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06.02.2020 | Original Paper

Photocatalytic CO₂ Reduction Over Ni-Modified Cd_1−xZn_xS-Based Photocatalysts: Effect of Phase Composition of Photocatalyst and Reaction Media on Reduction Rate and Product Distribution

verfasst von: Ekaterina A. Kozlova, Mikhail N. Lyulyukin, Dina V. Markovskaya, A. V. Bukhtiyarov, I. P. Prosvirin, Svetlana V. Cherepanova, Denis V. Kozlov

Erschienen in: Topics in Catalysis | Ausgabe 1-2/2020

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Abstract

Two types of nickel-modified Cd_1−xZn_xS-based photocatalysts, Cd_xZn_1−xNi_yS_y+1 (mol% Ni = 0.05–0.5; x = 0.8) and yNiS/Cd_xZn_1−xS (mol% Ni = 0.1–1.0; x = 0.8), were prepared via a simple two-stage technique. The samples were characterized by XRD, UV–vis spectroscopy, and XPS techniques. The activity of the synthesized photocatalysts were tested in the gas-phase photocatalytic reduction of CO₂ under visible light (λ = 450 nm). It has been shown that both Cd_xZn_1−xNi_yS_y+1 and yNiS/Cd_xZn_1−xS samples with ultra-low content of nickel sulfide have improved activity in the carbon dioxide reduction in comparison to bare Cd_xZn_1−xS solid solutions. Also, it has been demonstrated that the addition of the reducing agent—hydrogen—into the system does not lead to a positive effect: the rate of CO₂ reduction either remains unchanged or decreases.

Vorheriger Artikel Photocatalytic Reduction of CO2 Over Me (Pt, Pd, Ni, Cu)/TiO2 Catalysts

Nächster Artikel High Photocatalytic Activity Under Visible Light of Sandwich Structures Based on Anodic TiO2/CdS Nanoparticles/Sol–Gel TiO2

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Cheng M, Yang S, Chen R, Zhu X, Liao Q, Huang Y (2018) Visible light responsive CdS sensitized TiO₂ nanorod array films for efficient photocatalytic reduction of gas phase CO₂. Mol Catal 448:185–194. https://doi.org/10.1016/j.mcat.2018.01.005 CrossRef

Khan AA, Tahir M (2019) Recent advancements in engineering approach towards design of photoreactors for selective photocatalytic CO2 reduction to renewable fuels. J Carbondioxide Util 29:205–239. https://doi.org/10.1016/j.jcou.2018.12.008 CrossRef

Kozlova EA, Parmon VN (2017) Heterogeneous semiconductor photocatalysts for hydrogen production from aqueous solutions of electron donors. Russ Chem Rev 86:870–906. https://doi.org/10.1070/RCR4739 CrossRef

Vorontsov AV, Kozlova EA, Besov AS, Kozlov DV, Kiselev SA, Safatov AS (2010) Photocatalysis: light energy conversion for the oxidation, disinfection, and decomposition of water. Kinet Catal 51:801–808. https://doi.org/10.1134/S0023158410060042 CrossRef

Pang R, Teramura K, Asakura H, Hosokawa S, Tanaka T (2017) Highly selective photocatalytic conversion of CO₂ by water over Ag-loaded SrNb₂O₆ nanorods. Appl Catal B 218:770–778. https://doi.org/10.1016/j.apcatb.2017.06.052 CrossRef

Wang Y, Liu M, Chen W, Mao L, Shangguan W (2018) Ag loaded on layered perovskite H₂SrTa₂O₇ to enhance the selectivity of photocatalytic CO₂ reduction with H₂O. J Alloys Compds 786:149–154. https://doi.org/10.1016/j.jallcom.2019.01.325 CrossRef

Tseng IH, Wu JCS, Chou HY (2004) Effects of sol-gel procedures on the photocatalysis of Cu/TiO₂ in CO₂ photoreduction. J Catal 221:432–440. https://doi.org/10.1016/j.jcat.2003.09.002 CrossRef

Cao L, Sahu S, Anikumar P, Bunker CE, Xu J, Fernando KAS, Wang P, Gualiants EA, Tackett KN, Sun YP (2011) Carbon nanoparticles as visible-light photocatalysts for efficient CO₂ conversion and beyond. J Am Chem Soc 133:4754–4757. https://doi.org/10.1021/ja200804h CrossRefPubMed

Guan G, Kida T, Harada T, Isayama M, Yoshida A (2003) Photoreduction of carbon dioxide with water over K₂Ti₆O₁₃ photocatalyst combined with Cu/ZnO catalyst under concentrated sunlight. Appl Catal A 249:11–18. https://doi.org/10.1016/S0926-860X(03)00205-9 CrossRef

10.

Yamashita H, Nishiguchi H, Kamada N, Anpo M, Teraoka Y et al (1994) Photocatalytic reduction of CO₂ with H₂O on TiO₂ and Cu/TiO₂ catalysts. Res Chem Intermed 20(8):815–823. https://doi.org/10.1163/156856794X00568 CrossRef

11.

Liu B-J, Torimoto T, Yoneyama H (1998) Photocatalytic reduction of CO₂ using surface-modified CdS photocatalysts in organic solvents. J Photochem Photobiol A 113:93–97. https://doi.org/10.1016/S1010-6030(97)00318-3 CrossRef

12.

Li Y, Wei Z, Fan J, Li Z, Yao H (2019) Photocatalytic CO₂ reduction activity of Z-scheme CdS/CdWO₄ catalysts constructed by surface charge directed selective deposition of CdS. Appl Surf Sci 483:442–452. https://doi.org/10.1016/j.apsusc.2019.03.333 CrossRef

13.

