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Erschienen in: Journal of Coatings Technology and Research 4/2007

01.12.2007

Combinatorial approach to study the effect of acrylic polyol composition on the properties of crosslinked siloxane-polyurethane fouling-release coatings

verfasst von: Robert J. Pieper, Abdullah Ekin, Dean C. Webster, Franck Cassé, James A. Callow, Maureen E. Callow

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 4/2007

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Abstract

The effect of acrylic polyol composition on the properties of crosslinked siloxane-polyurethane coatings was explored. An acrylic polyol library was synthesized using batch solution polymerization and characterized using high-throughput gel permeation chromatography (Rapid-GPC) and differential scanning calorimetry (DSC). Siloxane-polyurethane coatings were prepared from 3-aminopropyl-terminated poly(dimethylsiloxane) (PDMS), the acrylic polyols and a polyisocyanate crosslinker. The siloxane-acrylic-polyurethane coatings were tested for mechanical and physical properties. The siloxane-polyurethane coatings had a systematic variation in glass transition temperature and had water contact angles ranging from 95° to 100°. Many of the coatings also showed a low-force of release in the pseudo-barnacle pull-off adhesion test. Performance testing of the fouling-release properties of the siloxane-polyurethane coatings on array panels with algae, namely the diatom Navicula and sporelings (young plants) of the green seaweed Ulva was also conducted.

