Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 17/2017

25.05.2017 | Metals

Phenanthroline-based ruthenium complexes for enhanced charge transportation in solvent-free ionic liquid electrolyte

verfasst von: Jonnalagadda Gopinath, Kyung Hee Park, Seok-Jae Kim, Vundadi Santosh, Annadanam V. Sesha Sainath, Marshal Dhayal

Erschienen in: Journal of Materials Science | Ausgabe 17/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In the present work, we synthesized a series of 1,10-phenanthroline-based ruthenium complexes (PRCs). The PRCs were characterized by 1H and 13C NMR, UV–Vis and fluorescence spectroscopic analyses. Further, we used these PRCs complexes as effective additives in ionic liquid (IL) electrolyte to enhance current conduction in electrochemical cells. Anodic peak current in cyclic voltammetry response of PRCs showed functional group dependence on the nature of ruthenium complex. Mono-propenyl-functionalized PRC additive in IL electrolyte exhibited relatively higher current density, lower charge transfer resistance and decreased impedance compared to the tri-propenyl-functionalized PRC as well as without functional groups on 1,10-phenanthroline ligand in Ru complex. Finally, the PRCs as additives in IL electrolyte were tested in dye-sensitized solar cell which showed an increase of 65% in the efficiency when mono-propenyl-functionalized PRC complex was used as an additive.
Vorheriger Artikel Kinetics of intermetallic phase growth and determination of diffusion coefficients in solid–solid-state reaction between Cu and (Sn+1at.%Ni) pads
Nächster Artikel Enhancing the mechanical properties of high strain rate rolled Mg–6Zn–1Mn alloy by pre-rolling

