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Erschienen in: Physics of Metals and Metallography 5/2019

01.05.2019 | STRUCTURE, PHASE TRANSFORMATIONS, AND DIFFUSION

Investigation of the Composition and Properties of a Cr2AlC MAX Phase-Based Material Prepared by Metallothermic SHS

verfasst von: V. A. Gorshkov, P. A. Miloserdov, A. V. Karpov, A. S. Shchukin, A. E. Sytschev

Erschienen in: Physics of Metals and Metallography | Ausgabe 5/2019

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Abstract

Cast composite material based on Cr2AlC MAX phase has been prepared by metallothermic self-propagating high-temperature synthesis (SHS) from a mixture of powders of chromium oxide, aluminum, and carbon. The experiments have been performed using an SHS reactor with a volume V of 3 L under an excess inert gas (Ar) pressure (P = 5 MPa). The prepared material has been studied by X-ray diffraction analysis, scanning electron microscopy, and local microstructural analysis. The quantitative analysis has been performed by the Rietveld method. The electrical resistivity was measured in the 1001300 K temperature range. The resulting material is an electrical conductor with metallic conductivity in the 100–1300 K temperature range, and has the electrical resistivity of the same order as the samples containing 100% Cr2AlC.

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Literatur
1.
Zurück zum Zitat M. W. Barsoum, “The MN + 1AXN phases: A new class of solids: Thermodynamically stable nanolaminates,” Prog. Solid State Chem. 28, 201–281 (2000).CrossRef M. W. Barsoum, “The MN + 1AXN phases: A new class of solids: Thermodynamically stable nanolaminates,” Prog. Solid State Chem. 28, 201–281 (2000).CrossRef
2.
Zurück zum Zitat J. D. Hettinger, S. E. Lofland, P. Finkel, T. Meehan, J. Palma, K. Harrell, S. Gupta, A. Ganguly, T. El-Raghy, and M. W. Barsoum, “Electrical transport, thermal transport, and elastic properties of M2AlC (M = Ti, Cr, Nb, and V),” Phys. Rev. B. 72, 115120 (2005).CrossRef J. D. Hettinger, S. E. Lofland, P. Finkel, T. Meehan, J. Palma, K. Harrell, S. Gupta, A. Ganguly, T. El-Raghy, and M. W. Barsoum, “Electrical transport, thermal transport, and elastic properties of M2AlC (M = Ti, Cr, Nb, and V),” Phys. Rev. B. 72, 115120 (2005).CrossRef
3.
Zurück zum Zitat W. B. Tian, P. L. Wang, G. Zhang, Y. Kan, Y. Li, and D. Yan, “Synthesis and thermal and electrical properties of bulk Cr2AlC,” Scr. Mater. 54, 841–846 (2006).CrossRef W. B. Tian, P. L. Wang, G. Zhang, Y. Kan, Y. Li, and D. Yan, “Synthesis and thermal and electrical properties of bulk Cr2AlC,” Scr. Mater. 54, 841–846 (2006).CrossRef
4.
Zurück zum Zitat Z. Lin, Y. Zhou, and M. Li, “Synthesis, microstructure, and property of Cr2AlC,” J. Mater. Sci. Technol. 23, 721–746 (2007). Z. Lin, Y. Zhou, and M. Li, “Synthesis, microstructure, and property of Cr2AlC,” J. Mater. Sci. Technol. 23, 721–746 (2007).
5.
Zurück zum Zitat J. M. Schneider, Z. Sun, R. Mertens, F. Uestel, and R. Ahuja, “Ab-Initio calculations and experimental determination of the structure of Cr2AlC,” Solid State Commun. 130, 445–449 (2004).CrossRef J. M. Schneider, Z. Sun, R. Mertens, F. Uestel, and R. Ahuja, “Ab-Initio calculations and experimental determination of the structure of Cr2AlC,” Solid State Commun. 130, 445–449 (2004).CrossRef
6.
Zurück zum Zitat W. Tian, K. Vanmeensel, P. Wang, G. Zhang, Y. Li, J. Vleugels, and O. Van der Biest, “Synthesis and characterization of Cr2AlC ceramics prepared by spark plasma sintering,” Mater. Lett. 61, 4442–4445 (2007).CrossRef W. Tian, K. Vanmeensel, P. Wang, G. Zhang, Y. Li, J. Vleugels, and O. Van der Biest, “Synthesis and characterization of Cr2AlC ceramics prepared by spark plasma sintering,” Mater. Lett. 61, 4442–4445 (2007).CrossRef
7.
Zurück zum Zitat Li. O. Xiao, S. B. Li, G. Song, and W. G. Sloof, “Synthesis and thermal stability of Cr2AlC,” J. Eur. Ceram. Soc. 31, 1497–1502 (2011). Li. O. Xiao, S. B. Li, G. Song, and W. G. Sloof, “Synthesis and thermal stability of Cr2AlC,” J. Eur. Ceram. Soc. 31, 1497–1502 (2011).
8.
Zurück zum Zitat B. B. Panigrahi, C. Min-Cheol, K. Yong-Il, C. Seong-Jai, and J. J. Gracio, “Reaction synthesis and pressureless sintering of Cr2AlC powder,” J. Amer. Ceram. Soc., No. 93, 1530–1533 (2010). B. B. Panigrahi, C. Min-Cheol, K. Yong-Il, C. Seong-Jai, and J. J. Gracio, “Reaction synthesis and pressureless sintering of Cr2AlC powder,” J. Amer. Ceram. Soc., No. 93, 1530–1533 (2010).