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Literatur
1.
Zurück zum Zitat Callow, ME, Callow, JE, Marine Biofouling: A Sticky Problem. Biologist (London, England) 49 (1) 10–14 (2002) Callow, ME, Callow, JE, Marine Biofouling: A Sticky Problem. Biologist (London, England) 49 (1) 10–14 (2002)
2.
Zurück zum Zitat Champ, MA, A Review of Organotin Regulatory Strategies, Pending Actions, Related Costs and Benefits. Sci. Total Environ. 258 21 (2000)CrossRef Champ, MA, A Review of Organotin Regulatory Strategies, Pending Actions, Related Costs and Benefits. Sci. Total Environ. 258 21 (2000)CrossRef
3.
Zurück zum Zitat Brady, RF, Properties which Influence Marine Fouling Resistance in Polymers Containing Silicon and Fluorine. Prog. Org. Coat. 35 (1–4) 31–35 (1999)CrossRef Brady, RF, Properties which Influence Marine Fouling Resistance in Polymers Containing Silicon and Fluorine. Prog. Org. Coat. 35 (1–4) 31–35 (1999)CrossRef
4.
Zurück zum Zitat Brady, RF Jr, Singer, IL, Mechanical Factors Favoring Release from Fouling Release Coatings. Biofouling 15 (1–3) 73–81 (2000) Brady, RF Jr, Singer, IL, Mechanical Factors Favoring Release from Fouling Release Coatings. Biofouling 15 (1–3) 73–81 (2000)
5.
Zurück zum Zitat Yebra, DM, Kiil, S, Dam-Johansen, K, Antifouling Technology—Past, Present and Future Steps Towards Efficient and Environmentally Friendly Antifouling Coatings. Prog. Org. Coat. 50 (2) 75–104 (2004)CrossRef Yebra, DM, Kiil, S, Dam-Johansen, K, Antifouling Technology—Past, Present and Future Steps Towards Efficient and Environmentally Friendly Antifouling Coatings. Prog. Org. Coat. 50 (2) 75–104 (2004)CrossRef
6.
Zurück zum Zitat Candries, M, Atlar, M, Anderson, CD, “Considering the Use of Alternative Antifoulings: The Advantages of Foul-Release Systems.” Conference Proceedings ENSUS, pp. 88–95 (2000) Candries, M, Atlar, M, Anderson, CD, “Considering the Use of Alternative Antifoulings: The Advantages of Foul-Release Systems.” Conference Proceedings ENSUS, pp. 88–95 (2000)
7.
Zurück zum Zitat Majumdar, P, Ekin, A, Webster, DC, Thermoset Siloxane-Urethane Fouling Release Coatings. ACS Symp. Ser. 957 61–75 (2007)CrossRef Majumdar, P, Ekin, A, Webster, DC, Thermoset Siloxane-Urethane Fouling Release Coatings. ACS Symp. Ser. 957 61–75 (2007)CrossRef
8.
Zurück zum Zitat Verkholantsev, V, Flavian, M, Polymer Structure and Properties of Heterophase and Self-Stratifying Coatings. Prog. Org. Coat. 29 (1–4) 239–246 (1996)CrossRef Verkholantsev, V, Flavian, M, Polymer Structure and Properties of Heterophase and Self-Stratifying Coatings. Prog. Org. Coat. 29 (1–4) 239–246 (1996)CrossRef
9.
Zurück zum Zitat Vink, P, Bots, TL, Formulation Parameters Influencing Self-Stratification of Coatings. Prog. Org. Coat. 28 (3) 173–181 (1996)CrossRef Vink, P, Bots, TL, Formulation Parameters Influencing Self-Stratification of Coatings. Prog. Org. Coat. 28 (3) 173–181 (1996)CrossRef
10.
Zurück zum Zitat Benjamin, S, Carr, C, Walbridge, DJ, Self-Stratifying Coatings for Metallic Substrates. Prog. Org. Coat. 28 (3) 197–207 (1996)CrossRef Benjamin, S, Carr, C, Walbridge, DJ, Self-Stratifying Coatings for Metallic Substrates. Prog. Org. Coat. 28 (3) 197–207 (1996)CrossRef
11.
Zurück zum Zitat Carr, C, Wallstoem, E, Theoretical Aspects of Self-Stratification. Prog. Org. Coat. 28 (3) 161–171 (1996)CrossRef Carr, C, Wallstoem, E, Theoretical Aspects of Self-Stratification. Prog. Org. Coat. 28 (3) 161–171 (1996)CrossRef
12.
Zurück zum Zitat Walbridge, DJ, Self-Stratifying Coatings—An Overview of a European Community Research Project. Prog. Org. Coat. 28 (3) 155–159 (1996)CrossRef Walbridge, DJ, Self-Stratifying Coatings—An Overview of a European Community Research Project. Prog. Org. Coat. 28 (3) 155–159 (1996)CrossRef
13.
Zurück zum Zitat Ekin, A, Webster, DC, Library Synthesis and Characterization of 3-aminopropyl-terminated poly(dimethylsiloxane)s and poly(e-caprolactone)-b-poly(dimethylsiloxane)s. J. Polym. Sci., Part A: Polym. Chem. 44 (16) 4880–4894 (2006)CrossRef Ekin, A, Webster, DC, Library Synthesis and Characterization of 3-aminopropyl-terminated poly(dimethylsiloxane)s and poly(e-caprolactone)-b-poly(dimethylsiloxane)s. J. Polym. Sci., Part A: Polym. Chem. 44 (16) 4880–4894 (2006)CrossRef
14.
