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Erschienen in:
The Monoanionic ECE-Pincer Ligand: A Versatile Privileged Ligand Platform—General Considerations Kapitel lesen Erstes Kapitel lesen

2013 | OriginalPaper | Buchkapitel

Noninnocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes

verfasst von : Elena Poverenov, David Milstein

Erschienen in: Organometallic Pincer Chemistry

Verlag: Springer Berlin Heidelberg

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Abstract

Pincer complexes are generally viewed as stable compounds in which the pincer ligand framework remains unchanged during stoichiometric and catalytic reactions. However, there are now several cases in which the pincer ligand itself undergoes transformations that result in extraordinary reactivity of the metal complex and formation of unusual species. In the current chapter, we review our work on “noninnocent” reactivity modes of various PCP and PCN-type pincer ligands of Rh, Ir, Ru, Os, Pd, and Pt. Participation of the arene ring in the reactivity of PCP type complexes has led to formation of unprecedented quinonoid complexes, including complexes in which the pincer ligand adopts structures of quinone methides, thio-quinone methides, xylylenes, methylene arenium, and oxo-arenium compounds. In addition, pincer systems can collapse and be regenerated under redox conditions, and reduction can lead to a ring-localized radical anion complex. The generation of C–H agostic arene PCP complexes has led to new insights regarding the C–H bond activation process, and the effect of CO ligands on it.

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Vorheriges Kapitel The Monoanionic ECE-Pincer Ligand: A Versatile Privileged Ligand Platform—General Considerations
Nächstes Kapitel Tuning of PCP Pincer Ligand Electronic and Steric Properties
Fußnoten
1
We are aware of two examples of completely nonplanar (rather than distorted square planar) Pd(II)L4 complexes, only one of them being diamagnetic [112, 113].
 
2
A mechanism involving organic halide oxidative addition to generate dibenzyl or biphenyl is also possible. See, for example [114].
 
3
In analogy to nonchelating systems, where reduction of PtCl2L2 (L = bulky tert-phosphines) with Na/Hg in THF affords PtL2 complexes, while reduction of PdCl2L2 (L = bulky tert-phosphines) with Na/Hg in THF resulted in formation of metallic palladium. The reduction was achieved only when excess phosphine was used. See [116] and references therein.
 
4
For nonisolated, anionic palladium(0) intermediates, and their involvement in oxidative addition reactions, see [119, 120].
 
5
Very unstable, not isolated [144].
 
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Metadaten
Titel
Noninnocent Behavior of PCP and PCN Pincer Ligands of Late Metal Complexes
verfasst von
Elena Poverenov
David Milstein
Copyright-Jahr
2013
Verlag
Springer Berlin Heidelberg
Buch
Organometallic Pincer Chemistry

Print ISBN: 978-3-642-31080-5

Electronic ISBN: 978-3-642-31081-2

Copyright-Jahr: 2013

DOI
https://doi.org/10.1007/978-3-642-31081-2_2

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