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2021 | OriginalPaper | Buchkapitel

9. Molecular Designs for Solid-State Luminescent Properties and Recent Progresses on the Development of Functional Luminescent Solid Materials

verfasst von : Kazuo Tanaka, Masayuki Gon, Yoshiki Chujo

Erschienen in: Progress in the Science of Functional Dyes

Verlag: Springer Singapore

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Abstract

Luminescent organic dyes are known to be an essential building block for developing modern organic optoelectronic devices. In these devices, organic dyes are normally used as a film. However, most of the organic dyes suffer from the quenching effect induced in the condensed state, named as concentration quenching or aggregation-caused quenching (ACQ). Therefore, so far, various strategies have been proposed for overcoming ACQ. In this chapter, we survey conventional strategies for suppressing ACQ and obtaining intense solid-state emission mainly regarding boron-containing materials which are known to be a platform for designing luminescent dyes. A series of typical examples to exhibit solid-state emission are presented in each part. Initially, luminescent organic– inorganic hybrids are illustrated. ACQ is often induced through non-specific intermolecular interactions in the condensed state. In order to realize the solution-like situation where each dye molecule is isolated from each other, the transparent hybrid matrices were useful as a scaffold. Recent progresses on the development of conjugated polymer-based hybrids by employing hybrid molecules as a building block is also demonstrated. The similar strategy for isolating dye molecules is accomplished by introducing steric substituents and structures near the chromophore moiety. Particularly, this strategy is conventionally applied for obtaining luminescent polymer films. Moreover, by assembling heterogeneous types of dyes at the cardo structure in the polymer main chains, the multiple emission bands originating from each dye were able to be simultaneously observed from the film samples. These results on simultaneous multiple emission bands are explained. Next topics are regarding aggregation-induced emission (AIE)-active molecules. By suppressing molecular motions at the steric moiety, intense emission can be observed in the aggregation state. Furthermore, it was shown that emission color from some of the AIE-active molecules was sensitive to molecular distributions in the solid state. Based on these characteristics, stimuli-responsive luminochromism was obtained. Basic design strategies and recent applications are described.

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Vorheriges Kapitel Red and Near-IR Fluorescent Two-Photon Absorption Dyes

Nächstes Kapitel Circularly Polarized Luminescence (CPL) Based on Planar Chiral [2.2]Paracyclophane

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Titel: Molecular Designs for Solid-State Luminescent Properties and Recent Progresses on the Development of Functional Luminescent Solid Materials
verfasst von: Kazuo Tanaka
Masayuki Gon
Yoshiki Chujo
Verlag: Springer Singapore
Buch: Progress in the Science of Functional Dyes
Print ISBN: 978-981-334-391-7

Electronic ISBN: 978-981-334-392-4

Copyright-Jahr: 2021
DOI: https://doi.org/10.1007/978-981-33-4392-4_9