Zurück zum Zitat Ekin, A, Webster, DC, Combinatorial and High-Throughput Screening of the Effect of Siloxane Composition on the Surface Properties of Crosslinked Siloxane-Polyurethane Coatings. J. Combin. Chem. 9 (1) 178–188 (2007)CrossRef Ekin, A, Webster, DC, Combinatorial and High-Throughput Screening of the Effect of Siloxane Composition on the Surface Properties of Crosslinked Siloxane-Polyurethane Coatings. J. Combin. Chem. 9 (1) 178–188 (2007)CrossRef
15.
Zurück zum Zitat Ekin, A, Webster, DC, Daniels, J, Stafslien, SJ, Casse, F, Callow, JA, Callow, ME, “Synthesis, Formulation and Characterization of Siloxane-Polyurethane Coatings for Underwater Marine Applications Using Combinatorial High-Throughput Experimentation.” J. Coat. Technol. Res., (2007), doi: 10.1007/s11998-007-9039-7 Ekin, A, Webster, DC, Daniels, J, Stafslien, SJ, Casse, F, Callow, JA, Callow, ME, “Synthesis, Formulation and Characterization of Siloxane-Polyurethane Coatings for Underwater Marine Applications Using Combinatorial High-Throughput Experimentation.” J. Coat. Technol. Res., (2007), doi: 10.1007/s11998-007-9039-7
16.
Zurück zum Zitat Ekin, A, Webster, DC, Synthesis and Characterization of Novel Hydroxyalkyl Carbamate and Dihydroxyalkyl Carbamate Terminated Poly(dimethylsiloxane) Oligomers and their Block Copolymers with Poly(ε-caprolactone). Macromolecules 39 8659–8668 (2006)CrossRef Ekin, A, Webster, DC, Synthesis and Characterization of Novel Hydroxyalkyl Carbamate and Dihydroxyalkyl Carbamate Terminated Poly(dimethylsiloxane) Oligomers and their Block Copolymers with Poly(ε-caprolactone). Macromolecules 39 8659–8668 (2006)CrossRef
17.
Zurück zum Zitat Brady, RF, A Fracture Mechanical Analysis of Fouling Release from Nontoxic Antifouling Coatings. Prog. Org. Coat. 43 (1–3) 188–192 (2001)CrossRef Brady, RF, A Fracture Mechanical Analysis of Fouling Release from Nontoxic Antifouling Coatings. Prog. Org. Coat. 43 (1–3) 188–192 (2001)CrossRef
18.
Zurück zum Zitat Chaudhury, MK, Finlay, JA, Chung, JY, Callow, ME, Callow, JA, The Influence of Elastic Modulus and Thickness on the Release of the Soft-Fouling Green Alga Ulva linza (syn. Enteromorpha linza) from poly(dimethylsiloxane) (PDMS) Model Networks. Biofouling 21 (1) 41–48 (2005)CrossRef Chaudhury, MK, Finlay, JA, Chung, JY, Callow, ME, Callow, JA, The Influence of Elastic Modulus and Thickness on the Release of the Soft-Fouling Green Alga Ulva linza (syn. Enteromorpha linza) from poly(dimethylsiloxane) (PDMS) Model Networks. Biofouling 21 (1) 41–48 (2005)CrossRef
19.
Zurück zum Zitat Kohl, JG, Singer, IL, Pull-Off Behavior of Epoxy Bonded to Silicone Duplex Coatings. Prog. Org. Coat. 36 (1–2) 15–20 (1999)CrossRef Kohl, JG, Singer, IL, Pull-Off Behavior of Epoxy Bonded to Silicone Duplex Coatings. Prog. Org. Coat. 36 (1–2) 15–20 (1999)CrossRef
20.
Zurück zum Zitat Singer, IL, Kohl, JG, Patterson, M, Mechanical Aspects of Silicone Coatings for Hard Foulant Control. Biofouling 16 (2–4) 301–309 (2000)CrossRef Singer, IL, Kohl, JG, Patterson, M, Mechanical Aspects of Silicone Coatings for Hard Foulant Control. Biofouling 16 (2–4) 301–309 (2000)CrossRef
21.
Zurück zum Zitat Wicks, ZW, Jones, FN, Pappas, SP, Organic Coatings: Science and Technology, 2nd Edition. Wiley, NY (1999) Wicks, ZW, Jones, FN, Pappas, SP, Organic Coatings: Science and Technology, 2nd Edition. Wiley, NY (1999)
22.
Zurück zum Zitat Cassé, F, Ribeiro, E, Ekin, A, Webster, DC, Callow, JA, Callow, ME, “Laboratory Screening of Coating Libraries for Algal Adhesion.” Biofouling, 23 (2007) (in press) Cassé, F, Ribeiro, E, Ekin, A, Webster, DC, Callow, JA, Callow, ME, “Laboratory Screening of Coating Libraries for Algal Adhesion.” Biofouling, 23 (2007) (in press)
23.
Zurück zum Zitat Holland, R, Dugdale, TM, Wetherbee, R, Brennan, AB, Finlay, JA, Callow, JA, Callow, M, Adhesion and Motility of Fouling Diatoms on a Silicone Elastomer. Biofouling 20 (6) 323–329 (2004)CrossRef Holland, R, Dugdale, TM, Wetherbee, R, Brennan, AB, Finlay, JA, Callow, JA, Callow, M, Adhesion and Motility of Fouling Diatoms on a Silicone Elastomer. Biofouling 20 (6) 323–329 (2004)CrossRef
24.
