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Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 3/2018

02.08.2018 | Original Paper: Sol–gel, hybrids, and solution chemistries

Zinc–diethanolamine complex: synthesis, characterization, and formation mechanism of zinc oxide via thermal decomposition

verfasst von: Ryohei Hayami, Nagato Endo, Takayuki Abe, Yuta Miyase, Takuya Sagawa, Kazuki Yamamoto, Satoru Tsukada, Takahiro Gunji

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 3/2018

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Abstract

Zn(OAc)2(H2DEA) was synthesized by the reaction of zinc acetate dihydrate (Zn(OAc)2•2H2O) with diethanolamine (H2DEA), and was characterized using single-crystal X-ray structural analysis, nuclear magnetic resonance spectroscopy, Fourier-transform infrared (FT-IR) spectroscopy, and elemental analysis. Zn(OAc)2(H2DEA) had a trigonal bipyramidal geometry comprised of one zinc atom, two acetate groups, and one H2DEA as a neutral tridentate ligand to form two five-membered rings. The states of Zn(OAc)2(H2DEA) heated at various temperatures were determined by FT-IR spectroscopy. At 270 °C, the H2DEA ligand dissociated and was removed. The absorption bands assigned to Zn–O stretching vibration of Zn4O core such as the zinc-oxo cluster appeared. When heated at 500 °C, the absorption bands of μ4-oxozincate and the acetate group disappeared completely and hexagonal wurtzite structural ZnO was formed at 550 °C. A possible thermal decomposition pathway from Zn(OAc)2(H2DEA) to ZnO was proposed. The ZnO film was highly transparent and formed by the deposition of ZnO nanoparticles with size ~40 nm.
Vorheriger Artikel Synthesis of high temperature resistant ZrO2-SiO2 composite aerogels via “thiol-ene” click reaction
Nächster Artikel Superhydrophilic and superhydrophobic surface from raspberry-like PMMA/M-SiO2 nanocomposite microspheres with dual-level hierarchical structure

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Metadaten
Titel
Zinc–diethanolamine complex: synthesis, characterization, and formation mechanism of zinc oxide via thermal decomposition
verfasst von
Ryohei Hayami
Nagato Endo
Takayuki Abe
Yuta Miyase
Takuya Sagawa
Kazuki Yamamoto
Satoru Tsukada
Takahiro Gunji
Publikationsdatum
02.08.2018
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 3/2018
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-018-4768-x

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