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
O’Regan B, Grätzel M (1991) A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 353:737–740CrossRef
2.
Mathew S, Yella A, Gao P, Humphry-Baker R, Curchod BFE, Ashari-Astani N, Tavernelli I, Rothlisberger U, Nazeeruddin MK, Grätzel M (2014) Dye-sensitized solar cells with 13% efficiency achieved through the molecular engineering of porphyrin sensitizers. Nat Chem 6:242–247CrossRef
3.
Koval CA, Howard JN (1992) Electron transfer at semiconductor electrode-liquid electrolyte interfaces. Chem Rev 92(3):411–433CrossRef
4.
Su'ait MS, Rahman MYA, Ahmad A (2015) Review on polymer electrolyte in dye-sensitized solar cells (DSSCs). Sol Energy 115:452–470CrossRef
5.
Park KH, Park DW, Dhayal M, Gu HB (2008) Electrochemical properties of liquid electrolyte added quasi-solid state TiO2 dye-sensitized solar cells. Electrochem Commun 10(7):1098–1100CrossRef
6.
Singh PK, Kim KI, Park NG, Rhee HW (2007) Dye sensitized solar cell using polymer electrolytes based on poly(ethylene oxide) with an ionic liquid. Adv Polym Emerg Technol 249–250(1):162–166
7.
Kohle O, Gratzel M, Meyer AF, Meyer TB (1997) The photovoltaic stability of bis(isothiocyanato)ruthenium(11)-bis-2,2′-bipyridine-4,4-dicarboxylic acid and related sensitizers. Adv Mater 9:904–906CrossRef
8.
Stathatos E (2012) Dye sensitized solar cells: a new prospective to the solar to electrical energy conversion. Issues to be solved for efficient energy harvesting. J Eng Sci Technol Rev 5:9–13
9.
Adeloye AO, Olomola TO, Adebayo AI, Ajibade PA (2012) A high molar extinction coefficient bisterpyridyl homoleptic Ru(II) complex with trans-2-methyl-2-butenoic acid functionality: potential dye for dye-sensitized solar cell. Int J Mol Sci 13:3511–3526CrossRef
10.
Sun Y, Collins SN, Joyce LE, Turro C (2010) Unusual photophysical properties of a ruthenium(II) complex related to [Ru(bpy)2(dppz)]2. Inorg Chem 49:4257–4262CrossRef
11.
Grätzel M (2001) Molecular photovoltaics that mimic photosynthesis. Pure Appl Chem 173:459–467
12.
Juris A, Balzani V, Barigelletti F, Campagna S, Belser P, Zelewsky AVV (1988) Ru(II) polypyridine complexes: photophysics, photochemistry, eletrochemistry and chemiluminescence. Coord Chem Rev 84:85–277CrossRef
13.
Balzani V, Juris A, Venturi M, Campagna S, Serroni S (1996) Luminescent and redox-active polynuclear transition metal complexes. Chem Rev 96:759–833CrossRef
14.
Cola LD, Belser P (1998) Photoinduced energy and electron transfer processes in rigidly bridged dinuclear Ru/Os complexes. Coord Chem Rev 177:301–346CrossRef
15.
Kaes C, Katz A, Hosseini MW (2000) Bipyridine: the most widely used ligand. A review of molecules comprising at least two 2,2′-bipyridine units. Chem Rev 100:3553–3590CrossRef
16.
Chao H, Ji LN (2005) DNA Interactions with ruthenium(II) polypyridine complexes containing asymmetric ligands. Bioinorg Chem Appl 3:15–28CrossRef
17.
Vos JG, Kelly JM (2006) Ruthenium polypyridyl chemistry; from basic research to applications and back again. Dalton Trans. 41:4869–4883CrossRef
18.
Katayama Y, Yoshihara M, Miura T (2015) Electrochemical reaction of tris(1,10-phenanthroline)iron complexes in some amide-type ionic liquids. J Electrochem Soc 162:H501–H506CrossRef
19.
Bencini A, Lippolis V (2010) 1,10-Phenanthroline: a versatile building block for the construction of ligands for various purposes. Coord Chem Rev 254:2096–2180CrossRef
20.
21.
Yang C, Xu J, Chen W, Lu M, Li Y, Wang X (2014) A novel colorimetric and fluorescent sensor for fluoride detection based on a three-arm phenanthroline derivative. J Mater Sci 49:7040–7048. doi:10.​1007/​s10853-014-8409-7 CrossRef
22.
Xiao L, Lan H, Kido J (2007) Highly efficient electron-transporting phenanthroline derivatives for electroluminescent devices. Chem Lett 36:802–803CrossRef
23.
Li YJ, Sasabe H, Su SJ, Tanaka D, Takeda T, Pu YJ, Kido J (2009) Phenanthroline derivatives for electron-transport layer in organic light-emitting devices. Chem Lett 38:712–713CrossRef
24.
Yang J, Gordon KC (2005) Organic light-emitting devices using ruthenium (II) (4,7-diphenyl–1,10-phenanthroline)3 as dopant. Synth Met 152:213–216CrossRef
25.
Accorsi G, Listorti A, Yoosaf K, Armaroli N (2009) 1,10-Phenanthrolines: versatile building blocks for luminescent molecules, materials and metal complexes. Chem Soc Rev 38:1690–1700CrossRef
26.
Karki L, Hupp JT (1997) Electroabsorption studies of metal-to-ligand charge transfer in Ru(phenanthroline)3 2+: evidence for intrinsic charge localization in the initially formed excited state. Inorg Chem 36:3318CrossRef
27.
Omberg KM, Schoonover JR, Bernhard S, Moss JA, Treadway JA, Kober EM, Dyer RB, Meyer TJ (1998) Mid-infrared spectrum of [Ru(phen)3]2+. Inorg Chem 37:3505–3508CrossRef
28.
Winkler K, McKnight N, Fawcett WR (2000) Electron transfer kinetics of tris(1,10-phenanthroline)ruthenium(II) electrooxidation in aprotic solvents. J. Phys. Chem. B. 104:3575–3580CrossRef
29.
Li X, Gui J, Yang H, Wu W, Li F, Tian H, Huang C (2008) A new carbazole-based phenanthrenyl ruthenium complex as sensitizer for a dye-sensitized solar cell. Inorg Chim Acta 361:2835–2840CrossRef
30.
Hara K, Sugihara H, Tachibana Y, Islam A, Yanagida M, Sayama K, Arakawa H (2001) Dye-sensitized nanocrystalline TiO2 solar cells based on ruthenium(II) phenanthroline complex photosensitizers. Langmuir 17:5992–5999CrossRef
31.
