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01.07.2013 | Research Paper

Fabrication of CoNi alloy hollow-nanostructured microspheres for hydrogen storage application

verfasst von: M. Yasir Rafique, Liqing Pan, M. Zubair Iqbal, Rafi-ud-din, Hongmei Qiu, M. Hassan Farooq, Zhengang Guo, Mujtaba Ellahi

Erschienen in: Journal of Nanoparticle Research | Ausgabe 7/2013

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Abstract

Co₂₀Ni₈₀ hollow-nanostructured microspheres are prepared by template-free hydrothermal method at low temperature (150 °C). The prepared CoNi nanostructures have face-centered cubic crystal lattice. Williamson–Hall analysis shows crystallite size of 55.5 nm and microstrain of 0.00265. Elemental mapping confirms the uniform distribution of Co and Ni atoms in sample. The size of hollow spheres is in the range of 1–3 μm which increase to 10 μm by increasing the reaction time. A stepwise growth mechanism based on time-dependent experiment is briefly described. The X-ray photoelectron spectroscopy analysis suggests the only metallic chemical state of Co and Ni in sample (no surface oxidation). The specific surface area of 80.56 m²/g is obtained for 2 μm hollow sphere. The Co₂₀Ni₈₀ hollow-nanostructured microsphere shows 0.92 mass% hydrogen absorption and 81 % release of stored hydrogen. Hydrogen storage is attributed to crystal defects. The effects of morphology and surface area on hydrogen storage capacity and response are described. The saturation magnetization of 72.1 emu/g and coercivity of 157.21 Oe are observed for 2 μm hollow spheres. However, saturation magnetization of 77.5 emu/g and coercivity of 120 Oe are observed for 10 μm hollow spheres. The enhanced coercivity is related to surface and shape anisotropy due to hollow structure.

Vorheriger Artikel Hydrothermal preparation of hydrophobic and hydrophilic nanoparticles of iron oxide and a modification with CM-dextran

Nächster Artikel Human serum albumin interactions with C60 fullerene studied by spectroscopy, small-angle neutron scattering, and molecular dynamics simulations

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Titel: Fabrication of CoNi alloy hollow-nanostructured microspheres for hydrogen storage application
verfasst von: M. Yasir Rafique
Liqing Pan
M. Zubair Iqbal
Rafi-ud-din
Hongmei Qiu
M. Hassan Farooq
Zhengang Guo
Mujtaba Ellahi
Publikationsdatum: 01.07.2013
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 7/2013
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-013-1768-1

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