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Erschienen in: Journal of Materials Science 22/2017

26.07.2017 | Energy materials

Ionic liquid-derived Co3O4/carbon nano-onions composite and its enhanced performance as anode for lithium-ion batteries

verfasst von: Yanshuang Meng, Gongrui Wang, Mingjun Xiao, Chaoyu Duan, Chen Wang, Fuliang Zhu, Yue Zhang

Erschienen in: Journal of Materials Science | Ausgabe 22/2017

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Abstract

In this work, a novel composite of Co3O4 nanoparticle and carbon nano-onions (CNOs) is synthesized by using ionic liquid as carbon and nitrogen source through a facile carbothermic reduction followed by low-temperature oxidation method. The SEM and HRTEM images reveal that the Co3O4 particles are homogenously embedded in the CNOs. Due to the unique nano-structure, the electrolyte contacts well with the active materials, leading to a better transfer of lithium ions. Moreover, the unique nano-structure not only buffers the volume changes but also facilitates the shuttling of electrons during the cycling process. As a result, the electrode made up of Co3O4/CNOs composite delivers favorable cycling performance (676 mAh g−1 after 200 cycles) and rate capability (557 mAh g−1 at the current of 1 C), showing a promising prospect for lithium-ion batteries as anode materials.

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Metadaten
Titel
Ionic liquid-derived Co3O4/carbon nano-onions composite and its enhanced performance as anode for lithium-ion batteries
verfasst von
Yanshuang Meng
Gongrui Wang
Mingjun Xiao
Chaoyu Duan
Chen Wang
Fuliang Zhu
Yue Zhang
Publikationsdatum
26.07.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 22/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1414-x

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