Sugihara H, Singh LP, Sayama K, Arakawa H, Nazeeruddin MdK, Gratzel M (1998) Efficient photosensitization of nanocrystalline TiO2 films by a new class of sensitizer: cis-dithiocyanato bis(4,7-dicarboxy–1,10-phenanthroline)ruthenium(II). Chem Lett 27:1005–1006CrossRef
32.
Yanagida M, Singh LP, Sayama K, Hara K, Katoh R, Islam A, Sugihara H, Arakawa H, Nazeerddin MdK, Gratzel M (2000) A new efficient photosensitizer for nanocrystalline solar cells: synthesis and characterization of cis-bis(4,7-dicarboxy–1,10-phenanthroline)dithiocyanato ruthenium(II). Chem. Soc Dalton Trans 16:2817–2822CrossRef
33.
Wu KL, Huckaba AJ, Clifford JN, Yang YW, Yella A, Palomares E, Grätzel M, Chi Y, Nazeeruddin MK (2016) Molecularly engineered Ru(II) sensitizers compatible with cobalt(II/III) redox mediators for dye-sensitized solar cells. Inorg Chem 55:7388–7395CrossRef
34.
Colombo A, Dragonetti C, Magni M, Roberto D, Demartin F, Caramori S, Bignozzi CA (2014) Efficient copper mediators based on bulky asymmetric phenanthrolines for DSSCs. ACS Appl Mater Interfaces 6:13945–13955CrossRef
35.
Teramoto K, Nishide T, Okumura S, Takao K, Ikeda Y (2014) Studies on metal complexes as active materials in redox-flow battery using ionic liquids as electrolyte: electrochemical properties of [Fe(L)x][Tf2 N]2 (L: multidentate ligands, x = 2 or 3) in 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)Imide, [BMI][Tf2 N]. Electrochemistry 82:566–572CrossRef
36.
Rong Y, Ku Z, Li X, Han H (2015) Transparent bifacial dye-sensitized solar cells based on an electrochemically polymerized organic counter electrode and an iodine-free polymer gel electrolyte. J Mater Sci 50:3803–3811. doi:10.​1007/​s10853-015-8945-9 CrossRef
37.
Magni M, Giannuzzi R, Colombo A, Cipolla PM, Dragonetti C, Caramori S, Carli S, Grisorio R, Suranna GP, Bignozzi CA, Roberto D, Manca M (2016) Tetracoordinated bis-phenanthroline copper-complex couple as efficient redox mediators for dye solar cells. Inorg Chem 55:5245–5253CrossRef
38.
Onguna MZ, Oterb O, Sabancıc G, Ertekinb K, Celikd E (2013) Enhanced stability of ruthenium complex in ionic liquid doped electrospun fibers. Sens Actuators B 183:11–19CrossRef
39.
Santiago FF, Bisquert J, Palomares E, Otero L, Kuang D, Zakeeruddin MS, Graltzel M (2007) Correlation between photovoltaic performance and impedance spectroscopy of dye-sensitized solar cells based on ionic liquids. J Phys Chem C 111:6550–6560CrossRef
40.
Bhuiyan AA, Kudo S, Bartlett J (2010) Synthesis and characterization of ruthenium complexes containing chlorophenanthroline and bipyridine. J Ark Acad Sci 64:33–40
41.
Tzalis D, Tor Y, Failla S, Siegel JS (1995) Simple one-step synthesis of 3-bromo and 3,8-dibromo–1,10-phenanthroline: fundamental building blocks in the design of metal chelates. Tetrahedron Lett 36:3489–3490CrossRef
42.
Langle SL, Abarbri M, Thibonnet J, Duchêne A (2009) Stille coupling made easier–the synergic effect of copper(I) salts and the fluoride ion. J Organomet Chem 694:2368–2374CrossRef
43.
Simon PHM, Lee V, Baldwin JE (2004) Stille Coupling made easier—the synergic effect of copper(I) salts and the fluoride ion. Angew Chem Int Ed 43:1132–1135CrossRef
44.
Denti G, Campagna S, Sabatino L, Serroni S, Ciano M, Balzani V (1990) Luminescent and redox-reactive building blocks for the design of photochemical molecular devices: mono-, di-, tri-, and tetranuclear ruthenium(II) polypyridine complexes. Inorg Chem 29:4750–4758CrossRef
45.
Cheng F, Yu S, Ren M, He C, Yin H (2016) Di- and trinuclear Ru(II) complexes of 1,10-phenanthroline and 2,2′-bipyridine derivatives; synthesis, photophysical and electrochemical properties. Transit Met Chem 41:305–314CrossRef
46.
Kalyanasundaram K, Nazeeruddin MdK (1990) Photophysics and photoredox reactions of ligand-bridged binuclear polypyridyl complexes of ruthenium(II) and of their monomeric analogs. Inorg Chem 29:1888–1897CrossRef
47.
Ruffray K, Autillo M, Goff XL, Maynadie J, Meyer D (2016) Influence of the solvent, structure and substituents of ruthenium(II) polypyridyl complexes on their electrochemical and photo-physical properties. Inorg Chim Acta 440:26–37CrossRef
48.
Pattar VP, Nandibewoor ST (2016) Electrochemical studies for the determination of an antibiotic drug, d-cycloserine, in pharmaceutical and human biological samples. J Taibah Univ Sci 10:92–99CrossRef
Metadaten
Titel
Phenanthroline-based ruthenium complexes for enhanced charge transportation in solvent-free ionic liquid electrolyte
verfasst von
Jonnalagadda Gopinath
Kyung Hee Park
Seok-Jae Kim
Vundadi Santosh
Annadanam V. Sesha Sainath
Marshal Dhayal
Publikationsdatum
25.05.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 17/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1207-2

Weitere Artikel der Ausgabe 17/2017

Journal of Materials Science 17/2017 Zur Ausgabe

Polymers

Effect of TEMPO oxidation of flax fibers on the grafting efficiency of silane coupling agents

Chemical routes to materials

Rational synthesis and tailored optical and magnetic characteristics of Fe3O4–Au composite nanoparticles

Ceramics

Static and dynamic compression strength of hot-pressed boron carbide using a dumbbell-shaped specimen

Energy materials

Facile synthesis of nitrogen-doped porous carbons for CO2 capture and supercapacitors

Composites

Friction and wear on hard alloy coatings of the Cr3C2–Ti system over silicified graphite in water

Polymers

Effect of fabric weaves on the dynamic response of two-dimensional woven fabric composites

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise