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Journal of Polymer Research
Erschienen in: Journal of Polymer Research 9/2022

01.09.2022 | Original Paper

New bioactive Co (II) coordination polymers with morphline and carboxylate ligands; Synthesis, structures, spectroscopic and thermal properties

verfasst von: Rasel. A. Mukred, Fahem. B. Yehya, Hamid. M. Al-gabr, Mohammed. A. Al Fakih

Erschienen in: Journal of Polymer Research | Ausgabe 9/2022

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Abstract

Three new bioactive nanosized supramolecular cobalt coordination polymers; {[Co2(tyr)2(Morph)2(Cl)2(H2O)2]}n (1), {[Co(Morph)6]+2[Co(bdc)(Morph)2(Cl)2]−2.3H2O}n (2) and {[Co(Morph)6]+2[Co(H2btec)(Morph)3(H2O)]−2.10H2O}n (3), where L-tyr = L-tyrosine, H2bdc = Terephthalic acid, H4btec = Pyromellitic acid and Morph = Morphline, they were prepared and characterized by elemental analysis, FT-IR and UV–VIS spectroscopies, magnetic, molar conductance, TGA/DTA, XRPD, catalytst and MM2 theoretical calculations. In all three compounds, the Morph ligand adopts a bidentate chelating coordination mode and the carboxylate anions of bdc−2 and H2btec−2 act as monodentate ligands while the tyr−1 anion act as bidentate ligand. The coordination geometry of the cobalt centers is an octahedral. The variation of carboxylates, morphline and central cobalt ions exerts a significant effect on the structures, properties and biological activity. Kinetic and thermodynamic parameters (n, E*, Z, ΔH*, ΔS* and ΔG*) were computed using Coats–Redfern equations and discussed, which confirms the second order kinetics. From the XRPD patterns, the crystal parameters as well as the particle sizes of the complexes could be evaluated. Complexes exhibit catalytic activity. The biological activity of the compounds has also been study against different bacteria and fungi.
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Metadaten
Titel
New bioactive Co (II) coordination polymers with morphline and carboxylate ligands; Synthesis, structures, spectroscopic and thermal properties
verfasst von
Rasel. A. Mukred
Fahem. B. Yehya
Hamid. M. Al-gabr
Mohammed. A. Al Fakih
Publikationsdatum
01.09.2022
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 9/2022
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-022-03193-1

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