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2021 | OriginalPaper | Buchkapitel

6. Modelling of Packed Bed Column for the Adsorption of Cu(II) Ions Using Chemically Enhanced Chitosan Beads

verfasst von : Ephraim Igberase, Peter Ogbemudia Osifo, Tumisang Seodigeng, Ikenna Emeji

Erschienen in: Enhanced Chitosan Material for Water Treatment

Verlag: Springer International Publishing

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Abstract

In this study, the removal of Cu(II) from aqueous solution using modified Chitosan as a chelating adsorbent was examined in a packed bed column. The characterization of the modified Chitosan using SEM analysis reveals orderly porous structure while BET analysis indicates that the material possesses large surface areas. Using swan model to fit the adsorption experimental data, the column breakthrough curves for the adsorption of Cu(II) ions onto the adsorbent was reasonably predicted well. The model predicted that at pH of 5.1, the diffusion coefficient was calculated to be between 2.82 × 10⁻¹⁰ and 3.12 × 10⁻¹⁰ m²/s at different bed heights. Following several adsorption and desorption cycles carried out, 5.0 and 11.0% mass loss of the beads was observed during the third and fourth cycles of adsorption and desorption cycles. The maximum adsorption capacities of the absorbent in the second, third and fourth cycles of adsorption were calculated to be 98, 91 and 86%, respectively. However, the adsorption performances of the absorbent was reduced greatly, as 22% weight loss was observed in the mass of the beads during the fifth cycle of adsorption desorption operations.

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Titel: Modelling of Packed Bed Column for the Adsorption of Cu(II) Ions Using Chemically Enhanced Chitosan Beads
verfasst von: Ephraim Igberase
Peter Ogbemudia Osifo
Tumisang Seodigeng
Ikenna Emeji
Verlag: Springer International Publishing
Buch: Enhanced Chitosan Material for Water Treatment
Print ISBN: 978-3-030-71721-6

Electronic ISBN: 978-3-030-71722-3

Copyright-Jahr: 2021
DOI: https://doi.org/10.1007/978-3-030-71722-3_6

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