Skip to main content
Erschienen in: Tribology Letters 1/2013

01.01.2013 | Original Paper

Lithium-Based Ionic Liquids: In Situ-Formed Lubricant Additive Only by Blending

verfasst von: Zenghong Song, Mingjin Fan, Yongmin Liang, Feng Zhou, Weimin Liu

Erschienen in: Tribology Letters | Ausgabe 1/2013

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

This article reports a novel way of in situ formation of ionic liquids (ILs) that are used as lubricant additives for steel/steel contacts. The ILs can be generated simply in base oils by mixing small molecules of 2-oxazolidinone, triglyme, or tetraglyme with lithium bis(trifluoromethane sulfonyl) imide in appropriate molar ratios at room temperature. The said ILs can be formed in polyether, polyester, and polyurea grease and show better solubility in these base oils than commonly used ILs such as 1-methyl-3-hexylimidazolium hexafluorophosphate (L-P106). They can significantly improve the friction-reducing and antiwear properties of the base oils.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
1.
Zurück zum Zitat Laszlo, J.A., Compton, D.L.: α-Chymotrypsin catalysis in imidazolium-based ionic liquids. Biotechnol. Bioeng. 75, 181–186 (2001)CrossRef Laszlo, J.A., Compton, D.L.: α-Chymotrypsin catalysis in imidazolium-based ionic liquids. Biotechnol. Bioeng. 75, 181–186 (2001)CrossRef
2.
Zurück zum Zitat Bose, S., Wijeratne, A.B., Thite, A., Kraus, G.A., Armstrong, D.W., Petrich, J.W.: Influence of chiral ionic liquids on stereoselective fluorescence quenching by photoinduced electron transfer in a naproxen dyad. J. Phys. Chem. B 113, 10825–10829 (2009)CrossRef Bose, S., Wijeratne, A.B., Thite, A., Kraus, G.A., Armstrong, D.W., Petrich, J.W.: Influence of chiral ionic liquids on stereoselective fluorescence quenching by photoinduced electron transfer in a naproxen dyad. J. Phys. Chem. B 113, 10825–10829 (2009)CrossRef
3.
Zurück zum Zitat Earle, M.J., Seddon, K.R.: Ionic liquid: green solvents for the future. Pure Appl. Chem. 72, 1391–1398 (2000)CrossRef Earle, M.J., Seddon, K.R.: Ionic liquid: green solvents for the future. Pure Appl. Chem. 72, 1391–1398 (2000)CrossRef
4.
Zurück zum Zitat Welton, T.: Room-temperature ionic liquids: solvents for synthesis and catalysis. Chem. Rev. 99, 2071–2083 (1999)CrossRef Welton, T.: Room-temperature ionic liquids: solvents for synthesis and catalysis. Chem. Rev. 99, 2071–2083 (1999)CrossRef
5.
Zurück zum Zitat Hagiwara, R., Ito, Y.: Room temperature ionic liquids of alkylimidazolium cations and fluoroanions. J. Fluorine Chem. 105, 221–227 (2000)CrossRef Hagiwara, R., Ito, Y.: Room temperature ionic liquids of alkylimidazolium cations and fluoroanions. J. Fluorine Chem. 105, 221–227 (2000)CrossRef
6.
Zurück zum Zitat Seddon, K.R.: Ionic liquids for clean technology. J. Chem. Tech. Biotechnol. 68, 351–356 (1997)CrossRef Seddon, K.R.: Ionic liquids for clean technology. J. Chem. Tech. Biotechnol. 68, 351–356 (1997)CrossRef
7.
Zurück zum Zitat Zhao, H.: Innovative applications of ionic liquids as ‘‘green” engineering liquids. Chem. Eng. Commun. 193, 1660–1677 (2006)CrossRef Zhao, H.: Innovative applications of ionic liquids as ‘‘green” engineering liquids. Chem. Eng. Commun. 193, 1660–1677 (2006)CrossRef
8.
