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Journal of Materials Science
Erschienen in: Journal of Materials Science 11/2016

26.02.2016 | Original Paper

Identification of α-Al2O3 surface sites and their role in the adsorption of stearic acid

verfasst von: J. Webber, J. E. Zorzi, C. A. Perottoni, S. Moura e Silva, R. C. D. Cruz

Erschienen in: Journal of Materials Science | Ausgabe 11/2016

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ABSTRACT

The adsorption isotherm of stearic acid (SA) on α-Al2O3 previously subjected to dialysis by ion exchange was determined with the aid of LC–MS analysis of the supernatant. The first monolayer saturation occurred at 0.8 %wt of SA and a second monolayer started above 1.6 %wt of SA. The interaction mechanism between α-Al2O3 and SA was investigated by DRIFTS analysis of the coated powder. The surface hydroxyls primarily involved in SA adsorption occupy doubly and triply coordinated sites on the α-Al2O3 surface, as evidenced by the inverse infrared bands at 3750 and 3695 cm−1. The interaction between α-Al2O3 and SA gives rise to bands at 1566 (νasCOO−) and 1468 cm−1 (νsCOO−), as well as bands at 1415 (ν+δCOH) and 1320 cm−1 (OH···H). It is proposed that adsorption of stearic acid on α-alumina occurs predominantly through electrostatic interactions and hydrogen bonding, without exchange reaction and direct complexation with surface Al cations.
Vorheriger Artikel A simple way to prepare a precursor for ZrC–SiC ceramics
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Literatur
1.
Sigmund W, Pyrgiotakis G, Daga A (2005) Theory and applications of colloidal processing. In: Lee BI, Komarneni S (eds) Chemical processing of ceramics. CRC Press, Boca Raton
2.
Holmberg K (2002) Handbook of applied colloid and surface chemistry. Wiley, New York
3.
Lewis JA (2004) Colloidal processing of ceramics. J Am Ceram Soc 83:2341–2359CrossRef
4.
Reed JS (1995) Principles of ceramics processing, 2nd edn. Wiley, New York
5.
Rosen MJ (2004) Surfactants and interfacial phenomena. Wiley, HobokenCrossRef
6.
Novak S, Vidovič K, Sajko M, Kosmač T (1997) Surface modification of alumina powder for LPIM. J Eur Ceram Soc 17:217–223CrossRef
7.
Tseng WJ (2000) Influence of surfactant on rheological behaviors of injection-molded alumina suspensions. Mater Sci Eng, A 289:116–122CrossRef
8.
Liu DM (1999) Effect of dispersant on the flow energy of ceramic injection molding mixtures. Mater Sci Eng A 259:141–144CrossRef
9.
Novak S, Olhero SMH, Ferreira JMF, Zupančič A (2004) Rheological properties of paraffin suspensions of surface-modified alumina powder for low-pressure injection moulding. Rheol Acta 43:559–566CrossRef
10.
11.
Zorzi JE, Perottoni CA, da Jornada JAH (2004) Moldagem por injeção em baixa pressão de peças complexas de cerâmicas avançadas produzidas com pós submicrométricos. Cerâmica 50:202–208CrossRef
12.
Chan T-Y, Lin S-T (1995) Effects of stearic acid on the injection molding of alumina. J Am Ceram Soc 78:2746–2752CrossRef
13.
Carter CB, Norton MG (2013) Ceramic materials: science and engineering. Springer, New YorkCrossRef
14.
de Oliveira IR, Studart AR, Pileggi RG, Pandolfelli VC (2000) Dispersão e Empacotamento de Partículas: Princípios e Aplicações em Processamento Cerâmico. Fazendo Arte, São Paulo
15.
Franks GV, Gan Y (2007) Charging behavior at the alumina–water interface and implications for ceramic processing. J Am Ceram Soc 90:3373–3388CrossRef
16.
Mutsuddy BC, Ford RG (1995) Ceramic injection molding. Chapman & Hall, London
17.
Knözinger H, Ratnasamy P (1978) Catalytic aluminas: surface models and characterization of surface sites. Catal Rev 17:31–70CrossRef
18.
El-Nadjar W, Bonne M, Trela E et al (2012) Infrared investigation on surface properties of alumina obtained using recent templating routes. Microporous Mesoporous Mater 158:88–98CrossRef
19.
