zitat Li Y, Li L, Sun J (2010) Bioinspired self-healing superhydrophobic coatings. Angew Chem Int Ed 49:6129–6133CrossRef Li Y, Li L, Sun J (2010) Bioinspired self-healing superhydrophobic coatings. Angew Chem Int Ed 49:6129–6133CrossRef
17.
Zurück zum Zitat Li GL, Zheng Z, Möhwald H, Shchukin DG (2013) Silica/polymer double-walled hybrid nanotubes: synthesis and application as stimuli-responsive nanocontainers in self-healing coatings. ACS Nano 7:2470–2478CrossRef Li GL, Zheng Z, Möhwald H, Shchukin DG (2013) Silica/polymer double-walled hybrid nanotubes: synthesis and application as stimuli-responsive nanocontainers in self-healing coatings. ACS Nano 7:2470–2478CrossRef
18.
Zurück zum Zitat Jackson AC, Bartelt JA, Braun PV (2011) Transparent self-healing polymers based on encapsulated plasticizers in a thermoplastic matrix. Adv Funct Mater 21:4705–4711CrossRef Jackson AC, Bartelt JA, Braun PV (2011) Transparent self-healing polymers based on encapsulated plasticizers in a thermoplastic matrix. Adv Funct Mater 21:4705–4711CrossRef
19.
Zurück zum Zitat Wang Y, Li T, Li S, Guo R, Sun J (2015) Healable and optically transparent polymeric films capable of being erased on demand. ACS Appl Mater Interfaces 7:13597–13603CrossRef Wang Y, Li T, Li S, Guo R, Sun J (2015) Healable and optically transparent polymeric films capable of being erased on demand. ACS Appl Mater Interfaces 7:13597–13603CrossRef
20.
Zurück zum Zitat Guo PL, Zhang HY, Liu XK, Sun JQ (2018) Counteranion-mediated intrinsic healing of poly(ionic liquid) copolymers. ACS Appl Mater Interfaces 10:2105–2113CrossRef Guo PL, Zhang HY, Liu XK, Sun JQ (2018) Counteranion-mediated intrinsic healing of poly(ionic liquid) copolymers. ACS Appl Mater Interfaces 10:2105–2113CrossRef
21.
Zurück zum Zitat Wang X, Wang Y, Bi S, Wang Y, Chen X, Qiu L, Sun J (2014) Optically transparent antibacterial films capable of healing multiple scratches. Adv Funct Mater 24:403–411CrossRef Wang X, Wang Y, Bi S, Wang Y, Chen X, Qiu L, Sun J (2014) Optically transparent antibacterial films capable of healing multiple scratches. Adv Funct Mater 24:403–411CrossRef
22.
Zurück zum Zitat Zhu YX, Xuan HY, Ren JY, Ge LQ (2015) Self-healing multilayer polyelectrolyte composite film with chitosan and poly(acrylic acid). Soft Matter 11:8452–8459CrossRef Zhu YX, Xuan HY, Ren JY, Ge LQ (2015) Self-healing multilayer polyelectrolyte composite film with chitosan and poly(acrylic acid). Soft Matter 11:8452–8459CrossRef
23.
Zurück zum Zitat Xuan HY, Ren JY, Zhang JH, Ge LQ (2017) Novel highly-flexible, acid-resistant and self-healing host–guest transparent multilayer films. Appl Surf Sci 411:303–314CrossRef Xuan HY, Ren JY, Zhang JH, Ge LQ (2017) Novel highly-flexible, acid-resistant and self-healing host–guest transparent multilayer films. Appl Surf Sci 411:303–314CrossRef
24.
Zurück zum Zitat Xuan HY, Ren JY, Wang XZ, Zhang JH, Ge LQ (2017) Flame-retardant, non-irritating and self-healing multilayer films with double-network structure. Compos Sci Technol 145:15–23CrossRef Xuan HY, Ren JY, Wang XZ, Zhang JH, Ge LQ (2017) Flame-retardant, non-irritating and self-healing multilayer films with double-network structure. Compos Sci Technol 145:15–23CrossRef
25.
Zurück zum Zitat Wang J, Hao D, Ye J, Umezawa N (2017) Determination of crystal structure of graphitic carbon nitride: ab initio evolutionary search and experimental validation. Chem Mater 29:2694–2707CrossRef Wang J, Hao D, Ye J, Umezawa N (2017) Determination of crystal structure of graphitic carbon nitride: ab initio evolutionary search and experimental validation. Chem Mater 29:2694–2707CrossRef
26.
