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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 5/2018

01.05.2018 | ORIGINAL PAPER

Plasticizers derived from cardanol: synthesis and plasticization properties for polyvinyl chloride(PVC)

verfasst von: Jie Chen, Zengshe Liu, Xiaoan Nie, Yonghong Zhou, Jianchun Jiang, Rex E. Murray

Erschienen in: Journal of Polymer Research | Ausgabe 5/2018

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Abstract

Two natural plasticizers derived from cardanol (CD), cardanol acetate (CA) and epoxidized cardanol acetate (ECA), were synthesized and characterized by 1H NMR and 13C NMR. The plasticizing effects of the obtained plasticizers on semi-rigid polyvinylchloride (PVC) formulations were also investigated. Two commercial phthalate ester plasticizers, dioctyl terephthalate (DOTP) and diisononyl phthalate (DINP), were used as controls. Mechanical and thermal properties, compatibility, thermal stability, microstructure, and workability were assessed by dynamic mechanical analysis (DMA), mechanical analysis, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and dynamic stability analysis, respectively. Results indicated that the natural plasticizer ECA had overallsuperior flexibility, compatibility, thermal stability, and workability comparable to both controls. The obtained CA and ECA have lower volatility resistance and similar extraction and exudation resistance than that of DOTP and DINP. The CA was further blended with DOTP in soft PVC films. Results of DMA, TGA and mechanicalanalysis indicated that CA can serve as a secondary plasticizer to improve the related properties of soft PVC formulations. These CD derived plasticizers show promise as an alternative to fully or partially replace petroleum-based plasticizers.
Vorheriger Artikel Chemically modified babassu coconut (Orbignya sp.) biopolymer: characterization and development of a thin film for its application in electrochemical sensors
Nächster Artikel Facile fabrication of hollow polyaniline spheres and its application in supercapacitor

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Metadaten
Titel
Plasticizers derived from cardanol: synthesis and plasticization properties for polyvinyl chloride(PVC)
verfasst von
Jie Chen
Zengshe Liu
Xiaoan Nie
Yonghong Zhou
Jianchun Jiang
Rex E. Murray
Publikationsdatum
01.05.2018
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 5/2018
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-018-1524-4

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