Łodziana Z, Nørskov JK, Stoltze P (2003) The stability of the hydroxylated (0001) surface of α-Al2O3. J Chem Phys 118:11179–11188CrossRef
20.
Levin I, Brandon D (2005) Metastable alumina polymorphs: crystal structures and transition sequences. J Am Ceram Soc 81:1995–2012CrossRef
21.
Trainor TP, Eng PJ, Brown GE et al (2002) Crystal truncation rod diffraction study of the α-Al2O3 (102) surface. Surf Sci 496:238–250CrossRef
22.
Ahn J, Rabalais JW (1997) Composition and structure of The Al2O3{0001}-(1 × 1) surface. Surf Sci 388:121–131CrossRef
23.
Morterra C, Magnacca G (1996) A case study: surface chemistry and surface structure of catalytic aluminas, as studied by vibrational spectroscopy of adsorbed species. Catal Today 27:497–532CrossRef
24.
Juhl KMS, Bovet N, Hassenkam T et al (2014) Change in organic molecule adhesion on α-alumina (sapphire) with change in NaCl and CaCl2 solution salinity. Langmuir 30:8741–8750CrossRef
25.
Huang P, Pham TA, Galli G, Schwegler E (2014) Alumina(0001)/water interface: structural properties and infrared spectra from first-principles molecular dynamics simulations. J Phys Chem C 118:8944–8951CrossRef
26.
Catalano JG, Park C, Zhang Z, Fenter P (2006) Termination and water adsorption at the α-Al2O3 (012)-aqueous solution interface. Langmuir 22:4473–4668CrossRef
27.
Hiemstra T, Yong H, Van Riemsdijk WH (1999) Interfacial charging phenomena of aluminum (Hydr)oxides. Langmuir 15:5942–5955CrossRef
28.
Ballinger TH, Yates JT (1991) IR spectroscopic detection of Lewis acid sites on alumina using adsorbed carbon monoxide. Correlation with aluminum-hydroxyl group removal. Langmuir 7:3041–3045CrossRef
29.
Zhang L, Tian C, Waychunas GA, Shen YR (2008) Structures and charging of α-alumina (0001)/water Interfaces studied by sum-frequency vibrational spectroscopy. J Am Chem Soc 130:7686–7694CrossRef
30.
Brown GE, Henrich VE, Casey WH et al (1999) Metal oxide surfaces and their interactions with aqueous solutions and microbial organisms. Chem Rev 99:77–174CrossRef
31.
Rosenqvist J, Persson P, Sjöberg S (2002) Protonation and charging of nanosized gibbsite (α-Al(OH)3) particles in aqueous suspension. Langmuir 18:4598–4604CrossRef
32.
Hass KC (1998) The chemistry of water on alumina surfaces: reaction dynamics from first principles. Science 282:265–268CrossRef
33.
Kasprzyk-Hordern B (2004) Chemistry of alumina, reactions in aqueous solution and its application in water treatment. Adv Colloid Interface Sci 110:19–48CrossRef
34.
Hidber PC, Graule TJ, Gauckler LJ (1997) Influence of the dispersant structure on properties of electrostatically stabilized aqueous alumina suspensions. J Eur Ceram Soc 17:239–249CrossRef
35.
Contescu C, Jagiello J, Schwarz JA (1993) Heterogeneity of proton binding sites at the oxide/solution interface. Langmuir 9:1754–1765CrossRef
36.
Johnson SB, Yoon TH, Slowey AJ, Brown GE (2004) Adsorption of organic matter at mineral/water interfaces: 3. implications of surface dissolution for adsorption of oxalate. Langmuir 20:11480–11492CrossRef
37.
Mawhinney DB, Rossin JA, Gerhart K, Yates JT (1999) Adsorption and reaction of 2-chloroethylethyl sulfide with Al2O3 surfaces. Langmuir 15:4789–4795CrossRef
38.
Shirai T, Li JW, Matsumaru K et al (2005) Surface hydration states of commercial high purity α-Al2O3 powders evaluated by temperature programmed desorption mass spectrometry and diffuse reflectance infrared fourier transform spectroscopy. Sci Technol Adv Mater 6:123–128CrossRef
39.
Hass KC, Schneider WF, Curioni A, Andreoni W (2000) First-principles molecular dynamics simulations of H2O on α-Al2O3 (0001). J Phys Chem B 104:5527–5540CrossRef
40.
Yoon TH, Johnson SB, Brown GE (2005) Adsorption of organic matter at mineral/water interfaces. IV. Adsorption of humic substances at boehmite/water interfaces and impact on boehmite dissolution. Langmuir 21:5002–5012CrossRef
41.
