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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 11/2012

01.11.2012 | Original Paper

Curing behavior and cured film performance of easy-to-clean UV-curable coatings based on hybrid urethane acrylate oligomers

verfasst von: Supranee Kaewpirom, Dapawan Kunwong

Erschienen in: Journal of Polymer Research | Ausgabe 11/2012

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Abstract

This study aims to prepare different formulations of UV-curable coatings based on hybrid urethane acrylate oligomers and to characterize their UV-cured films for application as easy-to-clean coatings. The effects of reactive monomer functionality and the oligomer structure on the reaction rate and extent of UV curing were investigated as well as on the cured films properties. The study began with the synthesis of two different hybrid urethane acrylate oligomers and their chemical structures were characterized by NMR and FT-IR. Six formulations of UV-curable coating were prepared by varying the type of urethane acrylate oligomers in addition to the type of reactive monomers, using 2,2-dimethoxy-2-phenyl acetophenone as a photoinitiator, methacrylic acid as a reactive diluent and 3-aminopropyltrimethoxysilane as a coupling agent. The UV curing process of such coatings was monitored by FT-IR and the C=C bond conversion was expressed. Finally, the weight loss, water contact angle, cross-cut adhesion and tensile properties of the UV-cured films were also investigated.
Vorheriger Artikel Preparation, tensile, damping and thermal properties of polyurethanes based on various structural polymer polyols: effects of composition and isocyanate index
Nächster Artikel Synthesis and characterization of ethylene-propylene copolymer and polyethylene using α-diimine nickel catalysts

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Metadaten
Titel
Curing behavior and cured film performance of easy-to-clean UV-curable coatings based on hybrid urethane acrylate oligomers
verfasst von
Supranee Kaewpirom
Dapawan Kunwong
Publikationsdatum
01.11.2012
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 11/2012
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-012-9995-1

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