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Journal of Nanoparticle Research

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01.10.2011 | Research Paper

Local structure study of vanadium pentoxide 1D-nanostructures

verfasst von: W. Avansi, L. J. Q. Maia, C. Ribeiro, E. R. Leite, V. R. Mastelaro

Erschienen in: Journal of Nanoparticle Research | Ausgabe 10/2011

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Abstract

Vanadium pentoxide (V₂O₅·nH₂O) 1D-nanostructures as nanowires and nanorods have been obtained by decomposition of vanadium peroxide in hydrothermal conditions. Electron microscopy, Raman spectroscopy, and X-ray absorption spectroscopy (XAS) were employed to characterize the morphology and the local structure of as-obtained samples. Scanning transmission electron microscopy (STEM) revealed that the diameter of the nanowires and nanorods were found to be 10–20 and 30–40 nm, respectively. The results demonstrated that a combination of Raman and XAS techniques allowed the accurate characterization of the local structure of V₂O₅ 1D-nanostructures which are related to different morphologies. Analyses of X-ray absorption near-edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) spectra reveals that the local structure of V in the as-obtained samples is similar to the bulk V₂O₅ (in orthorhombic phase), except for a higher degree of local symmetry within the structure of the VO₅ square pyramid. Additionally, the nanostructures prepared by this technique present a single crystalline nature and could emit visible light at room temperature which is related to the local order of V atoms of the studied samples.

Vorheriger Artikel Electrical characterization and Raman spectroscopy of individual vanadium pentoxide nanowire

Nächster Artikel Electronic properties of a zinc oxide nanotube under uniaxial tensile strain: a density functional theory study

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Abello L, Husson E, Repelin Y, Lucazeau G (1985) Structural study of gels of V₂O₅—vibrational spectra of xerogels. J Solid State Chem 56(3):379–389CrossRef

Avansi W, Ribeiro C, Leite ER, Mastelaro VR (2009) Vanadium pentoxide nanostructures: an effective control of morphology and crystal structure in hydrothermal conditions. Cryst Growth Des 9(8):3626–3631. doi:10.1021/cg900373f CrossRef

Avansi W, Ribeiro C, Leite ER, Matelaro VR (2010) Growth kinetics of vanadium pentoxide nanostructures under hydrothermal conditions. J Cryst Growth 312:3555–3559

Barth S, Hernandez-Ramirez F, Holmes JD, Romano-Rodriguez A (2010) Synthesis and applications of one-dimensional semiconductors. Prog Mater Sci 55 (6):563–627. doi:10.1016/j.pmatsci.2010.02.001

Beke S, Giorgio S, Korosi L, Nanai L, Marine W (2008) Structural and optical properties of pulsed laser deposited V2O5 thin films. Thin Solid Films 516(15):4659–4664. doi:10.1016/j.tsf.2007.08.113 CrossRef

Burda C, Chen X, Narayanan R, El-Sayed MA (2005) Chemistry and properties of nanocrystals of different shapes. Chem Rev 105(4):1025–1102CrossRef

Cademartiri L, Ozin GA (2009) Ultrathin nanowires—a materials chemistry perspective. Adv Mater 21(10):1013–1020CrossRef

Diaz-Guerra C, Piqueras J (2008) Thermal deposition growth and luminescence properties of single-crystalline V₂O₅ elongated nanostructures. Cryst Growth Des 8(3):1031–1034. doi:10.1021/cg070612w CrossRef

Gao SK, Chen YZ, Luo HY, Jiang LL, Ye BH, Wei MD, Wei KM (2008) Single-crystal vanadium pentoxide nanowires. J Nanosci Nanotechnol 8(7):3500–3503. doi:10.1166/jnn.2008.137 CrossRef

Giorgetti M, Passerini S, Smyrl WH, Berrettoni M (2000) Evidence of bilayer structure in V₂O₅ xerogel. Inorg Chem 39(7):1514–1517CrossRef

Glushenkov AM, Stukachev VI, Hassan MF, Kuvshinov GG, Liu HK, Chen Y (2008) A novel approach for real mass transformation from V₂O₅ particles to nanorods. Cryst Growth Des 8(10):3661–3665. doi:10.1021/cg800257d CrossRef

Hu Y, Li ZC, Zhang ZJ, Meng DQ (2009) Effect of magnetic field on the visible light emission of V₂O₅ nanorods. Appl Phys Lett 94(10). doi:10.1063/1.3095502

Leroy CM, Achard MF, Babot O, Steunou N, Masse P, Livage J, Binet L, Brun N, Backov R (2007) Designing nanotextured vanadium oxide-based macroscopic fibers: application as alcoholic sensors. Chem Mater 19:3988–3999. doi:10.1021/cm0711966 CrossRef