Zurück zum Zitat Qu, J., Blau, P.J., Dai, S., Luo, H., Meyer, H.M., Truhan, J.J.: Tribological characteristics of aluminum alloys sliding against steel lubricated by ammonium and imidazolium ionic liquids. Wear 267, 1226–1231 (2009)CrossRef Qu, J., Blau, P.J., Dai, S., Luo, H., Meyer, H.M., Truhan, J.J.: Tribological characteristics of aluminum alloys sliding against steel lubricated by ammonium and imidazolium ionic liquids. Wear 267, 1226–1231 (2009)CrossRef
9.
Zurück zum Zitat Ye, C.F., Liu, W.M., Chen, Y.X.G., Yu, L.: Room-temperature ionic liquids: a novel versatile lubricant. Chem. Commun. 21, 2244–2245 (2001)CrossRef Ye, C.F., Liu, W.M., Chen, Y.X.G., Yu, L.: Room-temperature ionic liquids: a novel versatile lubricant. Chem. Commun. 21, 2244–2245 (2001)CrossRef
10.
Zurück zum Zitat Liu, W., Ye, C., Chen, Y., Ou, Z., Sun, D.C.: Tribological behavior of sialon ceramics sliding against steel lubricated by fluorine-containing oils. Tribol. Int. 35, 503–509 (2002)CrossRef Liu, W., Ye, C., Chen, Y., Ou, Z., Sun, D.C.: Tribological behavior of sialon ceramics sliding against steel lubricated by fluorine-containing oils. Tribol. Int. 35, 503–509 (2002)CrossRef
11.
Zurück zum Zitat Mu, Z.G., Zhou, F., Zhang, S.X., Liang, Y.M., Liu, W.M.: Effect of the functional groups in ionic liquid molecules on the friction and wear behavior of aluminum alloy in lubricated aluminum-on-steel contact. Tribol. Int. 38, 725–731 (2005)CrossRef Mu, Z.G., Zhou, F., Zhang, S.X., Liang, Y.M., Liu, W.M.: Effect of the functional groups in ionic liquid molecules on the friction and wear behavior of aluminum alloy in lubricated aluminum-on-steel contact. Tribol. Int. 38, 725–731 (2005)CrossRef
12.
Zurück zum Zitat Jiménez, A.E., Bermúdez, M.D., Iglesias, P., Carrión, F.J., Martínez-Nicolás, G.: 1-N-Alkyl-3-methylimidazolium ionic liquids as neat lubricants and lubricant additives in steel–aluminium contacts. Wear 260, 766–782 (2006)CrossRef Jiménez, A.E., Bermúdez, M.D., Iglesias, P., Carrión, F.J., Martínez-Nicolás, G.: 1-N-Alkyl-3-methylimidazolium ionic liquids as neat lubricants and lubricant additives in steel–aluminium contacts. Wear 260, 766–782 (2006)CrossRef
13.
Zurück zum Zitat Phillips, B.S., Zabinski, J.S.: Ionic liquid lubrication effects on ceramics in a water environment. Tribol. Lett. 17, 533–541 (2004)CrossRef Phillips, B.S., Zabinski, J.S.: Ionic liquid lubrication effects on ceramics in a water environment. Tribol. Lett. 17, 533–541 (2004)CrossRef
14.
Zurück zum Zitat Liu, W.M., Ye, C.F., Gong, Q.Y., Wang, H.Z., Wang, P.: Tribological performance of room-temperature ionic liquids as lubricant. Tribol. Lett. 13, 81–85 (2002)CrossRef Liu, W.M., Ye, C.F., Gong, Q.Y., Wang, H.Z., Wang, P.: Tribological performance of room-temperature ionic liquids as lubricant. Tribol. Lett. 13, 81–85 (2002)CrossRef
15.
Zurück zum Zitat Zhang, C., Malhotra, S.V., Francis, A.J.: Toxicity of imidazolium- and pyridinium-based ionic liquids and the co-metabolic degradation of N-ethylpyridinium tetrafluoroborate. Chemosphere 82, 1690–1695 (2011)CrossRef Zhang, C., Malhotra, S.V., Francis, A.J.: Toxicity of imidazolium- and pyridinium-based ionic liquids and the co-metabolic degradation of N-ethylpyridinium tetrafluoroborate. Chemosphere 82, 1690–1695 (2011)CrossRef
16.
Zurück zum Zitat Fernandes, A.M., Rocha, M.A.A., Freire, M.G., Marrucho, I.M., Coutinho, J.A.P., Santos, L.M.N.B.: F.: evaluation of cation-anion interaction strength in ionic liquids. J. Phys. Chem. B 115, 4033–4041 (2011)CrossRef Fernandes, A.M., Rocha, M.A.A., Freire, M.G., Marrucho, I.M., Coutinho, J.A.P., Santos, L.M.N.B.: F.: evaluation of cation-anion interaction strength in ionic liquids. J. Phys. Chem. B 115, 4033–4041 (2011)CrossRef