Ha J, Hyun Yoon T, Wang Y et al (2008) Adsorption of organic matter at mineral/water interfaces: 7. ATR-FTIR and quantum chemical study of lactate interactions with hematite nanoparticles. Langmuir 24:6683–6692CrossRef
42.
Yoon TH, Johnson SB, Musgrave CB, Brown GE (2004) Adsorption of organic matter at mineral/water interfaces: I. ATR-FTIR spectroscopic and quantum chemical study of oxalate adsorbed at boehmite/water and corundum/water interfaces. Geochim Cosmochim Acta 68:4505–4518CrossRef
43.
Johnson SB, Yoon TH, Brown GE (2005) Adsorption of organic matter at mineral/water interfaces: 5. Effects of adsorbed natural organic matter analogues on mineral dissolution. Langmuir 21:2811–2821CrossRef
44.
Catalano JG, Park C, Fenter P, Zhang Z (2008) Simultaneous inner- and outer-sphere arsenate adsorption on corundum and hematite. Geochim Cosmochim Acta 72:1986–2004CrossRef
45.
Tong SR, Wu LY, Ge MF et al (2010) Heterogeneous chemistry of monocarboxylic acids on α-Al2O3 at different relative humidities. Atmos Chem Phys 10:7561–7574CrossRef
46.
Rubasinghege G, Ogden S, Baltrusaitis J, Grassian VH (2013) Heterogeneous uptake and adsorption of gas-phase formic acid on oxide and clay particle surfaces: the roles of surface hydroxyl groups and adsorbed water in formic acid adsorption and the impact of formic acid adsorption on water uptake. J Phys Chem A 117:11316–11327CrossRef
47.
Bowers A, Huang C (1985) Adsorption characteristics of polyacetic amino acids onto hydrous γ-Al2O3. J Colloid Interface Sci 105:197–215CrossRef
48.
Das MR, Mahiuddin S (2005) Kinetics and adsorption behaviour of benzoate and phthalate at the α-alumina–water interface: influence of functionality. Colloids Surf A 264:90–100CrossRef
49.
Liascukiene I, Aissaoui N, Asadauskas SJ et al (2012) Ordered nanostructures on a hydroxylated aluminum surface through the self-assembly of fatty acids. Langmuir 28:5116–5124CrossRef
50.
Öberg K, Persson P, Shchukarev A, Eliasson B (2001) Comparison of monolayer films of stearic acid and methyl stearate on an Al2O3 Surface. Thin Solid Films 397:102–108CrossRef
51.
Lim MS, Feng K, Chen X et al (2007) Adsorption and desorption of stearic acid self-assembled monolayers on aluminum oxide. Langmuir 23:2444–2452CrossRef
52.
Hasegawa M, Low MJ (1969) Infrared study of adsorption in situ at the liquid-solid interface. J Colloid Interface Sci 30:378–386CrossRef
53.
Kipling JJ, Wright EHM (1964) The adsorption of stearic acid from solution by oxide adsorbents. J Chem Soc 3535–3540
54.
Richard E, Aruna ST, Basu BJ (2012) Superhydrophobic surfaces fabricated by surface modification of alumina particles. Appl Surf Sci 258:10199–10204CrossRef
55.
Cruz RCD, Reinshagen J, Oberacker R et al (2005) Electrical conductivity and stability of concentrated aqueous alumina suspensions. J Colloid Interface Sci 286:579–588CrossRef
56.
Raharjo P, Ishizaki C, Ishizaki K (2000) Surface hydration states of high purity α-Al2O3 powders. J Ceram Soc Japan 108:449–455CrossRef
57.
Socrates G (2001) Infrared and raman characteristic group frequencies: tables and charts, 3rd edn. Wiley, New York
58.
Nakamoto K (1997) Infrared and raman spectra of inorganic and coordination compounds, 5th edn. Wiley, New York
59.
Silverstein RM, Webster FX, Kiemle DJ (1991) Spectrometric identification of organic compounds, 7th edn. Wiley, New York
60.
Gooβen LJ, Rodríguez N, Gooβen K (2008) Carboxylic acids as substrates in homogeneous catalysis. Angew Chemie Int Ed 47:3100–3120CrossRef
Metadaten
Titel
Identification of α-Al2O3 surface sites and their role in the adsorption of stearic acid
verfasst von
J. Webber
J. E. Zorzi
C. A. Perottoni
S. Moura e Silva
R. C. D. Cruz
Publikationsdatum
26.02.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 11/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-9819-5

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