Li BX, Xu Y, Rong GX, Jing M, Xie Y (2006) Vanadium pentoxide nanobelts and nanorolls: from controllable synthesis to investigation of their electrochemical properties and photocatalytic activities. Nanotechnology 17(10):2560–2566. doi:10.1088/0957-4484/17/10/020 CrossRef

Liu JF, Wang X, Peng Q, Li YD (2005) Vanadium pentoxide nanobelts: highly selective and stable ethanol sensor materials. Adv Mater 17(6):764. doi:10.1002/adma.200400993

Liu JF, Wang X, Peng Q, Li YD (2006) Preparation and gas sensing properties of vanadium oxide nanobelts coated with semiconductor oxides. Sensors Actuators B 115(1):481–487. doi:10.1016/j.snb.2005.10.012 CrossRef

Livage J (1991) Vanadium pentoxide gels. Chem Mater 3(4):578–593CrossRef

Livage J (1998) Synthesis of polyoxovanadates via “chimie douce”. Coord Chem Rev 178:999–1018CrossRef

Longo VM, de Figueiredo AT, de Lazaro S, Gurgel MF, Costa MGS, Paiva-Santos CO, Varela JA, Longo E, Mastelaro VR, De Vicente FS, Hernandes AC, Franco RWA (2008) Structural conditions that leads to photoluminescence emission in SrTiO3: an experimental and theoretical approach. J Appl Phys 104(2). doi:10.1063/1.2956741

Mansour AN, Dallek S, Smith PH, Baker WM (2002) Thermogravimetry and X-ray absorption spectroscopy study of heated V₂O₅·nH₍₂₎O aerogels and ambigels. J Electrochem Soc 149(12):A1589–A1597. doi:10.1149/1.1517284 CrossRef

Mansour AN, Smith PH, Baker WM, Balasubramanian M, McBreen J (2003a) A comparative in situ X-ray absorption spectroscopy study of nanophase V₂O₅ aerogel and ambigel cathodes. J Electrochem Soc 150(4):A403–A413. doi:10.1149/1.1554911 CrossRef

Mansour AN, Smith PH, Baker WM, Balasubramanian M, McBreen J (2003b) Comparative in situ X-ray absorption spectroscopy study of nanophase V₂O₅ aerogel and ambigel cathodes (vol 150, pg A403, 2003). J Electrochem Soc 150(6):L13–L13. doi:10.1149/1.1574327 CrossRef

Moreira ML, Paris EC, do Nascimento GS, Longo VM, Sambrano JR, Mastelaro VR, Bernardi MIB, Andres J, Varela JA, Longo E (2009) Structural and optical properties of CaTiO3 perovskite-based materials obtained by microwave-assisted hydrothermal synthesis: an experimental and theoretical insight. Acta Mater 57(17):5174–5185. doi:10.1016/j.actamat.2009.07.019 CrossRef

Motta FV, de Figueiredo AT, Longo VM, Mastelaro VR, Freitas AZ, Gomes L, Vieira ND, Longo E, Varela JA (2009) Disorder-dependent photoluminescence in Ba_0.8Ca_0.2TiO₃ at room temperature. J Lumin 129(7):686–690. doi:10.1016/j.jlumin.2009.01.014 CrossRef

Nakajima T, Isobe M, Tsuchiya T, Ueda Y, Manabe T (2010) Photoluminescence property of vanadates M2V2O7 (M: Ba, Sr and Ca). Opt Mater 32(12):1618–1621. doi:10.1016/j.optmat.2010.05.021

Niederberger M, Muhr HJ, Krumeich F, Bieri F, Gunther D, Nesper R (2000) Low-cost synthesis of vanadium oxide nanotubes via two novel non-alkoxide routes. Chem Mater 12(7):1995–2000CrossRef

Petkov V, Trikalitis PN, Bozin ES, Billinge SJL, Vogt T, Kanatzidis MG (2002) Structure of V₂O₅·nH₍₂₎O xerogel solved by the atomic pair distribution function technique. J Am Chem Soc 124(34):10157–10162. doi:10.1021/ja026143y CrossRef

Pinna N, Wild U, Urban J, Schlogl R (2003) Divanadium pentoxide nanorods. Adv Mater 15(4):329–331CrossRef

Pol VG, Pol SV, Calderon-Moreno JM, Gedanken A (2009) Core-shell vanadium oxide-carbon nanoparticles: synthesis, characterization, and luminescence properties. J Phys Chem C 113(24):10500–10504. doi:10.1021/jp902503w CrossRef

Ramana CV, Smith RJ, Hussain OM, Massot M, Julien CM (2005) Surface analysis of pulsed laser-deposited V₂O₅ thin films and their lithium intercalated products studied by Raman spectroscopy. Surf Interface Anal 37(4):406–411. doi:10.1002/sia.2018 CrossRef

Ravel B, Newville M (2005a) ATHENA and ARTEMIS: interactive graphical data analysis using IFEFFIT. Physica Scripta T115:1007–1010CrossRef

Ravel B, Newville M (2005b) ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT. J Synchrotron Radiat 12:537–541. doi:10.1107/s0909049505012719 CrossRef

Serier H, Achard MF, Babot O, Steunou N, Maquet J, Livage J, Leroy CM, Backov R (2006) Designing the width and texture of vanadium oxide macroscopic fibers: towards tuning mechanical properties and alcohol-sensing performance. Adv Funct Mater 16(13):1745–1753. doi:10.1002/adfm.200600044 CrossRef

Souza AG, Ferreira OP, Santos EJG, Mendes J, Alves OL (2004) Raman spectra in vanadate nanotubes revisited. Nano Lett 4(11):2099–2104. doi:10.1021/nl0488477 CrossRef

Stizza S, Mancini G, Benfatto M, Natoli CR, Garcia J, Bianconi A (1989) Structure of oriented V₂O₅ gel studied by polarized X-ray-absorption spectroscopy at the vanadium K edge. Phys Rev B 40(18):12229–12236CrossRef

Teramura K, Hosokawa T, Ohuchi T, Shishido T, Tanaka T (2008) Photoactivation mechanism of orthovanadate-like (V=O)O-3 species. Chem Phys Lett 460(4–6):478–481. doi:10.1016/j.cplett.2008.06.025 CrossRef

Velazquez JR, Banerjee S (2009) Catalytic growth of single-crystalline V₂O₅ nanowire arrays. Small 5(9):1025–1029. doi:10.1002/smll.200801278 CrossRef

Wang Y, Cao G (2006) Synthesis and enhanced intercalation properties of nanostructured vanadium oxides. Chem Mater 18(12):2787–2804CrossRef

Wang X, Li Y (2006) Solution-based synthetic strategies for 1-D nanostructures. Inorg Chem 45(19):7522–7534CrossRef

Wang Y, Takahashi K, Shang HM, Cao GZ (2005) Synthesis and electrochemical properties of vanadium pentoxide nanotube arrays. J Phys Chem B 109(8):3085–3088. doi:10.1021/jp044286w CrossRef

Wang YQ, Li ZC, Sheng X, Zhang ZJ (2007) Synthesis and optical properties of V₂O₅ nanorods. J Chem Phys 126(16). doi:10.1063/1.2722746

Yan B, Liao L, You YM, Xu XJ, Zheng Z, Shen ZX, Ma J, Tong LM, Yu T (2009) Single-crystalline V₂O₅ ultralong nanoribbon waveguides. Adv Mater 21(23):2436. doi:10.1002/adma.200803684

Zhang SG, Higashimoto S, Yamashita H, Anpo M (1998) Characterization of vanadium oxide/ZSM-5 zeolite catalysts prepared by the solid-state reaction and their photocatalytic reactivity: in situ photoluminescence, XAFS, ESR, FT-IR, and UV-vis investigations. J Phys Chem B 102(29):5590–5594CrossRef

Zhou B, He DY (2008) Raman spectrum of vanadium pentoxide from density-functional perturbation theory. J Raman Spectrosc 39(10):1475–1481. doi:10.1002/jrs.2025 CrossRef

Zhou GT, Wang XC, Yu JC (2005) Selected-control synthesis of NaV₆O₁₅ and Na₂V₆O₁₆·3H₍₂₎O single-crystalline nanowires. Cryst Growth Des 5(3):969–974. doi:10.1021/cg0496686 CrossRef

Zhou F, Zhao XM, Yuan CG, Li L (2008) Vanadium pentoxide nanowires: hydrothermal synthesis, formation mechanism, and phase control parameters. Cryst Growth Des 8(2):723–727. doi:10.1021/cg060816x CrossRef

Titel: Local structure study of vanadium pentoxide 1D-nanostructures
verfasst von: W. Avansi
L. J. Q. Maia
C. Ribeiro
E. R. Leite
V. R. Mastelaro
Publikationsdatum: 01.10.2011
Verlag: Springer Netherlands
Erschienen in: Journal of Nanoparticle Research / Ausgabe 10/2011
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI: https://doi.org/10.1007/s11051-011-0472-2

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