9.
Zurück zum Zitat D. Xiao, J. Zhu, F. Wang, and Y. Tang, “Synthesis of nano sized Cr2AlC powders by molten salt method,” J. Nanosci. Nanotechnol. 15, 7341–7345 (2015).CrossRef D. Xiao, J. Zhu, F. Wang, and Y. Tang, “Synthesis of nano sized Cr2AlC powders by molten salt method,” J. Nanosci. Nanotechnol. 15, 7341–7345 (2015).CrossRef
10.
Zurück zum Zitat X. Duan, L. Shen, D. Jia, Y. Zhou, S. Zwaag, and W. G. Sloof, “Synthesis of high-purity, isotropic or textured Cr2AlC bulk ceramics by spark plasma sintering of pressure-less sintered powders,” J. Eur. Ceram. Soc. 35, 1393–1400 (2015).CrossRef X. Duan, L. Shen, D. Jia, Y. Zhou, S. Zwaag, and W. G. Sloof, “Synthesis of high-purity, isotropic or textured Cr2AlC bulk ceramics by spark plasma sintering of pressure-less sintered powders,” J. Eur. Ceram. Soc. 35, 1393–1400 (2015).CrossRef
11.
Zurück zum Zitat W. B. Tian, Z. M. Sun, Y. Du, and H. Hashimoto, “Synthesis reactions of Cr2AlC from Cr–Al4C3–C by pulse discharge sintering,” Mater. Lett. 62, 3852–3855 (2008).CrossRef W. B. Tian, Z. M. Sun, Y. Du, and H. Hashimoto, “Synthesis reactions of Cr2AlC from Cr–Al4C3–C by pulse discharge sintering,” Mater. Lett. 62, 3852–3855 (2008).CrossRef
12.
Zurück zum Zitat W. B. Tian, P. L. Wang, Y. M. Kana, G. J. Zhang, Y. X. Li, and D. S. Yan, “Phase formation sequence of Cr2AlC ceramics starting from Cr–Al–C powders,” Mater. Sci. Eng., A 443, 229–234 (2007).CrossRef W. B. Tian, P. L. Wang, Y. M. Kana, G. J. Zhang, Y. X. Li, and D. S. Yan, “Phase formation sequence of Cr2AlC ceramics starting from Cr–Al–C powders,” Mater. Sci. Eng., A 443, 229–234 (2007).CrossRef
13.
Zurück zum Zitat G. Ying, X. LiM. He, Y. Li, and S. Du, “Synthesis and mechanical properties of nano-layered composite,” J. Alloys Compd. 506, 734–738 (2010).CrossRef G. Ying, X. LiM. He, Y. Li, and S. Du, “Synthesis and mechanical properties of nano-layered composite,” J. Alloys Compd. 506, 734–738 (2010).CrossRef
14.
Zurück zum Zitat L. O. Xiao, S. B. Li, G. Song, and W. G. Sloof, “Synthesis and thermal stability of Cr2AlC,” J. Eur. Ceram. Soc. 31, 1497–1502 (2011).CrossRef L. O. Xiao, S. B. Li, G. Song, and W. G. Sloof, “Synthesis and thermal stability of Cr2AlC,” J. Eur. Ceram. Soc. 31, 1497–1502 (2011).CrossRef
15.
Zurück zum Zitat E. A. Levashov, A. S. Rogachev, V. V. Kurbatkina, Yu. M. Maksimov, and V. I. Yukhvid, Perspective Materials and Technologies of Self-Propagating High-Temperature Synthesis. Tutorial, Ed. by N. A. Fetisova (Izd. Dom MISiS, Moscow, 2011) [in Russian]. E. A. Levashov, A. S. Rogachev, V. V. Kurbatkina, Yu. M. Maksimov, and V. I. Yukhvid, Perspective Materials and Technologies of Self-Propagating High-Temperature Synthesis. Tutorial, Ed. by N. A. Fetisova (Izd. Dom MISiS, Moscow, 2011) [in Russian].
16.
Zurück zum Zitat V. A. Gorshkov, P. A. Miloserdov, M. A. Luginina, N. V. Sachkova, and A. F. Belikova, “High-temperature synthesis of a cast material with a maximum content of the MAX phase Cr2AlC,” Inorg. Mater. 53, 271–277 (2017).CrossRef V. A. Gorshkov, P. A. Miloserdov, M. A. Luginina, N. V. Sachkova, and A. F. Belikova, “High-temperature synthesis of a cast material with a maximum content of the MAX phase Cr2AlC,” Inorg. Mater. 53, 271–277 (2017).CrossRef
17.
Zurück zum Zitat A. V. Karpov, Yu. G. Morozov, V. A. Bunin, and I. P. Borovinskaya, “Effect of yttria additions on the electrical conductivity of SHS nitride ceramics,” Inorg. Mater. 38, 631–634 (2002).CrossRef A. V. Karpov, Yu. G. Morozov, V. A. Bunin, and I. P. Borovinskaya, “Effect of yttria additions on the electrical conductivity of SHS nitride ceramics,” Inorg. Mater. 38, 631–634 (2002).CrossRef
18.
Zurück zum Zitat V. F. Gantmakher, Electrons in Disordered Media (FIZMATLIT, Moscow, 2013) [in Russian]. V. F. Gantmakher, Electrons in Disordered Media (FIZMATLIT, Moscow, 2013) [in Russian].
Metadaten
Titel
Investigation of the Composition and Properties of a Cr2AlC MAX Phase-Based Material Prepared by Metallothermic SHS
verfasst von
V. A. Gorshkov
P. A. Miloserdov
A. V. Karpov
A. S. Shchukin
A. E. Sytschev
Publikationsdatum
01.05.2019
Verlag
Pleiades Publishing
Erschienen in
Physics of Metals and Metallography / Ausgabe 5/2019
Print ISSN: 0031-918X
Elektronische ISSN: 1555-6190
DOI
https://doi.org/10.1134/S0031918X19050041

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