17.
Zurück zum Zitat Yu, F.L., Zhang, R.L., Xie, C.X., Yu, S.T.: Synthesis of thermoregulated phase-separable triazolium ionic liquids catalysts and application for Stetter reaction. Tetrahedron 66, 9145–9150 (2010)CrossRef Yu, F.L., Zhang, R.L., Xie, C.X., Yu, S.T.: Synthesis of thermoregulated phase-separable triazolium ionic liquids catalysts and application for Stetter reaction. Tetrahedron 66, 9145–9150 (2010)CrossRef
18.
Zurück zum Zitat Jiménez, A.E., Bermúdez, M.D.: Imidazoliumionic liquids as additives of the synthetic ester propylene glycol dioleate in aluminium–steel lubrication. Wear 265, 787–798 (2008)CrossRef Jiménez, A.E., Bermúdez, M.D.: Imidazoliumionic liquids as additives of the synthetic ester propylene glycol dioleate in aluminium–steel lubrication. Wear 265, 787–798 (2008)CrossRef
19.
Zurück zum Zitat Hu, Y.S., Li, H., Huang, X.J., Chen, L.Q.: Novel room temperature molten salt electrolyte based on LiTFSI and acetamide for lithium batteries. Electrochem. Commun. 6, 28–32 (2004)CrossRef Hu, Y.S., Li, H., Huang, X.J., Chen, L.Q.: Novel room temperature molten salt electrolyte based on LiTFSI and acetamide for lithium batteries. Electrochem. Commun. 6, 28–32 (2004)CrossRef
20.
Zurück zum Zitat Gorecki, W., Roux, C., Clémancey, M., Armand, M., Belorizky, E.: NMR and conductivity study of polymer electrolytes in the imide family: P(EO)/Li[N(SO2CnF2n+1)(SO2CmF2m+1)]. ChemPhysChem 3, 620–625 (2002)CrossRef Gorecki, W., Roux, C., Clémancey, M., Armand, M., Belorizky, E.: NMR and conductivity study of polymer electrolytes in the imide family: P(EO)/Li[N(SO2CnF2n+1)(SO2CmF2m+1)]. ChemPhysChem 3, 620–625 (2002)CrossRef
21.
Zurück zum Zitat Aihara, Y., Kuratomi, J., Bando, T., Iguchi, T., Yoshida, H., Ono, T., Kuwana, K.: Investigation on solvent-free solid polymer electrolytes for advanced lithium batteries and their performance. J. Power Source 114, 96–104 (2003)CrossRef Aihara, Y., Kuratomi, J., Bando, T., Iguchi, T., Yoshida, H., Ono, T., Kuwana, K.: Investigation on solvent-free solid polymer electrolytes for advanced lithium batteries and their performance. J. Power Source 114, 96–104 (2003)CrossRef
22.
Zurück zum Zitat Chen, R.J., Wu, F., Li, L., Qiu, X.P., Chen, L.Q., Chen, S.: The structure–activity relationship studies of binary room temperature complex electrolytes based on LiTFSI and organic compounds with acylamino group. Vib. Spectrosc. 44, 297–307 (2007)CrossRef Chen, R.J., Wu, F., Li, L., Qiu, X.P., Chen, L.Q., Chen, S.: The structure–activity relationship studies of binary room temperature complex electrolytes based on LiTFSI and organic compounds with acylamino group. Vib. Spectrosc. 44, 297–307 (2007)CrossRef
23.
Zurück zum Zitat Henderson, W.A.: Glyme–lithium salt phase behavior. J. Phys. Chem. B 110, 13177–13183 (2006)CrossRef Henderson, W.A.: Glyme–lithium salt phase behavior. J. Phys. Chem. B 110, 13177–13183 (2006)CrossRef
24.
Zurück zum Zitat Chen, R.J., Wu, F., Li, L., Xu, B., Qiu, X.P., Chen, S.: Novel binary room-temperature complex system based on LiTFSI and 2-oxazolidinone and its characterization as electrolyte. J. Phys. Chem. C 111, 5184–5194 (2007)CrossRef Chen, R.J., Wu, F., Li, L., Xu, B., Qiu, X.P., Chen, S.: Novel binary room-temperature complex system based on LiTFSI and 2-oxazolidinone and its characterization as electrolyte. J. Phys. Chem. C 111, 5184–5194 (2007)CrossRef
