Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Polymer Research
Erschienen in: Journal of Polymer Research 7/2019

01.07.2019 | ORIGINAL PAPER

Oxygen barrier, free volume and miscibility properties of fully bio-based polyamide 1010/poly(vinyl alcohol) blends

verfasst von: Lei Sun, Hong-bo Li, Ya-qiong Huang, Jia-wei Wu, James Runt, Mu-chen Kuo, Kuo-shien Huang, Jen-taut Yeh

Erschienen in: Journal of Polymer Research | Ausgabe 7/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Fully bio-based polyamide 1010 (PA1010) was successfully melt-blended with poly (vinyl alcohol) (PVA03, PVA05, PVA08 and PVA14) to prepare PA1010xPVAzy blends. The PA1010xPVA03y, PA1010xPVA05y, PA1010xPVA08y and PA1010xPVA14y films demonstrated the lowest oxygen transmission rates (OTR), free volume fraction (Fv), mean volume of the free volume holes (Vf) and mean number of free volume holes per unit volume (I3) values, when the PVA concentration in each PA1010xPVAzy series reached a corresponding critical value of 22.5, 20, 17.5 and 12.5 wt%, respectively. OTR, Fv, Vf and I3 values obtained for the best PA101087.5PVA1412.5, PA101082.5PVA0817.5, PA101080PVA0520 and PA101077.5PVA032.25 films reduced gradually as the degree of polymerization of PVA reduced. The results of dynamical mechanical and other experimental characterizations demonstrated that PA1010 and PVA are compatible to some extent, when the PVA are ≤ the corresponding critical concentration. The significantly enhanced oxygen permeation resistance and free volume characteristics for optimal PA1010xPVAzy films is at least partly due to the improved hydrogen-bonded molecular interactions between PA1010 C=O groups and PVA O-H groups.
Vorheriger Artikel Synthesized and mesomorphic properties of cholesterol end-capped poly(ε-caprolactone) polymers
Nächster Artikel Synthesis of post-metallocene catalyst and study of its olefin polymerization activity at room temperature in aqueous solution followed by prediction of yield

