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2018 | OriginalPaper | Buchkapitel

16. Next generation technologies

verfasst von : Prof. Juergen Janek, Prof. Philipp Adelhelm

Erschienen in: Lithium-Ion Batteries: Basics and Applications

Verlag: Springer Berlin Heidelberg

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Abstract

Rechargeable lithium-ion batteries have been continually developed since their introduction by Sony in 1991. Energy density is one of the key parameters for lithium-ion batteries. It was steadily increased by optimizing battery components such as electrode materials or electrolyte as well as by improving the cell construction technologies. The cell level progress during recent years is shown in Fig. 16.1. Both gravimetric (specific) and volumetric energy density were more than doubled.

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Nächstes Kapitel Lithium-ion cell and battery production processes

The theoretical (gravimetric) energy density is the stored chemical energy based on the pure electrode materials’ mass.

Initially, the terms “cell” and “battery” had strictly different definitions. An electrochemical cell is the smallest battery unit and consists of anode, cathode, electrolyte, separator, current collector, and housing. As opposed to that, a battery consists of at least two cells connected in series or in parallel. A 12-V lead battery for instance is made of six 2-V cells. Nowadays however, a cell is often called battery also. The electrochemical processes do not differ from cell to battery and this is why the present Chapter does not differentiate between those two terms. Specifying the practical energy densities however calls for a differentiation. All practical energy density values (with the exception of lead batteries) in this Chapter refer to cells.

The polysulfide species S_n ^2– that form at the cathode during discharging dissolve in the electrolyte there. A concentration gradient versus the anode develops, which causes the polysulfides to diffuse toward the anode. Step by step, the polysulfides are distributed in the electrolyte.

Gesamt-Roadmap Energiespeicher für die Elektromobilität 2030, Fraunhofer-Institut für System und Innovationsforschung ISI, Karlsruhe, Dezember 2015

Herbert D, Ulam J (1962) Inventors; electric dry cells and storage batteries

Nole DA, Moss V, Cordova R (1970) Inventors; battery employing lithium-sulphur electrodes with nonaqueous electrolyte

Abraham KM (1981) Status of rechargeable positive electrodes for ambient-temperature lithium batteries. J Power Sources 7(1):1 − 43MathSciNetCrossRef

Yamin H, Penciner J, Gorenshtain A, Elam M, Peled E (1985) The electrochemical-behavior of polysulfides in tetrahydrofuran. J Power Sources 14(1−3):129 − 134CrossRef

Akridge JR, Mikhaylik YV, White N (2004) Li/S fundamental chemistry and application to hig-performance rechargeable batteries. Solid State Ionics 175(1 – 4):243 – 245CrossRef

Mikhaylik YV, Akridge JR (2004) Polysulfide shuttle study in the Li/S battery system. J Electrochem Soc 151(11):A76 − A1969CrossRef

Nelson J, Misra S, Yang Y, Jackson A, Liu Y, Wang H et al (2012) In operando x-ray diffraction and transmission x-ray microscopy of lithium sulfur batteries. J Am Chem Soc 134(14):6337 – 6343CrossRef

Dominko R, Demir-Cakan R, Morcrette M, Tarascon J-M (2011) Analytical detection of soluble polysulphides in a modified Swagelok cell. Electrochem Commun 13(2):117 – 120CrossRef

10.

Kumaresan K, Mikhaylik Y, White RE (2008) A mathematical model for a lithium-sulfur cell. J Electrochem Soc 155(8):A576 − A582CrossRef

11.

Ji X, Lee KT, Nazar LF (2009) A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphur batteries. Nat Mater 8(6):500 – 506CrossRef

12.

Schneider H, Garsuch A, Panchenko A, Gronwald O, Janssen N, Novak P (2012) Influence of different electrode compositions and binder materials on the performance of lithium-sulfur batteries. J Power Sources 205:420 – 425CrossRef

13.

Cheon SE, Ko KS, Cho JH, Kim SW, Chin EY, Kim HT (2003) Rechargeable lithium sulfur battery – II. Rate capability and cycle characteristics. J Electrochem Soc 150(6):A800 – A805CrossRef

14.

Kang SH, Zhao X, Manuel J, Ahn HJ, Kim KW, Cho KK, Ahn JH (2014) Effect of sulfur loading on energy density of lithium sulfur batteries. PSSA 211(8):1895–1899

15.

Hagen M, Fanz P, Tübke J (2014) Cell energy density and electrolyte/sulfur ratio in Li-S cells. J Power Sources 264:30–34CrossRef

16.

Brückner J, Thieme S, Grossmann HT, Dörfler S, Althues H, Kaskel S (2014) Lithium-sulfur batteries: influence of C-rate, amount of electrolyte and sulfur loading on cycle performance. J Power Sources 268:82–87CrossRef

17.

Cleaver T, Kovacik P, Marinescu M, Zhang T, Offer G (2018) Perspective—commercializing lithium sulfur batteries: are we doing the right research? J Electrochem Soc 165(1):A6029–A6033CrossRef

18.

Adelhelm P, Hartmann P, Bender CL, Busche M, Eufinger C, Janek J, Beilstein J (2015) From lithium to sodium: cell chemistry of room temperature sodium–air and sodium–sulfur batteries. J Nanotechnol 6:1016–1055

19.

Hassoun J, Scrosati B (2010) A high-performance polymer tin sulfur lithium ion battery. Angewandte Chemie Int Edition 49(13):2371 – 2374CrossRef

20.

Aurbach D, Pollak E, Elazari R, Salitra G, Kelley CS, Affinito J (2009) On the surface chemical aspects of very high energy density, rechargeable li–sulfur batteries. J Electrochem Soc 156(8):A694 – A702CrossRef

21.

Jozwiuk A, Sommer H, Janek J, Brezesinski T (2015) Fair performance comparison of different carbon blacks in lithium-sulfur batteries with practical mass loadings – simple design competes with complex cathode architecture. J Power Sources 296:454–461CrossRef

22.

Medenbach L, Adelhelm P (2017) Cell concepts of metal-sulfur batteries (Metal = Li, Na, K, Mg): strategies for using sulfur in energy storage applications. Top Curr Chem 375(5):81CrossRef

23.

Lin Z, Liu Z, Fu W, Dudney NJ, Liang C (2013) Lithium Polysulfidophosphates: A Family of Lithium-Conducting Sulfur-Rich Compounds for Lithium-Sulfur Batteries. Angewandte Chemie. 125(29):7608 – 11CrossRef

24.

Yang Y, Zheng G, Cui Y (2013) A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage. Energy & Environmental Science 6(5):1552 – 8CrossRef

25.

Rauh RD, Abraham KM, Pearson GF, Surprenant JK, Brummer SB (1979) A lithium/dissolved sulfur battery with an organic electrolyte. J Electrochem Soc 126(4):523–527CrossRef

26.

Zhang SS, Read JA (2012) A new direction for the performance improvement of rechargeable lithium/sulfur batteries. J Power Sources 200:77–82CrossRef

27.

Zheng G, Cui Y (2013) A membrane-free lithium/polysulfide semi-liquid battery for large-scale energy storage. Energy Environ Sci 6:1552–1558CrossRef

28.

Fu Y, Su YS, Manthiram A (2013) Highly reversible lithium/dissolved polysulfide batteries with carbon nanotube electrodes. Angew Chem Int Edit 52(27):6930–6935CrossRef

29.

Hassoun J, Scrosati B (2010) Moving to a solid‐state configuration: a valid approach to making lithium‐sulfur batteries viable for practical applications. Adv Mater 22(45):5198–5201CrossRef

30.

Nagata H, Chikusa Y (2014) A lithium sulfur battery with high power density. J Power Sources 264:206–210CrossRef

31.

Adelhelm P, Hartmann P, Bender CL, Busche M, Eufinger C, Janek J (2015) From lithium to sodium: cell chemistry of room temperature sodium–air and sodium–sulfur batteries. Beilstein J Nanotechnol 6:1016–1055CrossRef

32.

Abraham KM, Jiang Z (1996) A polymer electrolyte-based rechargeable lithium/oxygen battery. J Electrochem Soc 143(1):1 – 5CrossRef

33.

Read J (2002) Characterization of the lithium/oxygen organic electrolyte battery. J Electrochem Soc 149(9):A1190 – A1195CrossRef

34.

Sawyer DT, Valentine JS (1981) How super is superoxide. Acc Chem Res 14(12):393 − 400CrossRef

35.

Aurbach D, Daroux M, Faguy P, Yeager E (1991) The electrochemistry of noble-metal electrodes in aprotic organic-solvents containing lithium-salts. J Electroanal Chem 297(1):225 – 244CrossRef

36.

Mizuno F, Nakanishi S, Kotani Y, Yokoishi S, Iba H (2010) Rechargeable Li-air batteries with carbonate-based liquid electrolytes. Electrochem 78(5):403 – 405CrossRef

37.