Zurück zum Zitat Lu QJ, Wang HY, Liu YL, Hou YX, Li HT, Zhang YY (2017) Graphitic carbon nitride nanodots: as reductant for the synthesis of silver nanoparticles and its biothiols biosensing application. Biosens Bioelectron 89:411–416CrossRef Lu QJ, Wang HY, Liu YL, Hou YX, Li HT, Zhang YY (2017) Graphitic carbon nitride nanodots: as reductant for the synthesis of silver nanoparticles and its biothiols biosensing application. Biosens Bioelectron 89:411–416CrossRef
27.
Zurück zum Zitat Pang XH, Bian HJ, Wang WJ, Liu C, Khan MS, Wang Q, Qi JN, Wei Q, Du B (2017) A bio-chemical application of N-GQDs and g-C3N4 QDs sensitized TiO2 nanopillars for the quantitative detection of pcDNA3-HBV. Biosens Bioelectron 91:456–464CrossRef Pang XH, Bian HJ, Wang WJ, Liu C, Khan MS, Wang Q, Qi JN, Wei Q, Du B (2017) A bio-chemical application of N-GQDs and g-C3N4 QDs sensitized TiO2 nanopillars for the quantitative detection of pcDNA3-HBV. Biosens Bioelectron 91:456–464CrossRef
28.
Zurück zum Zitat Achadu OJ, Nyokong T (2017) In situ one-pot synthesis of graphitic carbon nitride quantum dots and its 2,2,6,6-tetramethyl (piperidin-1-yl)oxyl derivatives as fluorescent nanosensors for ascorbic acid. Anal Chim Acta 991:113–126CrossRef Achadu OJ, Nyokong T (2017) In situ one-pot synthesis of graphitic carbon nitride quantum dots and its 2,2,6,6-tetramethyl (piperidin-1-yl)oxyl derivatives as fluorescent nanosensors for ascorbic acid. Anal Chim Acta 991:113–126CrossRef
29.
Zurück zum Zitat Xu JH, Ye S, Ding CD, Tan LH, Fu JJ (2018) Autonomous self-healing supramolecular elastomer reinforced and toughened by graphitic carbon nitride nanosheets tailored for smart anticorrosion coating applications. J Mater Chem A 6:5887–5898CrossRef Xu JH, Ye S, Ding CD, Tan LH, Fu JJ (2018) Autonomous self-healing supramolecular elastomer reinforced and toughened by graphitic carbon nitride nanosheets tailored for smart anticorrosion coating applications. J Mater Chem A 6:5887–5898CrossRef
30.
Zurück zum Zitat Chen LC, Song JB (2017) Tailored graphitic carbon nitride nanostructures: synthesis, modification, and sensing applications. Adv Funct Mater 27:1702695CrossRef Chen LC, Song JB (2017) Tailored graphitic carbon nitride nanostructures: synthesis, modification, and sensing applications. Adv Funct Mater 27:1702695CrossRef
31.
Zurück zum Zitat Zou WX, Shao Y, Pu Y, Luo YD, Sun JF, Ma KL, Tang CJ, Gao F, Dong L (2017) Enhanced visible light photocatalytic hydrogen evolution via cubic CeO2 hybridized g-C3N4 composite. Appl Catal B Environ 218:51–59CrossRef Zou WX, Shao Y, Pu Y, Luo YD, Sun JF, Ma KL, Tang CJ, Gao F, Dong L (2017) Enhanced visible light photocatalytic hydrogen evolution via cubic CeO2 hybridized g-C3N4 composite. Appl Catal B Environ 218:51–59CrossRef
32.
Zurück zum Zitat Liu NY, Liu J, Kong WQ, Li H, Huang H, Liu Y, Kang ZH (2014) One-step catalase controllable degradation of C3N4 for N-doped carbon dot green fabrication and their bioimaging applications. J Mater Chem B 2:5768–5774CrossRef Liu NY, Liu J, Kong WQ, Li H, Huang H, Liu Y, Kang ZH (2014) One-step catalase controllable degradation of C3N4 for N-doped carbon dot green fabrication and their bioimaging applications. J Mater Chem B 2:5768–5774CrossRef
33.
