Skip to main content
Erschienen in: Journal of Coatings Technology and Research 1/2009

01.03.2009

Hindered amine light stabilizers in pigmented coatings

verfasst von: Christian Schaller, Daniel Rogez, Adalbert Braig

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 1/2009

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

It is common practice to combine hindered amine light stabilizers (HALS) with UV absorbers (UVA) for optimal protection of coatings and plastics. The ratio of UVA and HALS strongly depends on the concentration of pigments (acting as UVA) used in the paint; that is, a clearcoatings require higher amounts of UVA, whereas opaque pigmented coatings require higher amounts of HALS. Here, especially basic HALS types can interfere with paint components like, for example, pigments due to acid/base interactions. In this article, we want to discuss the influence of HALS basicity on long-term performance in opaque white pigmented solventborne (SB) and waterborne (WB) coatings for industrial applications in correlation to the quality of the used TiO2.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Valet, A, Light Stabilizers for Paints, pp. 45–128. C.R. Vincentz Verlag, Hannover, Germany (1997). ISBN: 3878704437 Valet, A, Light Stabilizers for Paints, pp. 45–128. C.R. Vincentz Verlag, Hannover, Germany (1997). ISBN: 3878704437
2.
Zurück zum Zitat Pospisil, J., Nespurek, S. (2000) Photostabilization of coatings. Mechanisms and performance, Progress in Polymer Science, 25(9), 1261–1335CrossRef Pospisil, J., Nespurek, S. (2000) Photostabilization of coatings. Mechanisms and performance, Progress in Polymer Science, 25(9), 1261–1335CrossRef
3.
Zurück zum Zitat Bauer, D.R. (1995) Kinetics of photooxidation and photostabilization in crosslinked polymer coatings, Polymer Degradation and Stability, 48, 259–267.CrossRef Bauer, D.R. (1995) Kinetics of photooxidation and photostabilization in crosslinked polymer coatings, Polymer Degradation and Stability, 48, 259–267.CrossRef
4.
Zurück zum Zitat Decker, C., Biry, S., Zahouily, K. (1995) Photostabilisation of organic coatings, Polymer Degradation and Stability 49, 111–119.CrossRef Decker, C., Biry, S., Zahouily, K. (1995) Photostabilisation of organic coatings, Polymer Degradation and Stability 49, 111–119.CrossRef
5.
Zurück zum Zitat Keck, J., Stüber, G.J., Kramer, H.E.A. (1997) Deactivation processes of 2-hydroxyphenyl–1,3,5-triazines: Polymeric and monomeric UV absorbers of the benzotriazole and triazine class, Angewandte Macromolekulare Chemie 252, 119–138CrossRef Keck, J., Stüber, G.J., Kramer, H.E.A. (1997) Deactivation processes of 2-hydroxyphenyl–1,3,5-triazines: Polymeric and monomeric UV absorbers of the benzotriazole and triazine class, Angewandte Macromolekulare Chemie 252, 119–138CrossRef
6.
Zurück zum Zitat Schaller, C., Rogez, D., Braig, A. (2008) Hydroxyphenyl-s-triazines: Advanced multi-purpose UV-absorbers for coatings, Journal of Coatings Technology and Research 5(1), 25–31CrossRef Schaller, C., Rogez, D., Braig, A. (2008) Hydroxyphenyl-s-triazines: Advanced multi-purpose UV-absorbers for coatings, Journal of Coatings Technology and Research 5(1), 25–31CrossRef
7.
Zurück zum Zitat Stährfeld, A, Braig, A, “Advanced UV Protection of Automotive Clear Coatings.” Proceedings from the XXVI FATIPEC Congress, Dresden, Germany (2002) Stährfeld, A, Braig, A, “Advanced UV Protection of Automotive Clear Coatings.” Proceedings from the XXVI FATIPEC Congress, Dresden, Germany (2002)
8.
Zurück zum Zitat Kurumada, T., Ohsawa, H., Yamazaki, T. (1987) Synergism of hindered amine light stabilizers and UV-absorbers, Polymer Degradation and Stability, 19(3), 263–272CrossRef Kurumada, T., Ohsawa, H., Yamazaki, T. (1987) Synergism of hindered amine light stabilizers and UV-absorbers, Polymer Degradation and Stability, 19(3), 263–272CrossRef
