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1987 | Buch

The Mesophase Concept in Composites

verfasst von: Professor Dr. Pericles S. Theocaris

herausgegeben von: Dr. G. Henrici-Olivé, Professor S. Olivé

Verlag: Springer Berlin Heidelberg

Buchreihe : Polymers

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SUCHEN

Über dieses Buch

The increasing use of advanced composite materials in modem structures of high performance calls for a detailed knowledge of their properties. On the other hand, these materials possessing intense anisotropy, and in some cases non homogeneity, require complicated theories based on homogeneous anisotropic elasticity. Typically, such materials either involve fiber-reinforced composites, which are stacked in layers and form laminates, or particulate composites, containing a second phase in powder form. However, each case must be separately analyzed in terms of the particular characteristics of the materials involved and the process of preparation of the com­ posite systems. Composite materials consisting of more than one destinct phase are in general use in modem industrial applications. Machine parts, structural components and others may be manufactured from such materials. Epoxy resins are suitable matrices for this class of materials. This is due not only to their general-properties such as linear mechanical behavior, transparency, etc., but also to the possibility of modifying their mechanical and optical properties in a very wide range by using suitable modifiers. Their rheological behavior, as well as their dynamic properties have been extensively investigated.

Inhaltsverzeichnis

Frontmatter
II. Introduction
Abstract
Introducing a filler into a polymeric matrix results in the production of a composite material with superior strength. However, predicting the properties of the product is difficult, since they depend on a great number of parameters. Attempts to predict such features may only lead to a rough estimation of the influence of fillers on the overall behavior of the composite. For example, a linear increase of the strength of the composite is observed as the filler-volume fraction increases. However, the reinforcing action of the filler is limited by the nature, shape and grade of the filler, and, on the other hand, by the adhesion efficiency between the two phases and the mechanism of failure of the composite system. Also, another important factor affecting the strength properties is the interaction between individual filler particles. This last parameter is difficult to predict in a real composite. Figure I illustrates the interaction between an idealized array of parallel fibers embedded in a softer matrix, which resulted from shrinkage stresses developed during casting. A transverse section of this composite is shown. The isochromatics in this figure yield the difference of principal stresses due to shrinkage of the matrix 1, 2).
Pericles S. Theocaris
III. Models for Composite Materials
Abstract
Composite materials consist of two or more distinct constituents or phases, which are insoluble in one another.
Pericles S. Theocaris
IV. Retardation Spectra of Composites Indicating the Existence of a Mesophase
Abstract
An enhanced description of the actual behavior of composites is given by an improved composite model, which considers the mesophase to consist of an infinite number of concentric thin layers (cylinders or spheres) around inclusions (fibers or particles) allowing progressively different mechanical properties for each cylinder or sphere, changing from those of the inclusion to those of the matrix.
Pericles S. Theocaris
V. Static and Dynamic Properties of Composites as Influenced by the Mesophase
Abstract
Approximate equations have been established 57) for determining the transverse modulus of elasticity in a unidirectional fiber-reinforced composite material from its constituent material properties. The classical theory of elasticity was applied to the simplified model of a composite unit-cell. Stress functions were applied to the fiber and matrix with boundary conditions requiring continuity of displacements across the fiber-matrix interface, and perfect bonding was assumed. Graphical results are presented for glass-epoxy composites. The numerical results were compared with experimental data. The transverse elastic modulus, derived by applying the model introduced in this chapter, is in good agreement with experimental results.
Pericles S. Theocaris
VI. The Influence of the Mesophase on the Thermal Behavior of Composites
Abstract
In studying the thermal behavior of composites it was assumed that the mesophase material is an inhomogeneous substance with properties varying continuously from the inclusion boundary to the bulk matrix, i.e., the multiple-layer model was introduced. In this way, the variation of the thermal expansion coefficient in the mesophase zone was investigated. Two components of this coefficient were derived for fiber-reinforced composites, the one along the longitudinal direction and the other along the transverse direction of these laterally isotropic materials. The corrections inserted by introducing the influence of mesophase led to agree satisfactorily with Schapery’s experimental results 98).
Pericles S. Theocaris
VII. The Glass Transition of Composites and Influence of the Mesophase
Abstract
The glass-transition temperature T g is the threshold at which the slope of the specific volume vs. temperature curve changes abruptly. It marks the region between rubbery- and glassy-polymer behavior. An increase by a factor of one hundred to one thousand in the stiffness or modulus usually occurs in this temperature region, and physically it is the temperature at which the secondary bonding forces overcome the thermal disruptive forces 108).
Pericles S. Theocaris
VIII. Mechanisms of Moisture Absorption in Composites
Abstract
Moisture absorption is a main parameter affecting the thermomechanical behavior of composites 126). Absorbed moisture causes plasticization of the polymer matrix with a concurrent swelling and decrease of its glass transition temperature T g 127–130). Thermal expansion and swelling of a composite, due to temperature and moisture variations, influence significantly their mechanical behavior through residual stresses between filler and matrix 131). Moreover, incorporation of fillers into polymeric matrices leads to changes in their glass-transition temperature T g 132), probably because of the immobilization, by absorption of polymer segments close to the surface of the filler particles 133).
Pericles S. Theocaris
IX. Shrinkage Stress at the Mesophase Developed During Casting
Abstract
Among the most important factors determining the viscoelastic behavior of polymeric composite systems, are the adsorption of polymer macromolecules onto filler particles, as well as the adhesion between matrix and inclusions. The adsorption of polymer molecules onto filler particles is the main cause of the different conformations of macromolecules in the close vicinity of inclusions. Moreover, the change of shape of the macromolecules at the interface determines a region around the filler particles, which has different structure and properties than those of the bulk matrix. Thus, the presence of the filler in the polymeric matrix results in an imperfectness of the polymer network.
Pericles S. Theocaris
X. Stress Singularities at the Mesophase due to the Geometry of Inclusions
Abstract
One of the main factors contributing to the degree of adsorption developed between the setting matrix and an inclusion is the surface quality of the inclusion. An ideal spherical inclusion, or a cylindrical one terminating in two half-spheres, with a polished — or at least smooth — boundary is considered an ideal interface, along which sufficient factors leading to a mesophase may arise. The absence of cavities, abrupt edges, singularities, and sudden variations of the shape of the enveloping surface of an inclusion warrant a surface where stress concentrations or stress singularities are minimized, not yielding ground for anomalous developments of constrained regions of the setting matrix. Then, the quality of the surface of the inclusions is very important, as it contributes to the structure of the surface and to the adjacent boundary layer of the matrix.
Pericles S. Theocaris
XI. Stress Singularities in Cracked Phases
Abstract
The previous chapter described the stress concentrations and stress singularities developed in the composite because of geometric discontinuities in the inclusions. We now concentrate on singularities developed in the matrix. Since in the preparation of the composite the viscous matrix is generally cast around the solid inclusions, the matrix material is impelled to fill all cavities and protrusions of the inclusions and to adhere firmly along the interfaces of the inclusions.
Pericles S. Theocaris
Backmatter
Metadaten
Titel
The Mesophase Concept in Composites
verfasst von
Professor Dr. Pericles S. Theocaris
herausgegeben von
Dr. G. Henrici-Olivé
Professor S. Olivé
Copyright-Jahr
1987
Verlag
Springer Berlin Heidelberg
Electronic ISBN
978-3-642-70182-5
Print ISBN
978-3-642-70184-9
DOI
https://doi.org/10.1007/978-3-642-70182-5