Skip to main content
Erschienen in: Optical and Quantum Electronics 2/2016

01.02.2016

Optical and structural properties of TiO2 nanopowders with Co/Ce doping at various temperature

verfasst von: Nasrollah Najibi Ilkhechi, Mahnaz Alijani, Behzad Koozegar Kaleji

Erschienen in: Optical and Quantum Electronics | Ausgabe 2/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In this study, preparation of 2 mol% Ce and 4 mol% Co doped TiO2 nanopowders via sol–gel process have been investigated. The effects of Co and Ce doping and calcination temperature (475–1000 °C) on the structural and optical properties of titania nanopowders studied by X-ray diffraction (XRD), scanning electron microscope, transmission electron microscope and UV–Vis absorption spectroscope. XRD results showed that, Titania rutile phase formation in ternary system (Ti–Co–Ce) was inhibited by Ce4+ and promoted by Co4+ co-doped TiO2 in high temperatures (500–700 °C) and 61 mol% anatase composition is retained even after calcination at 800 °C. The optical absorption spectrum indicates that the TiO2 nanoparticles have a direct band gap of 3.21 eV. But optical band gap of the doped TiO2 (2 mol% Ce and 4 mol% Co) was found to be 3.14–3.20 eV.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Wirtschaft"

Online-Abonnement

Mit Springer Professional "Wirtschaft" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 340 Zeitschriften

aus folgenden Fachgebieten:

  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Versicherung + Risiko




Jetzt Wissensvorsprung sichern!

Literatur
Zurück zum Zitat Bouras, P., Slathatos, E., Lianos, P.: Pure versus metal-ion-doped nanocrystalline titania for photocatalysis. Appl. Catal. B Environ. 73, 51–59 (2007)CrossRef Bouras, P., Slathatos, E., Lianos, P.: Pure versus metal-ion-doped nanocrystalline titania for photocatalysis. Appl. Catal. B Environ. 73, 51–59 (2007)CrossRef
Zurück zum Zitat Caimei, F., Peng, X., Yanping, S.: Preparation of nano-TiO2 doped with cerium and its photocatalytic activity. J. Rare Earth 24, 309–313 (2006)CrossRef Caimei, F., Peng, X., Yanping, S.: Preparation of nano-TiO2 doped with cerium and its photocatalytic activity. J. Rare Earth 24, 309–313 (2006)CrossRef
Zurück zum Zitat Cao, Y., He, T., Zhao, L., Wang, E., Yang, W., Cao, Y.: Structure and phase transition behavior of Sn4+-doped TiO2 nanoparticles. J. Phys. Chem. C 113, 18121–18124 (2009)CrossRef Cao, Y., He, T., Zhao, L., Wang, E., Yang, W., Cao, Y.: Structure and phase transition behavior of Sn4+-doped TiO2 nanoparticles. J. Phys. Chem. C 113, 18121–18124 (2009)CrossRef
Zurück zum Zitat Chen, X., Mao, S.S.: Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem. Rev. 107, 2891–2959 (2007)CrossRef Chen, X., Mao, S.S.: Titanium dioxide nanomaterials: synthesis, properties, modifications, and applications. Chem. Rev. 107, 2891–2959 (2007)CrossRef
Zurück zum Zitat Fujishima, A., Honda, K.: Photolysis-decomposition of water at the surface of an irradiated semiconductor. Nature 238, 37–38 (1972)CrossRefADS Fujishima, A., Honda, K.: Photolysis-decomposition of water at the surface of an irradiated semiconductor. Nature 238, 37–38 (1972)CrossRefADS
Zurück zum Zitat Fukumura, T., Yamada, Y., Toyosaky, H., Hasegawa, T., Koinuma, H., Kawasaki, M.: Exploration of oxide-based diluted magnetic semiconductors toward transparent spintronics. Appl. Surf. Sci. 223, 62 (2004)CrossRefADS Fukumura, T., Yamada, Y., Toyosaky, H., Hasegawa, T., Koinuma, H., Kawasaki, M.: Exploration of oxide-based diluted magnetic semiconductors toward transparent spintronics. Appl. Surf. Sci. 223, 62 (2004)CrossRefADS
Zurück zum Zitat Gopal, M., Chan, W., Jonghe, L.: Room temperature synthesis of crystalline metal oxides. J. Mater. Sci. 32, 6001–6008 (1997)CrossRefADS Gopal, M., Chan, W., Jonghe, L.: Room temperature synthesis of crystalline metal oxides. J. Mater. Sci. 32, 6001–6008 (1997)CrossRefADS
Zurück zum Zitat Hoffmann, M.R., Martin, S.T., Choi, W., Bahnemann, D.W.: Environmental applications of semiconductor photocatalysis. Chem. Rev. 95, 69–96 (1995)CrossRef Hoffmann, M.R., Martin, S.T., Choi, W., Bahnemann, D.W.: Environmental applications of semiconductor photocatalysis. Chem. Rev. 95, 69–96 (1995)CrossRef
Zurück zum Zitat Janisch, R., Gopal, P., Spaldin, N.A.: Transition metal-doped TiO2 and ZnO—present status of the field. J. Phys.: Condens. Matter 17, R657 (2005)ADS Janisch, R., Gopal, P., Spaldin, N.A.: Transition metal-doped TiO2 and ZnO—present status of the field. J. Phys.: Condens. Matter 17, R657 (2005)ADS
Zurück zum Zitat Jin, Z., Zhang, X., Li, Y., Li, S., Lu, G.: 5.1 % Apparent quantum efficiency for stable hydrogen generation over eosin-sensitized CuO/TiO2 photocatalyst under visible light irradiation. Catal. Commun. 8, 1267–1273 (2007)CrossRef Jin, Z., Zhang, X., Li, Y., Li, S., Lu, G.: 5.1 % Apparent quantum efficiency for stable hydrogen generation over eosin-sensitized CuO/TiO2 photocatalyst under visible light irradiation. Catal. Commun. 8, 1267–1273 (2007)CrossRef
Zurück zum Zitat Klug, P., Alexander, L.E.: X-Ray Diffraction Procedures. Wiley, New York (1974) Klug, P., Alexander, L.E.: X-Ray Diffraction Procedures. Wiley, New York (1974)
Zurück zum Zitat Kostov, I.: The mineralogical knowledge of the ancient bulgarians according to some medieval sources. Annual vol. 46, part І, рр.87–92. Geology and Geophysics, Sofia, 2003 (1973) Kostov, I.: The mineralogical knowledge of the ancient bulgarians according to some medieval sources. Annual vol. 46, part І, рр.87–92. Geology and Geophysics, Sofia, 2003 (1973)
Zurück zum Zitat Kubacka, A., Fuerte, A., Martinez-Arias, A., Fernandez-Garcia, M.: Nanosized Ti–V mixed oxides: effect of doping level in the photo-catalytic degradation of toluene using sunlight-type excitation. Appl. Catal. B Environ. 74, 26–33 (2007)CrossRef Kubacka, A., Fuerte, A., Martinez-Arias, A., Fernandez-Garcia, M.: Nanosized Ti–V mixed oxides: effect of doping level in the photo-catalytic degradation of toluene using sunlight-type excitation. Appl. Catal. B Environ. 74, 26–33 (2007)CrossRef
Zurück zum Zitat Kudo, A.: Recent progress in the development of visible light-driven powdered photocatalysts for water splitting. Int. J. Hydrogen Energy 32, 2673–2678 (2007)CrossRef Kudo, A.: Recent progress in the development of visible light-driven powdered photocatalysts for water splitting. Int. J. Hydrogen Energy 32, 2673–2678 (2007)CrossRef
Zurück zum Zitat Li, F.B., Li, X.Z., Hou, M.F., Cheah, K.W., Choy, W.C.H.: Enhanced photocatalytic activity of Ce3+–TiO2 for 2-mercaptobenzothiazole degradation in aqueous suspension for odour control. Appl. Catal. A Gen. 285, 181–189 (2005)CrossRef Li, F.B., Li, X.Z., Hou, M.F., Cheah, K.W., Choy, W.C.H.: Enhanced photocatalytic activity of Ce3+–TiO2 for 2-mercaptobenzothiazole degradation in aqueous suspension for odour control. Appl. Catal. A Gen. 285, 181–189 (2005)CrossRef