Zurück zum Zitat Cassé, F, Stafslien, SJ, Bahr, JA, Daniels, J, Finlay, JA, Callow, JA, Callow, ME, Combinatorial Materials Research Applied to the Development of New Surfaces Coatings V. Application of a Spinning Water-Jet for the Semi-High Throughput Assessment of the Attachment Strength of Marine Fouling Algae. Biofouling 23 (2) 121–130 (2007)CrossRef Cassé, F, Stafslien, SJ, Bahr, JA, Daniels, J, Finlay, JA, Callow, JA, Callow, ME, Combinatorial Materials Research Applied to the Development of New Surfaces Coatings V. Application of a Spinning Water-Jet for the Semi-High Throughput Assessment of the Attachment Strength of Marine Fouling Algae. Biofouling 23 (2) 121–130 (2007)CrossRef
25.
Zurück zum Zitat Webster, DC, Bennett, J, Kuebler, S, Kossuth, MB, Jonasdottir, S, High Throughput Workflow for the Development of Coatings. JCT CoatingsTech. 1 (6) 34–39 (2004) Webster, DC, Bennett, J, Kuebler, S, Kossuth, MB, Jonasdottir, S, High Throughput Workflow for the Development of Coatings. JCT CoatingsTech. 1 (6) 34–39 (2004)
26.
Zurück zum Zitat Kossuth, MB, Hajduk, DA, Freitag, C, Varni, J, Parallel Dynamic Thermomechanical Measurements of Polymer Libraries. Macromol. Rapid Commun. 25 (1) 243–248 (2004)CrossRef Kossuth, MB, Hajduk, DA, Freitag, C, Varni, J, Parallel Dynamic Thermomechanical Measurements of Polymer Libraries. Macromol. Rapid Commun. 25 (1) 243–248 (2004)CrossRef
27.
Zurück zum Zitat Owens, DK, Wendt, RC, Estimation of the Surface Free Energy of Polymers. J. Appl. Polym. Sci. 13 (8) 1741–1747 (1969)CrossRef Owens, DK, Wendt, RC, Estimation of the Surface Free Energy of Polymers. J. Appl. Polym. Sci. 13 (8) 1741–1747 (1969)CrossRef
28.
Zurück zum Zitat Chisholm, BJ, Webster, DC, Bennett, JW, Berry, M, Christianson, DA, Kim, J, Mayo, B, Gubbins, NJ, “An Automated System for Adhesion Testing of Polymeric Coatings.” Rev. Sci. Instr., (2007) (in press) Chisholm, BJ, Webster, DC, Bennett, JW, Berry, M, Christianson, DA, Kim, J, Mayo, B, Gubbins, NJ, “An Automated System for Adhesion Testing of Polymeric Coatings.” Rev. Sci. Instr., (2007) (in press)
29.
Zurück zum Zitat Statz, A, Finlay, J, Dalsin, J, Callow, M, Callow, JA, Messersmith, PB, Algal Antifouling and Fouling-Release Properties of Metal Surfaces Coated with a Polymer Inspired by Marine Mussels. Biofouling 22 391–399 (2006)CrossRef Statz, A, Finlay, J, Dalsin, J, Callow, M, Callow, JA, Messersmith, PB, Algal Antifouling and Fouling-Release Properties of Metal Surfaces Coated with a Polymer Inspired by Marine Mussels. Biofouling 22 391–399 (2006)CrossRef
30.
Zurück zum Zitat Willemse, RXE, Staal, BBP, van Herk, AM, Pierik, SCJ, Klumperman, B, Application of Matrix-Assisted Laser Desorption Ionization Time-of-Flight Mass Spectrometry in Pulsed Laser Polymerization. Chain-Length-Dependent Propagation Rate Coefficients at High Molecular Weight: An Artifact Caused by Band Broadening in Size Exclusion Chromatography? Macromolecules 36 (26) 9797–9803 (2003)CrossRef Willemse, RXE, Staal, BBP, van Herk, AM, Pierik, SCJ, Klumperman, B, Application of Matrix-Assisted Laser Desorption Ionization Time-of-Flight Mass Spectrometry in Pulsed Laser Polymerization. Chain-Length-Dependent Propagation Rate Coefficients at High Molecular Weight: An Artifact Caused by Band Broadening in Size Exclusion Chromatography? Macromolecules 36 (26) 9797–9803 (2003)CrossRef
31.
Zurück zum Zitat Bullock, S, Johnston, EE, Willson, T, Gatenholm, P, Wynne, KJ, Surface Science of a Filled Polydimethylsiloxane-based Alkoxysilane-Cured Elastomer: RTV11. J. Colloid Interface Sci. 210 (1) 18–36 (1999)CrossRef Bullock, S, Johnston, EE, Willson, T, Gatenholm, P, Wynne, KJ, Surface Science of a Filled Polydimethylsiloxane-based Alkoxysilane-Cured Elastomer: RTV11. J. Colloid Interface Sci. 210 (1) 18–36 (1999)CrossRef
32.
Zurück zum Zitat Pike, JK, Ho, T, Wynne, KJ, Water-Induced Surface Rearrangements of Poly(dimethylsiloxane-urea-Urethane) Segmented Block Copolymers. Chem. Mater. 8 (4) 856–860 (1996)CrossRef Pike, JK, Ho, T, Wynne, KJ, Water-Induced Surface Rearrangements of Poly(dimethylsiloxane-urea-Urethane) Segmented Block Copolymers. Chem. Mater. 8 (4) 856–860 (1996)CrossRef
Metadaten
Titel
Combinatorial approach to study the effect of acrylic polyol composition on the properties of crosslinked siloxane-polyurethane fouling-release coatings
verfasst von
Robert J. Pieper
Abdullah Ekin
Dean C. Webster
Franck Cassé
James A. Callow
Maureen E. Callow
Publikationsdatum
01.12.2007
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 4/2007
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-007-9032-1

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