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Journal of Materials Science
Erschienen in: Journal of Materials Science 11/2019

27.02.2019 | Energy materials

Low-content Ni-doped CoS2 embedded within N,P-codoped biomass-derived carbon spheres for enhanced lithium/sodium storage

verfasst von: Yajuan Lian, Weili Xin, Meng Zhang, Yaru Li, Lan Yang, Ying Guo, Sailong Xu

Erschienen in: Journal of Materials Science | Ausgabe 11/2019

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Abstract

Carbonaceous materials have been promising for further advancing the lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs), but suffer from a relatively low specific capacity. One effective improvement strategy by doping heteroatoms is typically used. Herein, a preparation of low-content (26.7 wt%) Ni-doped CoS2 embedded N,P-codoped biomass-derived carbon spheres ((Ni0.5S0.5)S2@NPCS) as anode materials for LIBs and SIBs is demonstrated by the sulfuration of Ni, Co salt-loaded yeast spheres. The resultant composite is endowed with the following advantages: N,P-codoped carbon sphere, low-content bimetallic (Ni0.5Co0.5)S2 encapsulated with graphic shell. The composite indeed delivers highly enhanced electrochemical performances (a capacity of 600 mAh g–1 at 0.5 A g–1 after 450 cycles and 480 mAh g–1 at 1 A g–1 after 200 cycles) compared with the counterparts of CoS2@NPCS and pristine carbon spheres (NPCS) for LIBs. In addition, a decent reversible capacity for SIBs is achieved. The enchantment is supported by the result of electrochemical impedance spectra. The results demonstrate the biomass-derived carbon sphere can promise the preparation of promising anodes for energy storage.
Vorheriger Artikel Low-voltage multicolor electroluminescence from all-inorganic carbon dots/Si-heterostructured light-emitting diodes
Nächster Artikel Strain-sensitivity conductive MWCNTs composite hydrogel for wearable device and near-infrared photosensor

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Metadaten
Titel
Low-content Ni-doped CoS2 embedded within N,P-codoped biomass-derived carbon spheres for enhanced lithium/sodium storage
verfasst von
Yajuan Lian
Weili Xin
Meng Zhang
Yaru Li
Lan Yang
Ying Guo
Sailong Xu
Publikationsdatum
27.02.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 11/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03416-9

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