Zurück zum Zitat Mark H.F., Othmer D.F., Overberger C.G., Seaberg, G.T.: Encyclopedia of Chemical Technology, vol. 23, Wiley, New York (1983) Mark H.F., Othmer D.F., Overberger C.G., Seaberg, G.T.: Encyclopedia of Chemical Technology, vol. 23, Wiley, New York (1983)
Zurück zum Zitat Ohko, Y., Fujishima, A., Hashimoto, K.: Kinetic analysis of the photocatalytic degradation of gas-phase 2-propanol under mass transport-limited conditions with a TiO2 film photocatalyst. J. Phys. Chem. B 102, 1724–1729 (1998)CrossRef Ohko, Y., Fujishima, A., Hashimoto, K.: Kinetic analysis of the photocatalytic degradation of gas-phase 2-propanol under mass transport-limited conditions with a TiO2 film photocatalyst. J. Phys. Chem. B 102, 1724–1729 (1998)CrossRef
Zurück zum Zitat Palmer, F.L., Eggins, B.R.: The effect of operational parameters on the photocatalytic degradation of humic acid. J. Photochem. Photobiol. 148, 137–143 (2002)CrossRef Palmer, F.L., Eggins, B.R.: The effect of operational parameters on the photocatalytic degradation of humic acid. J. Photochem. Photobiol. 148, 137–143 (2002)CrossRef
Zurück zum Zitat Paola, A.D., Garcı´a-Lo´ pez, E., Ikeda, S., Marcı`, G., Ohtani, B., Palmisano, L.: Photocatalytic degradation of organic compounds in aqueous systems by transition metal doped polycrystalline TiO2. Catal. Today 75, 87–93 (2002)CrossRef Paola, A.D., Garcı´a-Lo´ pez, E., Ikeda, S., Marcı`, G., Ohtani, B., Palmisano, L.: Photocatalytic degradation of organic compounds in aqueous systems by transition metal doped polycrystalline TiO2. Catal. Today 75, 87–93 (2002)CrossRef
Zurück zum Zitat Rajeshwar, K., Tacconi, N.R., Chenthamarakshan, C.R.: Semiconductor-based composite materials: preparation, properties, and performance. Chem. Mater. 13, 2765–2782 (2001)CrossRef Rajeshwar, K., Tacconi, N.R., Chenthamarakshan, C.R.: Semiconductor-based composite materials: preparation, properties, and performance. Chem. Mater. 13, 2765–2782 (2001)CrossRef
Zurück zum Zitat Shinde, S.R., Ogale, S.B., Das Sarma, S., Simpson, J.R., Drew, H.D., Lofland, S.E., Lanci, C., Buban, J.P., Browning, N.D., Kulkarmi, V.N., Higgins, J., Sharma, R.P., Green, R.L., Venkatesan, T.: Ferromagnetism in laser deposited anatase Ti1−x Cox O2−δ films. Phys. Rev. B 67, 115211 (2003)CrossRefADS Shinde, S.R., Ogale, S.B., Das Sarma, S., Simpson, J.R., Drew, H.D., Lofland, S.E., Lanci, C., Buban, J.P., Browning, N.D., Kulkarmi, V.N., Higgins, J., Sharma, R.P., Green, R.L., Venkatesan, T.: Ferromagnetism in laser deposited anatase Ti1−x Cox O2−δ films. Phys. Rev. B 67, 115211 (2003)CrossRefADS
Zurück zum Zitat Stengl, V., Bakardjieva, S., Murafa, N.: Preparation and photocatalytic activity of rare earth doped TiO2 nanoparticles. Mater. Chem. Phys. 114, 217–226 (2009)CrossRef Stengl, V., Bakardjieva, S., Murafa, N.: Preparation and photocatalytic activity of rare earth doped TiO2 nanoparticles. Mater. Chem. Phys. 114, 217–226 (2009)CrossRef
Zurück zum Zitat Wang, C.Y., Liu, C.Y., Shen, T.: The photocatalytic oxidation of phenylmercaptotetrazole in TiO2 dispersions. J. Photochem. Photobiol. A Chem. 109, 65–70 (1997)CrossRef Wang, C.Y., Liu, C.Y., Shen, T.: The photocatalytic oxidation of phenylmercaptotetrazole in TiO2 dispersions. J. Photochem. Photobiol. A Chem. 109, 65–70 (1997)CrossRef
Zurück zum Zitat Weast, R.C.: Handbook of Chemistry and Physics, pp. B–154–B–155. CRC Press, Boca Raton (1984) Weast, R.C.: Handbook of Chemistry and Physics, pp. B–154–B–155. CRC Press, Boca Raton (1984)
Zurück zum Zitat Xie, Y., Yuan, C.: Photocatalysis of neodymium ion modified TiO2 sol under visible light irradiation. Appl. Surf. Sci. 221, 17–24 (2004)CrossRefADS Xie, Y., Yuan, C.: Photocatalysis of neodymium ion modified TiO2 sol under visible light irradiation. Appl. Surf. Sci. 221, 17–24 (2004)CrossRefADS
Zurück zum Zitat Yan, Q.Z., Su, X.T., Huang, Z.Y., Ge, C.C.: Sol–gel auto-igniting synthesis and structural property of cerium-doped titanium dioxide nanosized powders. J. Eur. Ceram. Soc. 26, 915–921 (2006)CrossRef Yan, Q.Z., Su, X.T., Huang, Z.Y., Ge, C.C.: Sol–gel auto-igniting synthesis and structural property of cerium-doped titanium dioxide nanosized powders. J. Eur. Ceram. Soc. 26, 915–921 (2006)CrossRef
Zurück zum Zitat Zhang, X., Liu, Q.Q.: Preparation and characterization of titania photocatalyst co-doped with boron, nickel, and cerium. Mater. Lett. 62, 2589–2592 (2008)CrossRef Zhang, X., Liu, Q.Q.: Preparation and characterization of titania photocatalyst co-doped with boron, nickel, and cerium. Mater. Lett. 62, 2589–2592 (2008)CrossRef
Metadaten
Titel
Optical and structural properties of TiO2 nanopowders with Co/Ce doping at various temperature
verfasst von
Nasrollah Najibi Ilkhechi
Mahnaz Alijani
Behzad Koozegar Kaleji
Publikationsdatum
01.02.2016
Verlag
Springer US
Erschienen in
Optical and Quantum Electronics / Ausgabe 2/2016
Print ISSN: 0306-8919
Elektronische ISSN: 1572-817X
DOI
https://doi.org/10.1007/s11082-016-0435-z

Weitere Artikel der Ausgabe 2/2016

Optical and Quantum Electronics 2/2016 Zur Ausgabe

Neuer Inhalt