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Journal of Polymer Research

Erschienen in:

01.02.2017 | ORIGINAL PAPER

Synthesis and self-assembly behavior of POSS tethered amphiphilic polymer based on poly(caprolactone) (PCL) grafted with poly(acrylic acid) (PAA) via ROP, ATRP, and CuAAC reaction

verfasst von: Souvik Ata, Shyam Basak, Dipakranjan Mal, Nikhil K. Singha

Erschienen in: Journal of Polymer Research | Ausgabe 2/2017

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Abstract

This investigation reports the preparation and self-assembly behavior of polyhedral oligomeric silsesquioxane (POSS) containing poly(caprolactone)-graft-poly(acrylic acid) (POSS-PCL-graft-PAA) polymer. This article focuses on the self-assembly behavior of POSS tethered amphiphilic graft copolymer. In this investigation, POSS tethered alkyne functionalized polycaprolactone (PCL) was prepared by strategic ring opening polymerization (ROP) of ε-caprolactone and α-propargyl-ε-caprolactone using hydroxyl-terminated POSS as an initiator. Azide-terminated poly(tert-butyl acrylate) (P^tBA) was grafted onto functional PCL via Cu-catalyzed azide-alkyne “click” (CuAAC) reaction. Finally, hydrolysis of the tert-butyl ester group into acid furnished the POSS tethered PCL-graft-PAA polymer. This amphiphilic graft copolymer was characterized by GPC, NMR, and FT-IR analyses and the morphology of the graft copolymer analyzed by HRTEM and FESEM analyses. On changing the graft copolymer concentration (low to high) in water, the morphology of the final graft copolymer changed from micelles to worm-like and core-shell. The structural motif of POSS plays an important role in this morphological transformation. The pH sensitivity was studied using DLS analysis as well as via release profile of rhodamine B as a model compound.

Vorheriger Artikel Synergistic effects of shear flow and nucleating agents on the crystallization mechanisms of Poly (Lactic Acid)

Nächster Artikel Structural, morphological and magnetic characterization of metal-chitosan/poly (vinyl amine) complexes

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Titel: Synthesis and self-assembly behavior of POSS tethered amphiphilic polymer based on poly(caprolactone) (PCL) grafted with poly(acrylic acid) (PAA) via ROP, ATRP, and CuAAC reaction
verfasst von: Souvik Ata
Shyam Basak
Dipakranjan Mal
Nikhil K. Singha
Publikationsdatum: 01.02.2017
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 2/2017
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-016-1171-6

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