nach oben

Erschienen in:

2013 | OriginalPaper | Buchkapitel

2. The Charge Conduction Process at Poly(o-aminophenol) Film Electrodes

verfasst von : Ricardo Tucceri

Erschienen in: Poly(o-aminophenol) Film Electrodes

Verlag: Springer International Publishing

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Electroactive polymers contain electron donor and acceptor sites that usually consist of up to hundreds of molecular layers. Oxidation and reduction of fixed sites introduce charged sites into the polymer, which, to achieve charge neutrality, require the ingress of counter-ions from the contacting electrolyte solution and, according to the Donnan relation, the egress of co-ions.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Vorheriges Kapitel Electropolymerization of o-aminophenol on Different Electrode Materials and in Different Electrolyte Media: Formation of Poly(o-aminophenol) Film Electrodes

Nächstes Kapitel Applications of Nonconducting Poly(o-aminophenol) Films in Bioelectrochemistry and Electrocatalysis

Barbero, C., Silber, J.J., Sereno, L.: Electrochemical properties of poly-ortho-aminophenol modified electrodes in aqueous acid solutions. J. Electroanal. Chem. 291, 81 (1990)CrossRef

Bard, A.J., Faulkner, L.R.: Electrochemical Methods. Fundamentals and Applications. Wiley, New York (1980)

Barbero, C., Zerbino, J., Sereno, L., Posadas, D.: Optical properties of electropolymerized orthoaminophenol. Electrochim. Acta 32, 693 (1987)CrossRef

Gabrielli, C., Takenouti, H., Haas, O., Tsukada, A.: Impedance investigation of the charge transport in film-modified electrodes. J. Electroanal. Chem. 302, 59 (1991)CrossRef

Nicholson, R.S.: Theory and application of cyclic voltammetry for measurements of electrode reaction kinetics. Anal. Chem. 37, 1351 (1965)CrossRef

Laviron, E.: Theoretical study of a reversible reaction followed by a chemical reaction in thin layer linear potential sweep voltammetry. J. Electroanal. Chem. 39, 1 (1972)CrossRef

Konopelnik, O.I., Aksimentyeva, O.I., Grytsiv, M.Ya.: Electrochromic transitions on polyaminoarene films on the transparent electrodes. Mater. Sci. 20, 49–59 (2002)

Maksimov, Y.M., Khaldum, M., Podlovchenko, B.I.: Electrocatalysis on polymer-modified electrodes. Elektrokhimiya 27, 739 (1991)

Dobosh, D.: Electochemical Constants. Ed. Mir., Moscow (1980)

10.

Foot, P.J.S., Simon, R.: Electrochromic properties of conductiong polyanilines. J. Phys. D: Appl. Phys. 22, 159 (1989)CrossRef

11.

Levin, O., Kondratiev, V., Malek, V.: Charge transfer processes at poly-o-phenylenediamine and poly-o-aminophenol films. Electrochim. Acta, 50, 1573 (2005)

12.

Ohsaka, T., Kunimura, S., Oyama, N.: Electrode kinetics of poly(o-aminophenol) film prepared by electro-oxidative polymerization of o-aminophenol and its electrochromic properties. Electrochim. Acta 33, 639 (1988)CrossRef

13.

Barbero, C., Tucceri, R.I., Posadas, D., Silber, J.J., Sereno, L.: Impedance characteristics of poly(o-aminophenol) electrodes. Electrochim. Acta, 40, 1037 (1995)

14.

Chidsey, C.E.D., Murray, R.W.: Redox capacity and direct current electron conductivity in electroactive materials. J. Phys. Chem. 90, 1479 (1986)CrossRef

15.

Komura, T., Ito, Y., Yamaguti, T., Takahasi, K.: Charge-transport processes at poly-o-aminophenol film electrodes: electron hopping accompanied by proton exchange. Electrochim. Acta 43, 723 (1988)CrossRef

16.

Mathias, M.F., Haas, O.: An alternating current impedance model including migration and redox-site interactions at polymer-modified electrodes. J. Phys. Chem. 96, 3174 (1992)CrossRef

17.

Armstrong, R.D.: Impedance plane display for an electrode with diffusion restricted to a thin layer. J. Electroanal. Chem. 198, 177 (1986)CrossRef

18.

Rodríguez Nieto, F.J., Posadas, D., Tucceri, R.: Effect of the of the bathing Electrolyte Concentration on the Charge Transport Process at Poly(o-aminophenol) Modified Electrodes. An ac Impedance study. J. Electroanal. Chem. 434, 83–91 (1997)CrossRef

19.

Albery, W.J., Elliot, C.M., Mount, A.R.: A transmission line model for modified and thin layer cells. J. Electroanal. Chem. 288, 15 (1990)CrossRef

20.

Albery, W.J., Mount, A.R.: A further development of the use of transmission lines to describe the movement of charge in conducting polymers. J. Electroanal. Chem. 388, 1 (1995)CrossRef

21.