Zurück zum Zitat Liu X, Chen N, Li YX, Deng DY, Xing XX, Wang YD (2016) A general nonaqueous sol-gel route to g-C3N4-coupling photocatalysts: the case of Z-scheme g-C3N4/TiO2 with enhanced photodegradation toward RhB under visible-light. Sci Rep 6:39531CrossRef Liu X, Chen N, Li YX, Deng DY, Xing XX, Wang YD (2016) A general nonaqueous sol-gel route to g-C3N4-coupling photocatalysts: the case of Z-scheme g-C3N4/TiO2 with enhanced photodegradation toward RhB under visible-light. Sci Rep 6:39531CrossRef
34.
Zurück zum Zitat Hu JD, Chen DY, Li NJ, Xu QF, Li H, He JH, Lu JM (2018) Fabrication of graphitic-C3N4 quantum dots/graphene-InVO4 aerogel hybrids with enhanced photocatalytic NO removal under visible-light irradiation. Appl Catal B 236:45–52CrossRef Hu JD, Chen DY, Li NJ, Xu QF, Li H, He JH, Lu JM (2018) Fabrication of graphitic-C3N4 quantum dots/graphene-InVO4 aerogel hybrids with enhanced photocatalytic NO removal under visible-light irradiation. Appl Catal B 236:45–52CrossRef
35.
Zurück zum Zitat Zhang JS, Chen Y, Wang XC (2015) Two-dimensional covalent carbon nitride nanosheets: synthesis, functionalization, and applications. Energy Environ Sci 8:3092–3108CrossRef Zhang JS, Chen Y, Wang XC (2015) Two-dimensional covalent carbon nitride nanosheets: synthesis, functionalization, and applications. Energy Environ Sci 8:3092–3108CrossRef
36.
Zurück zum Zitat Dong XP, Cheng FX (2015) Recent development in exfoliated two-dimensional g-C3N4 nanosheets for photocatalytic applications. J Mater Chem A 3:23642–23652CrossRef Dong XP, Cheng FX (2015) Recent development in exfoliated two-dimensional g-C3N4 nanosheets for photocatalytic applications. J Mater Chem A 3:23642–23652CrossRef
37.
Zurück zum Zitat Ye BY, Han XX, Yan MD, Zhang HH, Xi FN, Dong XP, Liu JY (2017) Fabrication of metal-free two dimensional/two dimensional homojunction photocatalyst using various carbon nitride nanosheets as building blocks. J Colloid Interface Sci 507:209–216CrossRef Ye BY, Han XX, Yan MD, Zhang HH, Xi FN, Dong XP, Liu JY (2017) Fabrication of metal-free two dimensional/two dimensional homojunction photocatalyst using various carbon nitride nanosheets as building blocks. J Colloid Interface Sci 507:209–216CrossRef
38.
Zurück zum Zitat Yao CK, Yuan AL, Zhang HH, Li BX, Xi FN, Dong XP (2019) Facile surface modification of textiles with photocatalytic carbon nitride nanosheets and the excellent performance for self-cleaning and degradation of gaseous formaldehyde. J Colloid Interface Sci 533:144–153CrossRef Yao CK, Yuan AL, Zhang HH, Li BX, Xi FN, Dong XP (2019) Facile surface modification of textiles with photocatalytic carbon nitride nanosheets and the excellent performance for self-cleaning and degradation of gaseous formaldehyde. J Colloid Interface Sci 533:144–153CrossRef
41.
Zurück zum Zitat Hong SH, Kim SJ, Park JP, Shin M, Kim K, Ryu JH, Lee H (2018) Dynamic bonds between boronic acid and alginate: hydrogels with stretchable, self-healing, stimuli-responsive, remoldable, and adhesive properties. Biomacromolecules 19:2053–2061CrossRef Hong SH, Kim SJ, Park JP, Shin M, Kim K, Ryu JH, Lee H (2018) Dynamic bonds between boronic acid and alginate: hydrogels with stretchable, self-healing, stimuli-responsive, remoldable, and adhesive properties. Biomacromolecules 19:2053–2061CrossRef
Metadaten
Titel
Intrinsic self-healing and biocompatibility of carbon nitride coatings via inhibiting or degrading ethylene for fruit preservation
verfasst von
Hongyun Xuan
Yanxi Zhu
Jiaoyu Ren
Liqin Ge
Publikationsdatum
18.03.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 12/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03383-1

Weitere Artikel der Ausgabe 12/2019

Journal of Materials Science 12/2019 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.