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Anuar Sharuddin SD, Abnisa F, Wan Dsud MMA, Aroua MK (2016) A review on pyrolysis of plastic wastes. Energy Convers Manag 115:308–326CrossRef
2.
3.
Kawai F (2006) In: microbial and Eznymatic bioproducts. Springer, Berlin, Heidelberg
4.
Winnacker M, Rieger B (2016) Biobased Polyamides: Recent Advances in Basic and Applied Research. Rapid Commun 37:1391–1413CrossRef
5.
Brehmer B, Boom RM, Sanders J (2009) Maximum fossil fuel feedstock replacement potential of petrochemicals via biorefineries. Chem Eng Res Des 87:1103–1119CrossRef
6.
Pai FC, Lai SM, Chu HH (2013) Characterization and Properties of Reactive Poly(lactic acid)/Polyamide 610 Biomass Blends. J Appl Polym Sci 130:2563–2571CrossRef
7.
Funk I, Rimmel N, Schorsch C, Sieber V, Schmid J (2017) Production of dodecanedioic acid via biotransformation of low cost plant-oil derivatives using Candida tropicalis. J Ind Microbiol Biotechnol 44:1491–1502CrossRef
8.
Dayrit FM (2015) The Properties of Lauric Acid and Their Significance in Coconut Oil. J Am Oil Chem Soc 92:1–15CrossRef
9.
Green KD, Turner MK, Woodley JM (2000) Candida cloacae oxidation of long-chain fatty acids to dioic acids. Enzym Microb Technol 27:205–211CrossRef
10.
Koulouri EG, Kallitsis JK (1998) Miscibility behavior of Poly(vinyl alcohol)/Nylon 6 blends and their reactive blending with Poly(ethylene-co-ethyl acrylate). Polymer 39:2373–2379CrossRef
11.
Lai SM, Liu YH, Huang CT, Huang CT, Don TM (2017) Miscibility and toughness improvement of poly(lactic acid)/poly(3-Hydroxybutyrate) blends using a melt-induced degradation approach. J Polym Res 24(7):102–113CrossRef
12.
Zhao Y, Chen GJ, Xiao M, SJ W (2016) Biodegradable PPC/(PVA-TPU) ternary blend blown films with enhanced mechanical properties. J Polym Res 23(4):80–89CrossRef
13.
Cui L, Yeh JT, Wang K, Fu Q (2008) Miscibility and isothermal crystallization behavior of polyamide 6/poly(vinyl alcohol) blend. J Polym Sci Polym Phys 46:1360–1368CrossRef
14.
Cui L, Fu Q, Chang CJ, Qiang C, Chang J, Yeh JT (2009) The effect of poly(vinyl alcohol) hydrolysis on the properties of its blends with nylon 6. Polym Eng Sci 49:1553–1561CrossRef
15.
Yeh JT, Xu P, Tsai FC (2007) Blending properties of poly(vinyl alcohol) and nylon 6-clay nanocomposite blends. J Mater Sci 42:6590–6599CrossRef
16.
Griehl W, Ruestem D (1970) Nylon-12-Preparation, Properties, and Applications. Ind Eng Chem 62(3):16–22CrossRef
17.
Huang YQ, Wu JW, Li G, Li HB, Wang DW, Runt J, Yeh JT (2018) Oxygen barrier, free volume, and blending properties of polyamide 12/poly (vinyl alcohol) blends. Polym Adv Technol 29:1649–1660CrossRef
18.
Li HB, Wu JW, Huang YQ, Runt J, Huang CM, Huang KS, Yeh JT (2019). J Polym Res In press
19.
Wu JW, Huang YQ, Li HB, Runt J, Yeh JT (2018) Properties of polyamide 6,10/poly(vinyl alcohol) blends and impact on oxygen barrier performance. Polym Int 67:453–462CrossRef
20.
Tao SJ (1972) Positronium Annihilation in Molecular Substances. J Chem Phys 56:5499–5410CrossRef
21.
Nakanishi H, Wang SJ, Jean YC (1988) Positron annihilation in fluids. World Scientific, Singapore
22.
Deng Q, Sundar CS, Jean YC (1992) Pressure dependence of free-volume hole properties in an epoxy polymer. J Phys Chem 96:492–495CrossRef
23.
Wang YY, Nakanishi H, Jean YC, Sandreczki TC (1990) Positron annihilation in amine-cured epoxy polymers—pressure dependence. J Polym Sci Polym Phys Ed 28:1431–1441CrossRef
24.
Gao G, Wang JY, Yin JH, Yu XQ, Ma RT, Tang XY, Yin ZH, Zhang XM (2015). J Appl Polym Sci 72:683–688CrossRef
25.
Probst O, Moore EM, Resasco DE, Grad BP (2004) Nucleation of polyvinyl alcohol crystallization by single-walled carbon nanotubes. Polymer 45:4437–4443CrossRef
26.
27.
Li Y, Bao YZ, Feng Z, Zhang A (2010). J Appl Polym Sci 83:2749–2754CrossRef
28.
Holland BJ, Hay JN (2002) The thermal degradation of poly(vinyl acetate) measured by thermal analysis–Fourier transform infrared spectroscopy. Polymer 43:2207–2211CrossRef
29.
Holland BJ, Hay JN (2001) The thermal degradation of poly(vinyl alcohol). Polymer 42:6775–6783CrossRef
30.
Chen Z, Huang W, Fang PF, Yu W, Wang SJ, Xiong J, Xu YS (2010) The hydrogen bond and free volume property of poly(ether-urethane) irradiated by neutron. J Polym Sci Polym Phys 48(3):381–388CrossRef
31.
Cerrada ML, Perez E (1998) Wide-Angle X-ray Diffraction Study of the Phase Behavior of Vinyl Alcohol−Ethylene Copolymers. Macromolecules 31:2559–2564CrossRef
32.
Metadaten
Titel
Oxygen barrier, free volume and miscibility properties of fully bio-based polyamide 1010/poly(vinyl alcohol) blends
verfasst von
Lei Sun
Hong-bo Li
Ya-qiong Huang
Jia-wei Wu
James Runt
Mu-chen Kuo
Kuo-shien Huang
Jen-taut Yeh
Publikationsdatum
01.07.2019
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 7/2019
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-019-1819-0

Weitere Artikel der Ausgabe 7/2019

Journal of Polymer Research 7/2019 Zur Ausgabe

ORIGINAL PAPER

Devulcanization of natural rubber compounds by extrusion using thermoplastics and characterization of revulcanized compounds

ORIGINAL PAPER

A novel blend material to improve the crystallization and mechanical properties of poly (ethylene terephthalate)

ORIGINAL PAPER

Preparation and properties of nanocomposites composed of a water-soluble nylon and chitin nanofibers

ORIGINAL PAPER

Molecular design, synthesis and characterization of intrinsically black polyimide films with high thermal stability and good electrical properties

ORIGINAL PAPER

Synthesized and mesomorphic properties of cholesterol end-capped poly(ε-caprolactone) polymers

ORIGINAL PAPER

Polyamide 6 and thermoplastic polyurethane recycled hybrid Fibres via twin-screw melt extrusion

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise