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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 10/2018

01.10.2018 | ORIGINAL PAPER

Mathematical modelling of cobalt based composite membrane using TMS method; confirming its efficiency and selectivity

verfasst von: Aiman Zehra, Mohammad Mujahid Ali Khan, Rafiuddin

Erschienen in: Journal of Polymer Research | Ausgabe 10/2018

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Abstract

This viewpoint describes the concept of incorporating polymer into inorganic matrix to form composite material. The coupling of both the materials enhanced the electrotransport properties and hence more efficient and highly selective membrane is formed. This approach was demonstrated by introducing 25% PVC into cobalt arsenate matrix which resulted in higher chemical, mechanical and thermal stabilities confirmed by different characterization techniques such as XRD, TG/DTA, FTIR, SEM, TEM and EDS. Electrotransport properties have been evaluated and compared with a mathematical model called as TMS model which clearly indicates the good agreement between calculated and theoretical values of membrane potential. Also, fixed charge density, charge effectiveness and transport number were being calculated from the model. All the parameters found to show dependence on electrolyte concentration and applied pressure during the fabrication of membrane. Membrane potential, transport number and mobility ratio of different univalent electrolytes followed the trend as LiCl> NaCl> KCl which is in accordance with the size of cations. Fixed charge density gave the opposite trend. Membrane showed positive values of membrane potential that confirms the cation selective nature of the membrane. Thus results revealed that the synthesized membrane is a promising candidate for use in practical applications.
Vorheriger Artikel Local conformation controlled crystallization of isotactic poly(butene-1)
Nächster Artikel Preparation and characterization of modified ultrafiltration nylon 6 membrane modified by poly (acrylamide-co-maleic anhydride)

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Metadaten
Titel
Mathematical modelling of cobalt based composite membrane using TMS method; confirming its efficiency and selectivity
verfasst von
Aiman Zehra
Mohammad Mujahid Ali Khan
Rafiuddin
Publikationsdatum
01.10.2018
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 10/2018
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-018-1611-6

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