Rodríguez Nieto, F.J., Tucceri, R.: The pH Effect on the Charge Transport at Redox Polymer-Modified Electrodes. An ac Impedance Study applied to Poly(o-aminophenol) Film Electrodes. J. Electroanal. Chem. 416, 1–24 (1996)CrossRef

22.

Kunimura, S., Ohsaka, T., Oyama, N.: Preparation of thin polymeric films on electrode surfaces by electropolymerization of o-aminophenol. Macromolecules 21, 894 (1988)CrossRef

23.

Tucceri, R.: A review about the charge conduction process at poly(o-aminopenol) film electrodes. Open Phys. Chem. J. 4, 62 (2010)

24.

MacDiarmid, A.G., Kaner, R.B.: In: Handbook of Conducting Polymers, T.A. Skotheim (ed.), vol. 1, p. 689. Marcel Dekker, New York (1986)

25.

Huang, W.S., Hamphrey, B.D., MacDiarmid A.J.: Polyaniline, a novel conducting polymer. Morphology and chemistry of its oxidation and reduction in aqueous electrolytes. J. Chem. Soc. Faraday Trans. 1, 82, 2385 (1986)

26.

Chattaraj, A.P., Basumallik, I.N.: Improved conducting polymer cathodes for lithium batteries. J. Power Sources 45, 237 (1993)CrossRef

27.

Tanaka, K., Shichiri, T., Yamabe, T.: Influence of polymerization temperature on the characteristics of polythiophene films. Synth. Met. 16, 207 (1986)

28.

Satoh, M., Kaneto, K., Yoshino, K.: Electrochemistry preparation of high quality poly(p-phenylene) film. J. Chem. Soc., Chem. Commun. 25, 1629 (1985)CrossRef

29.

Chance, R.R., Boudreaux, D.S., Bredas, J.L., Silbey, R. In: T.A. Skotheim (ed.), Handbook of Conducting Polymers, vol. 2, p. 825. Marcel Dekker, New York (1986)

30.

Ortega, M.: Conducting potential range of poly(o-aminophenol). Thin Solid Films 371, 28 (2000)CrossRef

31.

Salvagione, H.J., Arias-Padilla, J., Pérez, J.M., Vázquez, J.L., Morallón, E., Miras, M.C., Barbero, C.: Study of the redox mechanism of poly(o-aminophenol) using in situ techniques: evidence of two redox processes. J. Electroanal. Chem. 576, 139 (2005)CrossRef

32.

Tucceri, R.I., Barbero, C., Silber, J.J., Sereno, L., Posadas, D.: Spectroelectrochemical study of poly-o-aminophenol. Electrochim. Acta 42, 919 (1997)CrossRef

33.

Malek, K.: Dynamic Monte-Carlo simulation of electrochemical switching of a conducting polymer film. Chem. Phys. Lett. 375, 477 (2003)CrossRef

34.

Aoki, K.: Nernst equation complicated by electric random percolation at conducting polymer-coated electrodes. J. Electroanal. Chem. 310, 1 (1991)CrossRef

35.

Aoki, K.: Simulation of electrochemical slow relaxation at electrically conducting polymer-coated electrodes based on the concept of percolation. J. Electroanal. Chem. 373, 67 (1994)CrossRef

36.

Aoki, K., Teragashi, Y., Tokeida, M.: Light scattering of polyaniline films responding to electrochemical switching. J. Electroanal. Chem. 460, 254 (1999)CrossRef

37.

Odin, C., Nachtschein, M.: Slow relaxation in conducting polymers. Phys. Rev. Lett. 67, 1114 (1991)CrossRef

38.

Buck, R.P.: Electron hopping in one dimension: mixed conductor membranes. J. Phys. Chem. 92, 4196 (1988)CrossRef

39.

Tucceri, R.: A review about the surface resistance technique in electrochemistry. Surf. Sci. Rep. 56, 85 (2004)CrossRef

40.

Tucceri, R.I.: Surface resistance measurements on thin gold film electrodes coated with poly(o-aminophenol) films. J. Electroanal. Chem. 505, 72 (2001)CrossRef

41.

Tucceri, R.I.: Specularity change of a thin gold film surface coated with poly(o-aminophenol) during the polymer redox conversion. The pH affect on the redox sites distribution at the metal||polymer interface. J. Electroanal. Chem. 543, 61 (2003)CrossRef

42.

Rodríguez, F.J., Tucceri, R.: Influencia del grado de oxidación y de la concentración del electrolito soporte sobre el transporte de carga de un polímero electroactivo. Información Tecnológica 9, 109 (1988)

43.

Rudnicki, J.D., Brisard, G.M., Gasteiger, H.A., Russo, R.E., McLarnon, F.R., Cairns, E.J.: Effect of the supporting electrolyte and beam diameter on probe beam deflection experiments. J. Electroanal. Chem. 362, 55 (1993)CrossRef

44.

