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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 6/2013

01.06.2013 | Original Paper

Synthesis and properties of transparent polyimides derived from trans- and cis-1,4-bis(3,4-dicarboxyphenoxy)cyclohexane dianhydrides

verfasst von: Guofei Chen, Xueliang Pei, Jiangtao Liu, Xingzhong Fang

Erschienen in: Journal of Polymer Research | Ausgabe 6/2013

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Abstract

To get a transparent polyimide and investigate the isomeric effect of trans and cis configuration, two novel dianhydrides, trans- and cis-1,4-bis(3,4-dicarboxyphenoxy)cyclohexane dianhydrides were synthesized (trans-2 and cis-2), and polycondensations of the dianhydrides with different aromatic diamines containing trifluoromethyl group or meta-substituent were carried out by two-step procedure. The resulting polyimides had glass transition temperature (T g) in the range of 203–262 °C, and exhibited good mechanical properties with tensile strengths of 53–102 MPa, tensile moduli of 2.1–3.3 GPa, and elongations at break of 1.9–16.5 %. All semi-aromatic polyimide films showed high optical transparency in the visible region along with the cut-off wavelength of 369–375 nm due to the introduction of cyclohexane moiety into the main chain. Furthermore, compared with cis-2-based polyimides, the polyimides derived from trans-2 had higher T g, better chemical solvent resistance and mechanical properties. It could be attributed to the relatively denser polymer chain packing in trans-2 based polyimides, which was confirmed by wide-angle X-ray diffraction.
Vorheriger Artikel Calcium carbonate deposition on layer-by-layer systems assembled from star polymers
Nächster Artikel Light scattering and surface tensiometric studies of tip-modified PEO-PBO diblock copolymers in water

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Metadaten
Titel
Synthesis and properties of transparent polyimides derived from trans- and cis-1,4-bis(3,4-dicarboxyphenoxy)cyclohexane dianhydrides
verfasst von
Guofei Chen
Xueliang Pei
Jiangtao Liu
Xingzhong Fang
Publikationsdatum
01.06.2013
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 6/2013
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-013-0159-8

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