Freunberger SA, Chen Y, Peng Z, Griffin JM, Hardwick LJ, Barde F et al (2011) Reactions in the rechargeable Li-O₂ battery with alkyl carbonate electrolytes. J Am Chem Soc 133(20):8040 – 8047CrossRef

38.

McCloskey BD, Scheffler R, Speidel A, Bethune DS, Shelby RM, Luntz AC (2011) On the efficacy of electrocatalysis in nonaqueous Li-O₂ batteries. J Am Chem Soc 133(45):18038 – 18041CrossRef

39.

Peng ZQ, Freunberger SA, Chen YH, Bruce PG (2012) A Reversible and Higher-Rate Li-O₂ Battery. Science. 337(6094):563 – 6.CrossRef

40.

Chase GV, Zecevic S, Walker W, Uddin J, Sasaki KA, Giordani V, Bryantsev V, Blanco M, Addison D (2011) US Patent Application No 20120028137 A1 2011

41.

Hase Y, Shiga T, Nakano M, Takechi K, Setoyama N (2009) US Patent Application No US 2009/0239113 A1 2009

42.

Chen Y, Freunberger SA, Peng Z, Fontaine O, Bruce PG (2013) Charging a Li–O₂ battery using a redox mediator. Nat Chem 5:489–494CrossRef

43.

Lim HD, Song H, Kim J, Gwon H, Bae Y, Park KY, Hong J, Kim H, Kim T, Kim YH, Lepró X, Ovalle-Robles R, Baughman R, Kang K (2014) Superior rechargeability and efficiency of lithium–oxygen batteries: hierarchical air electrode architecture combined with a soluble catalyst. Angew Chem Int Ed Engl 53(15):3926–3931CrossRef

44.

Bergner BJ, Schürmann A, Peppler K, Garsuch A, Janek J (2014) TEMPO: a mobile catalyst for rechargeable Li-O₂ batteries. J Am Chem Soc 136(42):15054–15064CrossRef

45.

Feng N, Mu X, Zhang X, He P, Zhou H (2017) Intensive study on the catalytical behavior of N-methylphenothiazine as a coluble mediator to oxidize the Li₂O₂ cathode of the Li–O₂ battery. ACS Appl Mater Interfaces 9(4):3733–3739CrossRef

46.

Liang Z, Lu YC (2016) Critical role of redox mediator in suppressing charging instabilities of lithium–oxygen batteries. J Am Chem Soc 138(24):7574–7583CrossRef

47.

Aetukuri NB, McCloskey BD, Garcia JM, Krupp LE, Viswanathan V, Luntz AC (2015) Solvating additives drive solution-mediated electrochemistry and enhance toroid growth in non-aqueous Li–O₂ batteries. Nat Chem 7:50–56CrossRef

48.

Meini S, Piana M, Tsiouvaras N, Garsuch A, Gasteiger HA (2012) The effect of water on the discharge capacity of a non-catalyzed carbon cathode for Li-O₂ batteries. Electrochem Solid-State Lett 15(4):A45–A48CrossRef

49.

Schwenke KU, Metzger M, Restle T, Piana M, Gasteiger HA (2015) The influence of water and protons on Li₂O₂ crystal growth in aprotic Li-O₂ cells. J Electrochem Soc 162(4):A573–A584CrossRef

50.

Li F, Wu S, Li D, Zhang T, He P, Yamada A, Zhou H (2015) The water catalysis at oxygen cathodes of lithium–oxygen cells. Nat Commun 6:7843CrossRef

51.

Xia C, Black R, Fernandes R, Adams B, Nazar LF (2015) The critical role of phase-transfer catalysis in aprotic sodium oxygen batteries. Nat Chem 7:496–501CrossRef

52.

Hartmann P, Bender CL, Vracar M, Dürr AK, Garsuch A, Janek J, Adelhelm P (2013) A rechargeable room-temperature sodium superoxide (NaO₂) battery. Nat Mater 12:228 – 232CrossRef

53.

http://www.ibm.com/smarterplanet/us/en/smart_grid/article/battery500.html

54.

de Jonghe LC et al (2007) inventors; protected active metal electrode and battery cell structures with non-aqueous interlayer architecture

55.

Peled E, Menkin S (2017) Review—SEI: past, present and future. J Electrochem Soc 164(7):A1703–A1719CrossRef

56.

Aurbach D et al (2009) On the surface chemical aspects of very high energy density, rechargeable Li-sulfur batteries. J Electrochem Soc 156(8):A694 − A702CrossRef

57.

Brandt K (1994) Historical development of secondary lithium batteries. Solid State Ionics.69(3 – 4):173 – 183CrossRef

58.