Gobal, F., Malek, K., Mahjani, M.G., Jafarian, M., Safarnavadeh, V.: A study of the fractal dimension of the electrodeposited poly-ortho-aminophenol films in presence of different anions. Synth. Met. 108, 15 (2000)CrossRef

45.

Stromme, M., Niklasson, G.A., Granqvist, C.G.: Determination of fractal dimension by cyclic I-V studies: The Laplace-transform method. Phys. Rev. B 52, 14192 (1995)CrossRef

46.

Malek, K., Gobal, F.: Application of chaotic logistic map for the interpretation of anion-insertion on poly-ortho-aminophenol films. Synth. Met. 113, 167 (2000)CrossRef

47.

González, E.R.: Interpretation of the Power Response of a Fuel Cell with a Quadratic Logistic Differential Equation. J. Electrochem. Soc., 143, L 113 (1996)

48.

Rasband, S.N.: Chaotic Dynamics of Nonlinear Systems. Wiley, New York (1990)

49.

Tucceri, R.: Application of the Surface Resistance technique to detect the different interactions of ClO₄ ^-, SO₄ ^2- and C₆H₅SO₃ ^- anions and Cu(II) cation with a gold surface partially blocked with poly(o-aminophenol). J. Argent. Chem. Soc. 94, 55 (2006)

50.

Tucceri, R.: The metal/electroactive polymer interface studied by surface resistance. J. Surf. Eng. Mater. Adv. Technol. 3, 205 (2013)

51.

Ybarra, G., Moina, C., Florit, M.I., Posadas, D.: Redox mediation at electroactive polymer coated electrodes: Mechanistic diagnosis criteria from steady state polarization curves. J. Electroanal. Chem. 609, 129 (2007)CrossRef

52.

Ybarra, G., Moina, C., Florit, M.I., Posadas, D.: Current rectification by mediating electroactive polymers. Electrochim. Acta 53, 3955 (2008)CrossRef

53.

Bonfranceschi, A., Pérez Córdoba, A., Keunchkarian, S., Zapata, S., Tucceri, R.: Transport across poly(o-aminophenol) modified electrodes in contact with media containing redox active couples. A study using rotating disc electrode voltammetry. J. Electroanal. Chem. 477, 1 (1999)CrossRef

54.

Ikeda, T., Schmehl, R., Denisevich, P., Willman, K., Murray, R.W.: Permeation of electroactive solutes through ultrathin polymeric films on electrode surfaces. J. Am. Chem. Soc. 104, 2683 (1982)CrossRef

55.

Pinilla Macías, J.M., Hernández Hernández, L., Moreno Sobrino, J.M., Sevella Escribano, M.T.: Determination of paraquat by cathodic stripping voltammetry after accumulation through the formation of an ion pair on a hanging mercury drop electrode. Electroanalysis 79, 5 (1993)

56.

Rodríguez Nieto, F.J., Tucceri, R., Posadas, D.: EIS Detection of the Partial Oxidation of Polymers derived from Aryl Amines. J. Electroanal. Chem. 403, 241 (1996)CrossRef

57.

Tucceri, R.: The effect of high positive potentials on the different charge transport and charge transfer parameters of poly(o-aminophenol) modified electrodes. A study using cyclic voltammetry, rotating disc electrode voltammetry and ac impedance measurements. J. New Mater. Electrochem. Syst. 8, 305 (2005)

58.

Vorotyntsev, M.A., Deslouis, C., Musiani, M.M., Tribollet, B., Aoki, K.: Transport across an electroactive polymer film in contact with media allowing both ionic and electronic interfacial exchange. Electrochim. Acta 44, 2105 (1999)CrossRef

59.

Tucceri, R.I.: Redox mediation and permeation processes at deactivated poly(o-aminophenol) films. A study applying rotating disc electrode voltammetry and electrochemical impedance spectroscopy. J. Electroanal. Chem. 633, 198 (2009)CrossRef

60.

Tucceri, R.I.: Charge transfer and charge transport parameters at deactivated poly(o-aminophenol) film electrodes. A study applying Electrochemical Impedance Spectroscopy. J. Electroanal. Chem. 659, 83 (2011)CrossRef

61.

Vorotyntsev, M.A.: Impedance of thin films with two mobile charge carriers. Interfacial exchange of both species with adjacent media. Effect of the double layer charges. Electrochim. Acta 47, 2071 (2002)CrossRef

Titel: The Charge Conduction Process at Poly(o-aminophenol) Film Electrodes
verfasst von: Ricardo Tucceri
Verlag: Springer International Publishing
Buch: Poly(o-aminophenol) Film Electrodes
Print ISBN: 978-3-319-02113-3

Electronic ISBN: 978-3-319-02114-0

Copyright-Jahr: 2013
DOI: https://doi.org/10.1007/978-3-319-02114-0_2

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht