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Topics in Catalysis
Erschienen in: Topics in Catalysis 14-17/2015

01.10.2015 | Original Paper

Photocatalytic Degradation of Organic Pollutants in Wastewater

verfasst von: Minna Pirilä, Mohammed Saouabe, Satu Ojala, Buddhika Rathnayake, Fabien Drault, Anna Valtanen, Mika Huuhtanen, Rachid Brahmi, Riitta L. Keiski

Erschienen in: Topics in Catalysis | Ausgabe 14-17/2015

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Abstract

Even today the efficient treatment of industrial wastewaters is not evident. The effluents may contain large amounts of harmful organic compounds that are not easily removed with conventional methods. This study focuses on the photocatalytic treatment of four organic pollutants originated from different types of industry. The pollutants are diuron (herbicide), p-coumaric acid (agro-industrial wastewater), bisphenol A and phthalic anhydride (plasticizers), which all are widely used and cause significant health and environmental problems. To get deeper understanding, the photocatalytic degradation of the model molecules was studied both in synthetic solutions and in industrial wastewater matrix over TiO2 P25 in two different batch photoreactors under UV-A irradiation. The effects of catalyst loading, pH and initial concentration were studied. To gain understanding on the reactivity of molecules and costs of treatment, the kinetic modelling and energy modelling were compared and the specific applied energy (ESAE) was estimated. ESAE is proposed as a useful value to estimate the energy needed to degrade one mole of pollutant and further to calculate the operating costs to treat the wastewater. Of the model pollutants, diuron was removed the most efficiently and its removal consumed the least amount of energy in terms of the specific applied energy. Bisphenol A was found to be the most difficult to be removed by photocatalysis. The industrial wastewater matrix affected negatively the removal results.
Vorheriger Artikel Aromatic Alcohols as Model Molecules for Studying Hydrogenolysis Reactions Promoted by Palladium Catalysts
Nächster Artikel Microwave-Assisted Synthesis of BiOBr Microspheres for Photocatalytic Degradation of Tartaric Acids in Aqueous Solution

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Metadaten
Titel
Photocatalytic Degradation of Organic Pollutants in Wastewater
verfasst von
Minna Pirilä
Mohammed Saouabe
Satu Ojala
Buddhika Rathnayake
Fabien Drault
Anna Valtanen
Mika Huuhtanen
Rachid Brahmi
Riitta L. Keiski
Publikationsdatum
01.10.2015
Verlag
Springer US
Erschienen in
Topics in Catalysis / Ausgabe 14-17/2015
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-015-0477-7

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