Monroe C, Newman J (2005) The impact of elastic deformation on deposition kinetics at lithium/polymer interfaces. J Electrochem Soc 152(2):A396 – A404CrossRef

59.

Li W, Yao H, Yan K, Zheng G, Liang Z, Chiang Y-M, Cui Y (2015) The synergetic effect of lithium polysulfide and lithium nitrate to prevent lithium dendrite growth. Nat Commun 6:7436.CrossRef

60.

Ding F, Xu W, Graff GL, Zhang J, Sushko ML, Chen X, Shao Y, Engelhard MH, Nie Z, Xiao J, Liu X, Sushko PV, Liu J, Zhang J-G (2013) Dendrite-free lithium deposition via self-healing electrostatic shield mechanism. J Am Chem Soc 135(11):4450–4456.CrossRef

61.

Suo L, Hu Y-S, Li H, Armand M, Chen L (2013) A new class of solvent-in-salt electrolyte for high-energy rechargeable metallic lithium batteries. Nat Commun 4.

62.

Qian J, Henderson WA, Xu W, Bhattacharya P, Engelhard M, Borodin O, Zhang J-G (2015) High rate and stable cycling of lithium metal anode. Nat Commun 6.

63.

Khurana R, Schaefer JL, Archer LA, Coates GW (2014) Suppression of lithium dendrite growth using cross-linked polyethylene/poly(ethylene oxide) electrolytes: a new approach for practical lithium-metal polymer batteries. J Am Chem Soc 136(20):7395–7402.CrossRef

64.

Yang Y, McDowell MT, Jackson A, Cha JJ, Hong SS, Cui Y (2010) New nanostructured Li₂S/Silicon rechargeable battery with high specific energy. Nano Lett 10(4):1486 – 1491CrossRef

65.

Elazari R, Salitra G, Gershinsky G, Garsuch A, Panchenko A, Aurbach D (2012) Rechargeable lithiated silicon–sulfur (SLS) battery prototypes. Electrochem Commun 14(1):21 – 24CrossRef

66.

Handbook of Solid State Batteries, 2nd ed., Dudney N J, West W C, Nanda J (Eds.), World Scientific 2015

67.

Janek J, Zeier W (2016) A solid future for battery development. Nat Energy 1(9):16141

68.

Luntz A C, Voss J, Reuter K (2015) Interfacial challenges in solid-state Li ion batteries. J Phys Chem Lett 6:4599–4604CrossRef

69.

Robinson A L, Janek J (2014) Solid-state batteries enter EV fray. MRS Bulletin 39:1046CrossRef

70.

Kato, Y. et al. (2016) High-power all-solid-state batteries using sulfide superionic conductors. Nat Energy 1:16030

71.

Oh G, Hirayama M, Kwon O, Suzuki K, Kanno R (2016) Bulk-type all solid-state batteries with 5 V class LiNi_0.5Mn_1.5O₄ cathode and Li₁₀GeP₂S₁₂ solid electrolyte. Chem Mater 28:2634–2640

72.

Bachman JC, Muy S, Grimaud A, Chang HH, Pour N, Lux SF, Paschos O, Maglia F, Lupart S, Lamp P, Giordano L, Shao-Horn Y (2016) Inorganic solid-state electrolytes for lithium batteries: mechanisms and properties governing ion conduction. Chem Rev 116(1):140–162

73.

Minami T, Hayashi A, Tatsumisago M (2006) Recent progress of glass and glass-ceramics as solid electrolytes for lithium secondary batteries. Solid State Ionics 177:2715–2720CrossRef

74.

Wenzel S, Weber D, Leichtweiss T, Sann J, Janek J (2016) Interphase formation and degradation of charge transfer kinetics between a lithium metal anode and highly crystalline Li₇P₃S₁₁ solid electrolyte. Solid State Ionics 286:24–33CrossRef

75.

Zhu Y, He X, Mo Y (2015) Origin of outstanding stability in the lithium solid electrolyte materials: insights from thermodynamic analyses based on first-principles calculations. ACS Appl Mater Interface 7:23685–23693CrossRef

Titel: Next generation technologies
verfasst von: Prof. Juergen Janek
Prof. Philipp Adelhelm
Verlag: Springer Berlin Heidelberg
Buch: Lithium-Ion Batteries: Basics and Applications
Print ISBN: 978-3-662-53069-6

Electronic ISBN: 978-3-662-53071-9

Copyright-Jahr: 2018
DOI: https://doi.org/10.1007/978-3-662-53071-9_16