Bie C, Zhu B, Xu F, Zhang L, Yu J (2019) In situ grown monolayer N-doped graphene on CdS hollow spheres with seamless contact for photocatalytic CO₂ reduction. Adv Mater 31:1902868. https://doi.org/10.1002/adma.201902868 CrossRef

14.

Navalon S, Dhakshunamoorthy A, Alvaro M, Garcia H (2013) Photocatalytic CO₂ reduction using non-titanium metal oxides and sulfides. Chemsuschem 6:562–577. https://doi.org/10.1002/cssc.201200670 CrossRefPubMed

15.

Kozlova EA, Lyulyukin MN, Markovskaya DV, Selishchev DS, Cherepanova SV, Kozlov DV (2019) Synthesis of Cd_1-xZn_xS photocatalysts for gas-phase CO₂ reduction under visible light. Photochem Photobiol Sci 18:871–877. https://doi.org/10.1039/c8pp00332g CrossRefPubMed

16.

Markovskaya DV, Kozlova EA, Cherepanova SV, Kolinko PA, Gerasimov EYu, Parmon VN (2017) Doping or deposition of NiS on Cd_0.3Zn_0.7S photocatalysts: optimizing photocatalytic hydrogen evolution. ChemPhotoChem 1:575–581. https://doi.org/10.1002/cptc.201700121 CrossRef

17.

Zhang X, Jing D, Liu M, Guo L (2008) Efficient photocatalytic H₂ production under visible light irradiation over Ni doped Cd_1-xZn_xS microsphere photocatalysts. Catal Commun 9:1720–1724. https://doi.org/10.1016/j.catcom.2008.01.032 CrossRef

18.

Markovskaya DV, Cherepanova SV, Saraev AA, Gerasimov EYu, Kozlova EA (2015) Photocatalytic hydrogen evolution from aqueous solutions of Na₂S/Na₂SO₃ under visible light irradiation on CuS/Cd_0.3Zn_0.7S and Ni_zCd_0.3Zn_0.7S_1+z. Chem Eng J 262:146–155. https://doi.org/10.1016/j.cej.2014.09.090 CrossRef

19.

Korovin E, Selishchev D, Kozlov D (2016) Photocatalytic CO₂ reduction on the TiO₂ P25 under the high power UV-LED irradiation. Topics Catal 59:1292–1296. https://doi.org/10.1007/s11244-016-0651-6 CrossRef

20.

Wei Y, Wu X, Zhao Y, Wang L, Zhao Z, Huang X, Liu J, Li J (2018) Efficient photocatalysts of TiO₂ nanocrystals-supported PtRu alloy nanoparticles for CO₂ reduction with H₂O: synergistic effect of Pt-Ru. Appl Catal B 236:445–457. https://doi.org/10.1016/j.apcatb.2018.05.043 CrossRef

21.

Cherepanova SV (2012) X-ray scattering on one-dimensional disordered structures. J Struct Chem 53:109–132. https://doi.org/10.1134/S0022476612070116 CrossRef

22.

Ansovini D, Jun Lee CJJ, Chua CS, Ong LT, Tan HR, Webb WR, Raja R, Lim Y-F (2016) A highly active hydrogen evolution electrocatalyst based on a cobalt–nickel sulfide composite electrode. J Mater Chem A 4:9744–9749. https://doi.org/10.1016/0016-2361(95)80018-D CrossRef

23.

Liang X, Dong R, Li D, Bu X, Li F, Shu L, Wei R, Ho JC (2018) Coupling of Nickel Boride and Ni(OH)₂ nanosheets with hierarchical interconnected conductive porous structure synergizes the oxygen evolution reaction. ChemCatChem 10:4555–4561. https://doi.org/10.1002/cctc.201800993 CrossRef

24.

Zhang J, Xu Q, Zhang QS, Yu J (2013) Enhanced visible-light hydrogen-production activity of copper-modified Zn_xCd_1-xS. Chemsuschem 6:2009–2015. https://doi.org/10.1002/cssc.201300409 CrossRefPubMed

25.

Habisreutinger SN, Schmidt-Mende L, Stolarczyk JK (2013) Photocatalytic reduction of CO2 on TiO2 and other semiconductors. Angew Chem Int Ed 52:7372–7408. https://doi.org/10.1002/anie.201207199 CrossRef

26.

Uner D, Oymak MM (2012) On the mechanism of photocatalytic CO₂ reduction with water in the gas phase. Catal Today 181:82–88. https://doi.org/10.1016/j.cattod.2011.06.019 CrossRef

27.

Moudler J, Stickle W, Sobol P, Bomben K (1992) Handbook of X-ray photoelectron spectroscopy. Perkin-Elmer Corp, Eden Priarie

28.

Zhang L, Tian B, Chen F, Zhang J (2012) Nickel sulfide as co-catalyst on nanostructured TiO₂ for photocatalytic hydrogen evolution. J Int J Hydrogen Energy 37:17060–17067. https://doi.org/10.1016/j.ijhydene.2012.08.120 CrossRef

Titel: Photocatalytic CO2 Reduction Over Ni-Modified Cd1−xZnxS-Based Photocatalysts: Effect of Phase Composition of Photocatalyst and Reaction Media on Reduction Rate and Product Distribution
verfasst von: Ekaterina A. Kozlova
Mikhail N. Lyulyukin
Dina V. Markovskaya
A. V. Bukhtiyarov
I. P. Prosvirin
Svetlana V. Cherepanova
Denis V. Kozlov
Publikationsdatum: 06.02.2020
Verlag: Springer US
Erschienen in: Topics in Catalysis / Ausgabe 1-2/2020
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI: https://doi.org/10.1007/s11244-020-01233-y

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