9.
Zurück zum Zitat Klemchuk, P.P., Gande, M.E. (1988) Stabilization mechanisms of hindered amines, Polymer Degradation and Stability, 22, 241–274CrossRef Klemchuk, P.P., Gande, M.E. (1988) Stabilization mechanisms of hindered amines, Polymer Degradation and Stability, 22, 241–274CrossRef
10.
Zurück zum Zitat Klemchuk, P,P., Gande, M.E., Cordola, E. (1990) Hindered amine mechanisms. III: Investigations using isotopic labeling, Polymer Degradation and Stability, 27, 65–74CrossRef Klemchuk, P,P., Gande, M.E., Cordola, E. (1990) Hindered amine mechanisms. III: Investigations using isotopic labeling, Polymer Degradation and Stability, 27, 65–74CrossRef
11.
Zurück zum Zitat Pospisil, J., Klemchuk, P.P. (1990) Oxidative deterioration processes in organic materials in: Pospisil, J., Klemchuk, P.P., editors. Oxidation Inhibition in Organic Materials, Vol. 1. Boca Raton: CRC Press, 1–10 Pospisil, J., Klemchuk, P.P. (1990) Oxidative deterioration processes in organic materials in: Pospisil, J., Klemchuk, P.P., editors. Oxidation Inhibition in Organic Materials, Vol. 1. Boca Raton: CRC Press, 1–10
12.
Zurück zum Zitat Hayoz, P, Peter, W, Rogez, D, “Improved Photoprotection of Wood and Durability Improvement of Wood Coatings.” Proceedings from the 3rd Wood Coatings Congress, The Hague, Netherlands, 2002 Hayoz, P, Peter, W, Rogez, D, “Improved Photoprotection of Wood and Durability Improvement of Wood Coatings.” Proceedings from the 3rd Wood Coatings Congress, The Hague, Netherlands, 2002
13.
Zurück zum Zitat Hayoz, P., Peter, W., Rogez, D. (2003) Verbesserter Lichtschutz für Holzsubstrate: Farbstabilisierung bei naturbelassenen und gebeizten Hölzern für den Innenbereich, Farbe und Lack, 109(7), 26–33 Hayoz, P., Peter, W., Rogez, D. (2003) Verbesserter Lichtschutz für Holzsubstrate: Farbstabilisierung bei naturbelassenen und gebeizten Hölzern für den Innenbereich, Farbe und Lack, 109(7), 26–33
14.
Zurück zum Zitat Schaller, C., Rogez, D. (2006) Defended from the sun, European Coatings Journal, 12, 22–27 Schaller, C., Rogez, D. (2006) Defended from the sun, European Coatings Journal, 12, 22–27
15.
Zurück zum Zitat Zeren, S, “UV Stabilisation of Powder Clear Coats.” Proceedings from the XXVI FATIPEC Congress, Dresden, Germany, 2002 Zeren, S, “UV Stabilisation of Powder Clear Coats.” Proceedings from the XXVI FATIPEC Congress, Dresden, Germany, 2002
16.
Zurück zum Zitat Cliff, N., Adamson, K., Kanouni, M., Yaneff, P. (2004) Migration of reactable UVA and HALS in automotive plastic coatings, Journal of Coatings Technology and Research, 1(3), 201–212. Cliff, N., Adamson, K., Kanouni, M., Yaneff, P. (2004) Migration of reactable UVA and HALS in automotive plastic coatings, Journal of Coatings Technology and Research, 1(3), 201–212.
17.
Zurück zum Zitat Gugumus, F. (1995) The performance of light stabilizers in accelerated and natural weathering, Polymer Degradation and Stability, 50, 101–116CrossRef Gugumus, F. (1995) The performance of light stabilizers in accelerated and natural weathering, Polymer Degradation and Stability, 50, 101–116CrossRef
18.
Zurück zum Zitat Sampers, J. (2002) Importance of weathering factors other than UV radiation and temperature in outdoor Exposure, Polymer Degradation and Stability, 76, 455–465CrossRef Sampers, J. (2002) Importance of weathering factors other than UV radiation and temperature in outdoor Exposure, Polymer Degradation and Stability, 76, 455–465CrossRef
19.
