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Erschienen in: Journal of Coatings Technology and Research 2/2020

03.01.2020

Vapor phase assembly of urea–amine compounds and their protection against the atmospheric corrosion of carbon steel

verfasst von: Hong-Liang Zhang, Teng-Fei Ma, Li-Xin Gao, Da-Quan Zhang, Guo-An Wei, Hong-Bin Yan, Shi-Li Wei

Erschienen in: Journal of Coatings Technology and Research | Ausgabe 2/2020

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Abstract

Two kinds of polyamine compounds, bis-cyclohexylaminoethylurea (BCAU) and monocyclohexylaminoethylurea (MCAU), are synthesized via Mannich reaction. The anticorrosion films on carbon steel surface are prepared by the vapor phase assembly method. After 72 h volatilization at 50°C, the mass-loss for BCAU and MCAU in the closed space are 1.13% and 1.45%. The volatile-inhibiting sieve (VIS) test, the volatile-inhibiting ability test and the electrochemical impedance spectroscopy measurement are used to compare the prevention of the atmospheric corrosion by the assembly film. BCAU and MCAU have 92.44% and 87.56% inhibition efficiency for carbon steel in VIS test. On the basis of theoretical calculation and surface analysis, the protective film structures on carbon surface from the vapor phase assembly are proposed.

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Metadaten
Titel
Vapor phase assembly of urea–amine compounds and their protection against the atmospheric corrosion of carbon steel
verfasst von
Hong-Liang Zhang
Teng-Fei Ma
Li-Xin Gao
Da-Quan Zhang
Guo-An Wei
Hong-Bin Yan
Shi-Li Wei
Publikationsdatum
03.01.2020
Verlag
Springer US
Erschienen in
Journal of Coatings Technology and Research / Ausgabe 2/2020
Print ISSN: 1547-0091
Elektronische ISSN: 1935-3804
DOI
https://doi.org/10.1007/s11998-019-00301-7

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