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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 12/2014

01.12.2014 | Original Paper

Synthesis of a bismaleimide/cyanate ester copolymer containing phenolphthalein functional group with excellent dielectric properties and thermally stable

verfasst von: Guanglei Wu, Yonghong Cheng, Qian Xie, Chang Liu, Kaichang Kou, Longhai Zhuo, Yiqun Wang

Erschienen in: Journal of Polymer Research | Ausgabe 12/2014

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Abstract

In this paper, a copolymer has been prepared with bismaleimide resin (BMI) and phenolphthalein cyanate ester resin (PPCE) which formed bismaleimide-triazine (BT) copolymer. PPCE is synthesized in cyanogens halide-phenol method, with the microstructure examined by fourier transmission infrared spectroscopy (FT-IR), 1H-NMR, 13C-NMR, and thermogravimetric analysis (TGA). The BMI/PPCE copolymer exhibits excellent mechanical properties and stable thermal properties when the content of BMI is 30 wt.%. And the moisture absorption of the blends is found to be small higher than PPCE resin. The dielectric properties of BMI/PPCE copolymer, such as dielectric constant and dielectric dissipation factor, show good stability over a wide frequency range from 10 to 60 MHz. In addition, the BMI/PPCE copolymer has a better thermal stability compared with PPCE resin with the increasing of BMI content.
Vorheriger Artikel Kinetics study of living microemulsion polymerization mediated by reversible addition-fragmentation chain transfer
Nächster Artikel Crystallization kinetics of γ phase poly(vinylidene fluoride)(PVDF) induecd by tetrabutylammonium bisulfate

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Metadaten
Titel
Synthesis of a bismaleimide/cyanate ester copolymer containing phenolphthalein functional group with excellent dielectric properties and thermally stable
verfasst von
Guanglei Wu
Yonghong Cheng
Qian Xie
Chang Liu
Kaichang Kou
Longhai Zhuo
Yiqun Wang
Publikationsdatum
01.12.2014
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 12/2014
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-014-0615-0

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