25.
Zurück zum Zitat Tamura, T., Yoshida, K., Hachida, T., Tsuchiya, M., Nakamura, M., Kazue, Y., Tachikawa, N., Dokko, K., Watanabe, M.: Physicochemical properties of glyme–Li salt complexes as a new family of room-temperature ionic liquids. Chem. Lett. 39, 753–755 (2010)CrossRef Tamura, T., Yoshida, K., Hachida, T., Tsuchiya, M., Nakamura, M., Kazue, Y., Tachikawa, N., Dokko, K., Watanabe, M.: Physicochemical properties of glyme–Li salt complexes as a new family of room-temperature ionic liquids. Chem. Lett. 39, 753–755 (2010)CrossRef
26.
Zurück zum Zitat Yoshida, K., Nakamura, M., Kazue, Y., Tachikawa, N., Tsuzuki, S., Seki, S., Dokko, K., Watanabe, M.: Oxidative-stability enhancement and charge transport mechanism in glyme–lithium salt equimolar complexes. J. Am. Chem. Soc. 133, 13121–13129 (2011)CrossRef Yoshida, K., Nakamura, M., Kazue, Y., Tachikawa, N., Tsuzuki, S., Seki, S., Dokko, K., Watanabe, M.: Oxidative-stability enhancement and charge transport mechanism in glyme–lithium salt equimolar complexes. J. Am. Chem. Soc. 133, 13121–13129 (2011)CrossRef
27.
Zurück zum Zitat Borisenko, L.I., Ishchuk, YuL: Properties of polyurea greases on a synthetic base. Chem. Technol. Fuels Oils 40, 415–417 (2004)CrossRef Borisenko, L.I., Ishchuk, YuL: Properties of polyurea greases on a synthetic base. Chem. Technol. Fuels Oils 40, 415–417 (2004)CrossRef
29.
Zurück zum Zitat Wang, H.Z., Lu, Q.M., Ye, C.F., Liu, W.M., Cui, Z.J.: Friction and wear behaviors of ionic liquid of alkylimidazolium hexafluorophosphates as lubricants for steel/steel contact. Wear 256, 44–48 (2004)CrossRef Wang, H.Z., Lu, Q.M., Ye, C.F., Liu, W.M., Cui, Z.J.: Friction and wear behaviors of ionic liquid of alkylimidazolium hexafluorophosphates as lubricants for steel/steel contact. Wear 256, 44–48 (2004)CrossRef
30.
Zurück zum Zitat Hernández Battez, A., González, R., Viesca, J.L., Blanco, D., Asedegbega, E., Osorio, A.: Tribological behaviour of two imidazolium ionic liquids as lubricant additives for steel/steel contacts. Wear 266, 1224–1228 (2009)CrossRef Hernández Battez, A., González, R., Viesca, J.L., Blanco, D., Asedegbega, E., Osorio, A.: Tribological behaviour of two imidazolium ionic liquids as lubricant additives for steel/steel contacts. Wear 266, 1224–1228 (2009)CrossRef
31.
Zurück zum Zitat Minami, I.: Ionic liquids in tribology. Molecules 14, 2286–2305 (2009)CrossRef Minami, I.: Ionic liquids in tribology. Molecules 14, 2286–2305 (2009)CrossRef
32.
Zurück zum Zitat Suzuki, A., Shinka, Y., Masuko, M.: Tribological characteristics of imidazolium-based room temperature ionic liquids under high vacuum. Tribol. Lett. 27, 307–313 (2007)CrossRef Suzuki, A., Shinka, Y., Masuko, M.: Tribological characteristics of imidazolium-based room temperature ionic liquids under high vacuum. Tribol. Lett. 27, 307–313 (2007)CrossRef
Metadaten
Titel
Lithium-Based Ionic Liquids: In Situ-Formed Lubricant Additive Only by Blending
verfasst von
Zenghong Song
Mingjin Fan
Yongmin Liang
Feng Zhou
Weimin Liu
Publikationsdatum
01.01.2013
Verlag
Springer US
Erschienen in
Tribology Letters / Ausgabe 1/2013
Print ISSN: 1023-8883
Elektronische ISSN: 1573-2711
DOI
https://doi.org/10.1007/s11249-012-0046-1

Weitere Artikel der Ausgabe 1/2013

Tribology Letters 1/2013 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.