Zurück zum Zitat Scoponi, M., Cimmino, S., Kaci, M. (2000) Photo-stabilisation mechanism under natural weathering and accelerated photo-oxidative conditions of LDPE Films for agricultural applications, Polymer Degradation and Stability, 41, 7969–7980 Scoponi, M., Cimmino, S., Kaci, M. (2000) Photo-stabilisation mechanism under natural weathering and accelerated photo-oxidative conditions of LDPE Films for agricultural applications, Polymer Degradation and Stability, 41, 7969–7980
20.
Zurück zum Zitat Landyult, T., Rogez, D. (2008) Hiding the hydrophobicity - encapsulated organic light stabilizer, European Coating Journal, 4(8), 34–38 Landyult, T., Rogez, D. (2008) Hiding the hydrophobicity - encapsulated organic light stabilizer, European Coating Journal, 4(8), 34–38
21.
Zurück zum Zitat Peter, W, Schaller, C, Schellenberg, C, Rogez, D, “A New Concept of Aqueous Additive Preparations for Water-Borne Coatings.” Proceedings from the Water-Borne and High-Solids Coatings Conference, Brussels, Belgium, 2006 Peter, W, Schaller, C, Schellenberg, C, Rogez, D, “A New Concept of Aqueous Additive Preparations for Water-Borne Coatings.” Proceedings from the Water-Borne and High-Solids Coatings Conference, Brussels, Belgium, 2006
22.
Zurück zum Zitat Turton, T.J., White, J.R. (2001) Effect of stabilizer and pigment on photo-degradation depth profiles in polypropylene, Polymer Degradation and Stability, 74, 559–568CrossRef Turton, T.J., White, J.R. (2001) Effect of stabilizer and pigment on photo-degradation depth profiles in polypropylene, Polymer Degradation and Stability, 74, 559–568CrossRef
23.
Zurück zum Zitat Schaller, C., Rogez, D., (2007) New approaches in wood coating stabilization, Journal of Coating Technology and Research, 4(4), 401–409CrossRef Schaller, C., Rogez, D., (2007) New approaches in wood coating stabilization, Journal of Coating Technology and Research, 4(4), 401–409CrossRef
24.
Zurück zum Zitat Liauwa, C.M., Childs, A., Allen, N.S., Edge, M., Franklin, K.R., Collopy, D.G. (1999) Effect of interactions between stabilisers and silica used for anti-blocking applications on UV and thermal stability of polyolefin film, Polymer Degradation and Stability, 65, 207–215CrossRef Liauwa, C.M., Childs, A., Allen, N.S., Edge, M., Franklin, K.R., Collopy, D.G. (1999) Effect of interactions between stabilisers and silica used for anti-blocking applications on UV and thermal stability of polyolefin film, Polymer Degradation and Stability, 65, 207–215CrossRef
25.
Zurück zum Zitat Haacke, G., Longordo, E., Andrawes, F.F., Campbell, B.H. (1998) Interactions between light stabilizers and pigment particles in polymeric coatings, Progress in Organic Coatings, 34, 75–83CrossRef Haacke, G., Longordo, E., Andrawes, F.F., Campbell, B.H. (1998) Interactions between light stabilizers and pigment particles in polymeric coatings, Progress in Organic Coatings, 34, 75–83CrossRef
26.
Zurück zum Zitat Kittel, H, Spille, J, Lehrbuch der Lacke und Beschichtungen, Band 5: Pigmente, Füllstoffe und Farbmetrik, 5.2.1.1.4. “Nachbehandlung”, 2.Auflage, pp. 31–32. Hirzel S. Verlag, Stuttgart, Germany (2003). ISBN: 9783777610153 Kittel, H, Spille, J, Lehrbuch der Lacke und Beschichtungen, Band 5: Pigmente, Füllstoffe und Farbmetrik, 5.2.1.1.4. “Nachbehandlung”, 2.Auflage, pp. 31–32. Hirzel S. Verlag, Stuttgart, Germany (2003). ISBN: 9783777610153
Metadaten
Titel
Hindered amine light stabilizers in pigmented coatings
verfasst von
Christian Schaller
Daniel Rogez
Adalbert Braig
Publikationsdatum
01.03.2009
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 1/2009
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-008-9130-8

Weitere Artikel der Ausgabe 1/2009

Journal of Coatings Technology and Research 1/2009 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.