Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 13/2016

04.04.2016 | Original Paper

Metastable Co23B6 phase solidified from deeply undercooled Co79.3B20.7 alloy melt

verfasst von: X. X. Wei, W. Xu, J. L. Kang, M. Ferry, J. F. Li

Erschienen in: Journal of Materials Science | Ausgabe 13/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

M23X6 (M-transition metal, X-nonmetal) phases widely exist in alloy steels and some other multicomponent alloys, but were seldom solidified from binary alloys. In the present work, the alloy melt with the nominal composition of Co23B6 phase, Co79.3B20.7, was undercooled to different degrees, and metastable Co23B6 phase was solidified at undercooling beyond 60 K owing to its lower energy barrier to nucleation than the equilibrium Co3B phase. The Co23B6 phase formed at high temperature can be retained to room temperature if the cooling rate is larger than 25 K min−1. This phase was confirmed to be the classic Cr23C6-type structure (space group \( {\text{Fm}}\bar{3}{{\rm m}} \)) with a lattice parameter, measured by Rietveld refinement method, of a = 10.4912(1) Å.
Vorheriger Artikel Improved catalytic performance of porcine pancreas lipase immobilized onto nanoporous gold via covalent coupling
Nächster Artikel Free surface effects on rotational deformation in nanocrystalline materials

