Sorption of cesium and iodide ions onto KENTEX-bentonite

The sorption of cesium and iodide ions onto KENTEX-bentonite was investigated using batch test and in-diffusion test methods. The cesium ions were highly sorbed on the bentonite, and the experimental data fit the Freundlich isotherm well. The distribution coefficient, K _d, of the cesium ions was variably affected by the chemical conditions of the solution (initial ion concentration, pH, salinity) and temperature. An increasing pH of solution increased the K _d. However, there were different K _d values that decrease with an increase in the initial ion concentration, salinity, and temperature. The iodide ions, on the contrary, were negligibly sorptive. The K _d values obtained from the in-diffusion tests were quite lower than those from the batch tests, which could be explained by changes in the pore water chemistry and surface area available for sorption.