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Zheng LG, Hu XQ, Kang XH, Li DZ (2015) Precipitation of M23C6 and its effect on tensile properties of 0.3C–20Cr–11Mn–1Mo–0.35N steel. Mater Des 78:42–50CrossRef
2.
Bashev VF, Miroshnichenko IS, Sergeev GA (1981) New metastable phases of cobalt-boron, iron-boron, and nickel-boron systems. Neorg Mater 17:1206–1217
3.
Franke H, Herold U, Koester U, Rosenberg M (1978) Metastable phases in rapidly quenched iron-boron alloys. In: Cantor B (ed) Proceedings of the third international conference on rapidly quenched metals, vol. 1, p 155
4.
Khan Y, Wibbeke H (1991) Formation of the τ-phase in the iron-boron alloys. Z Metallkd 82:703–705
5.
Inal OT, Robino CV, Keller L, Yost FG, Karnowsky MM (1981) Annealing behavior of amorphous iron-boron (Fe80B20) on continuous heating. J Mater Sci 11:3183–3193. doi:10.​1007/​BF00540327 CrossRef
6.
Hirata A, Hirotsu Y, Amiya K, Nishiyama N, Inoue A (2008) Nanocrystallization of complex Fe23B6-type structure in glassy Fe–Co–B–Si–Nb alloy. Intermetallics 16:491–497CrossRef
7.
Idzikowski B, Szajek A (2003) Formation of the nanocrystalline cubic (FeNi)23B6 phase in the nickel-rich FeNiZrB alloys and its magnetic behaviour. J Optoelectron Adv Mater 5:239–244
8.
Long JG, Ohodnicki PR, Laughlin DE, McHenry ME, Ohkubo T, Hono K (2007) Structural studies of secondary crystallization products of the Fe23B6-type in a nanocrystalline FeCoB-based alloy. J Appl Phys 101:09N114
9.
Fornell J, González S, Rossinyol E, Suriñach S, Baró MD, Louzguine-Luzgin DV, Perepezko JH, Sort J, Inoue A (2010) Enhanced mechanical properties due to structural changes induced by devitrification in Fe–Co–B–Si–Nb bulk metallic glass. Acta Mater 58:6256–6266CrossRef
10.
Shapaan M, Gubicza J, Lendvai J, Varga LK (2004) Crystallization behavior of (Fe100−xCox)62Nb8B30 bulk amorphous alloy. Mater Sci Eng A 375–377:785–788CrossRef
11.
Xu JF, Liu F, Dang B (2012) Phase selection in undercooled Ni-3.3 wt% B alloy melt. Metall Mater Trans A 44:1401–1408CrossRef
12.
Liu F, Xu JG, Zhang D, Jian ZY (2014) Solidification of highly undercooled hypereutectic Ni-Ni3B alloy melt. Metall Mater Trans A 45:4810–4819CrossRef
13.
Battezzati L, Antonione C, Baricco M (1997) Undercooling of Ni-B and Fe-B alloys and their metastable phase diagrams. J Alloys Compd 247:164–171CrossRef
14.
Yang CL, Liu F, Yang GC, Chen YZ, Liu N, Zhou YH (2007) Microstructure and phase selection in bulk undercooled Fe-B eutectic alloys. J Alloys Compd 441:101–106CrossRef
15.
Yang CL, Liu F, Yang GC, Zhou YH (2009) Structure evolution upon non-equilibrium solidification of bulk undercooled Fe-B system. J Cryst Growth 311:404–412CrossRef
16.
Yang CL, Yang GC, Liu F, Chen YZ, Liu N, Chen D, Zhou YH (2006) Metastable phase formation in eutectic solidification of highly undercooled Fe83B17 alloy melt. Phys B 373:136–141CrossRef
17.
Quirinale DG, Rustan GE, Kreyssig A, Goldman AI (2015) Synergistic stabilization of metastable Fe23B6 and γ-Fe in undercooled Fe83B17. Appl Phys Lett 106:241906CrossRef
18.
Kotzott D, Ade M, Hillebrecht H (2009) Single crystal studies on Co-containing τ-borides Co23−xMxB6 (M = Al, Ga, Sn, Ti, V, Ir) and the boron-rich τ-boride Co12.3Ir8.9B10.5. J Solid State Chem 182:538–546CrossRef
19.
Ohodnicki PR, Cates NC, Laughlin DE, McHenry ME, Widom M (2008) Ab initio theoretical study of magnetization and phase stability of the (Fe Co, Ni)23B6 and (Fe Co, Ni)23Zr6 structures of Cr23C6 and Mn23Th6 prototypes. Phys Rev B 78:144414CrossRef
20.
Li MJ, Lin X, Song GS, Yang GC, Zhou YH (1999) Microstructure evolution and metastable phase formation in undercooled Fe-30 at.% Co melt. Mater Sci Eng A 268:90–96CrossRef
21.
Liu N, Liu F, Yang GC, Chen YZ, Yang CL, Zhou YH (2009) Nucleation and phase selection in undercooled Fe–Co melt. J Alloys Compd 467:L11–L15CrossRef
22.
Ojha SN (2001) Metastable phase formation during solidification of undercooled melt. Mater Sci Eng A 304–306:114–118CrossRef
23.
Christian JW (1975) The theory of transformation in metals and alloys. Pergamon Press, Oxford, p 418
24.
Spaepen F, Meyer RB (1976) The surface tension in a structural model for the solid-liquid interface. Scr Metall 10:257–263CrossRef
25.
Hirata A, Hirotsu Y, Amiya K, Nishiyama N, Inoue A (2009) Fe23B6-type quasicrystal-like structures without icosahedral atomic arrangement in an Fe-based metallic glass. Phys Rev B 80:140201CrossRef
26.
Sheng HW, Luo WK, Alamgir FM, Bai JM, Ma E (2006) Atomic packing and short-to-medium-range order in metallic glasses. Nature 439:419–425CrossRef
27.
Herlach DM, Gillessen F, Volkmann T, Wollgarten M, Urban K (1992) Phase selection in undercooled quasicrystal-forming Al-Mn alloy melts. Phys Rev B 46:5203CrossRef
28.
Holland-Moritz D, Schroers J, Herlach DM, Grushko B, Urban K (1998) Undercooling and solidification behaviour of melts of the quasicrystal-forming alloys Al–Cu–Fe and Al–Cu–Co. Acta Mater 46:1601–1615CrossRef
Metadaten
Titel
Metastable Co23B6 phase solidified from deeply undercooled Co79.3B20.7 alloy melt
verfasst von
X. X. Wei
W. Xu
J. L. Kang
M. Ferry
J. F. Li
Publikationsdatum
04.04.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 13/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-9941-4

Weitere Artikel der Ausgabe 13/2016

Journal of Materials Science 13/2016 Zur Ausgabe

Original Paper

A general method to synthesize a family of mesoporous silica nanoparticles less than 100 nm and their applications in anti-reflective/fogging coating

Original Paper

Thickness-modulated metal–insulator transition of VO2 film grown on sapphire substrate by MBE

Original Paper

Solidification microstructures in Ag3Sn–Cu3Sn pseudo-binary alloys

Original Paper

A time efficient reduction strategy for bulk production of reduced graphene oxide using selenium powder as a reducing agent

Original Paper

Modification of morphological, mechanical, optical and thermal properties in polycaprolactone-based nanocomposites by the incorporation of diacid-modified ZnO nanoparticles

Original Paper

Construction of imprint sites in mesopores of SBA-15 via thiol-ene click reaction

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise