Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Sol-Gel Science and Technology
Erschienen in: Journal of Sol-Gel Science and Technology 2/2020

09.03.2020 | Original Paper: Functional coatings, thin films and membranes (including deposition techniques)

Photoelectrochemical reduction of CO2 over Ru/Mn/Co trimetallic catalysts supported anatase TiO2 under visible light irradiation

verfasst von: Ahmad Nazeer Che Mat, Wan Jefrey Basirun, Nor Asrina Sairi, Muhammad Shahid Mehmood

Erschienen in: Journal of Sol-Gel Science and Technology | Ausgabe 2/2020

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Excessive emission of carbon dioxide (CO2) into the environment in addition to depletion of natural fossil fuel leads to the environmental pollution and energy crisis. Therefore, the photelectroreduction of CO2 is a suitable and versatile technique to convert CO2 gas into valuable organic products. Herein, Ru/Mn/Co (1:13:13) supported anatase TiO2 has been prepared using precipitation method and tested for photoelectrochemical reduction of CO2 into formic acid in aqueous and N,N-dimethylformamide (DMF) under visible light. Incorporation of Ru, Mn, and Co successfully reduced the bandgap to 1.66 eV and shifted the light absorption to the visible region with effective suppression of charge carriers recombination which is injurious to the photocatalytic reaction resultant in better photocatalytic performance. The photocurrent density in the aqueous medium is higher than DMF with a value of 12 μA cm−2 vs. Ag/AgCl. Stable photocurrent form chronoamperometry indicative of better product selectivity toward formic acid with Faradaic efficiency in aqueous and DMF are 0.8% and 2.23%, respectively.
Vorheriger Artikel Sn-rich CZTS films spin-coated from methanol-based sol-gel solution: annealing effect on microstructure and optoelectronic properties
Nächster Artikel Synthesis of a bicontinuous structured SrTiO3 porous film with significant photocatalytic activity by controlling phase separation process

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Yu KMK, Curcic I, Gabriel J, Tsang SCE (2008) Recent advances in CO2 capture and utilization. ChemSusChem 1:893–899
2.
Ge M, Cao C, Huang J, Li S, Chen Z, Zhang K-Q, Al-Deyab S, Lai Y (2016) A review of one-dimensional TiO2 nanostructured materials for environmental and energy applications. J Mater Chem A 4:6772–6801
3.
Cook TR, Dogutan DK, Reece SY, Surendranath Y, Teets TS, Nocera DG (2010) Solar energy supply and storage for the legacy and nonlegacy worlds. Chem Rev 110:6474–6502
4.
Gusain R, Kumar P, Sharma OP, Jain SL, Khatri OP (2016) Reduced graphene oxide–CuO nanocomposites for photocatalytic conversion of CO2 into methanol under visible light irradiation. Appl Catal B 181:352–362
5.
Demirbas A (2010) Methane hydrates as potential energy resource: Part 2–Methane production processes from gas hydrates. Energy Convers Manag 51:1562–1571
6.
Ran J, Zhang J, Yu J, Jaroniec M, Qiao SZ (2014) Earth-abundant cocatalysts for semiconductor-based photocatalytic water splitting. Chem Soc Rev 43:7787–7812
7.
Fujishima A, Honda K (1972) TiO2 photoelectrochemistry and photocatalysis. Nature 238:37–38CrossRef
8.
Halmann M (1978) Photoelectrochemical reduction of aqueous carbon dioxide on p-type gallium phosphide in liquid junction solar cells. Nature 275:115
9.
Gupta SM, Tripathi M (2011) A review of TiO2 nanoparticles. Chin Sci Bull 56:1639
10.
Fujishima A, Zhang X, Tryk DA (2008) TiO2 photocatalysis and related surface phenomena. Surf Sci Rep. 63:515–582
11.
Fujishima A, Rao TN, Tryk DA (2000) Titanium dioxide photocatalysis. J Photochemistry Photobiol C 1:1–21
12.
Konstantinou IK, Albanis TA (2004) TiO2-assisted photocatalytic degradation of azo dyes in aqueous solution: kinetic and mechanistic investigations: a review. Appl Catal B 49:1–14
13.
Morgan BJ, Watson GW (2010) Intrinsic n-type defect formation in TiO2: a comparison of rutile and anatase from GGA+ U calculations. J Phys Chem C 114:2321–2328
14.
Liu F, Lu L, Xiao P, He H, Qiao L, Zhang Y (2012) Effect of oxygen vacancies on photocatalytic efficiency of TiO2 nanotubes aggregation. Bull Korean Chem Soc 33:2255–2259
15.
Yang C-T, Wood BC, Bhethanabotla VR, Joseph B (2014) CO2 adsorption on anatase TiO2 (101) surfaces in the presence of subnanometer Ag/Pt clusters: implications for CO2 photoreduction. J Phys Chem C 118:26236–26248
16.
Lee J, Sorescu DC, Deng X (2011) Electron-induced dissociation of CO2 on TiO2 (110). J Am Chem Soc 133:10066–10069
17.
Ni M, Leung MK, Leung DY, Sumathy K (2007) A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production. Renew Sustain Energy Rev 11:401–425
18.
Ma Y, Wang X, Jia Y, Chen X, Han H, Li C (2014) Titanium dioxide-based nanomaterials for photocatalytic fuel generations. Chem Rev 114:9987–10043
19.
Lee K, Lee S, Cho H, Jeong S, Kim WD, Lee S, Lee DC (2018) Cu+-incorporated TiO2 overlayer on Cu2O nanowire photocathodes for enhanced photoelectrochemical conversion of CO2 to methanol. J Energy Chem 27:264–270
20.
Tasbihi M, Kočí K, Edelmannová M, Troppova I, Reli M, Schomaecker R (2018) Pt/TiO2 photocatalysts deposited on commercial support for photocatalytic reduction of CO2. J Photochemistry Photobiol A 366:72–80
21.
Jia P-y, Guo R-t, Pan W-g, Huang C-y, Tang J-y, Liu X-y, Qin H, Xu Q-y (2019) The MoS2/TiO2 heterojunction composites with enhanced activity for CO2 photocatalytic reduction under visible light irradiation. Colloids Surf A 570:306–316
22.
Shariati A (2019) Fe-N-TiO2/CPO-Cu-27 nanocomposite for superior CO2 photoreduction performance under visible light irradiation. Sol Energy 186:166–174
23.
Wang L, Jin P, Duan S, She H, Huang J, Wang Q (2019) In-situ incorporation of copper (II) porphyrin functionalized zirconium MOF and TiO2 for efficient photocatalytic CO2 reduction. Science 64:926–933
24.
Shehzad N, Tahir M, Johari K, Murugesan T, Hussain M (2018) Improved interfacial bonding of graphene-TiO2 with enhanced photocatalytic reduction of CO2 into solar fuel. J Environ Chem Eng 6:6947–6957
25.
Gui MM, Chai S-P, Xu B-Q, Mohamed AR (2014) Enhanced visible light responsive MWCNT/TiO2 core–shell nanocomposites as the potential photocatalyst for reduction of CO2 into methane. Sol Energy Mater Sol Cells 122:183–189
26.
Dong Y, Nie R, Wang J, Yu X, Tu P, Chen J, Jing H (2019) Photoelectrocatalytic CO2 reduction based on metalloporphyrin-modified TiO2 photocathode. Chin J Catal 40:1222–1230
27.
Sápi A, Rajkumar T, Ábel M, Efremova A, Grósz A, Gyuris A, Ábrahámné KB, Szenti I, Kiss J, Varga T (2019) Noble-metal-free and Pt nanoparticles-loaded, mesoporous oxides as efficient catalysts for CO2 hydrogenation and dry reforming with methane. J CO2 Utilization 32:106–118
28.
Johánek V, Ostroverkh A, Fiala R (2019) Vapor-feed low temperature direct methanol fuel cell with Pt and PtRu electrodes: Chemistry insight. Renew Energy 138:409–415
29.
Pati S, Jangam A, Wang Z, Dewangan N, Wai MH, Kawi S (2019) Catalytic Pd0.77Ag0.23 alloy membrane reactor for high temperature water-gas shift reaction: methane suppression. Chem Eng J 362:116–125
30.
Sen IS, Mitra A, Peucker-Ehrenbrink B, Rothenberg SE, Tripathi SN, Bizimis M (2016) Emerging airborne contaminants in India: Platinum Group Elements from catalytic converters in motor vehicles. Appl Geochem 75:100–106
31.
Qu J, Zhang X, Wang Y, Xie C (2005) Electrochemical reduction of CO2 on RuO2/TiO2 nanotubes composite modified Pt electrode. Electrochim Acta 50:3576–3580
32.
Popić J, Avramov-Ivić M, Vuković N (1997) Reduction of carbon dioxide on ruthenium oxide and modified ruthenium oxide electrodes in 0.5 M NaHCO3. J Electroanal Chem 421:105–110
33.
Bandi A (1990) Electrochemical reduction of carbon dioxide on conductive metallic oxides. J Electrochem Soc 137:2157–2160
34.
Bandi A, Kühne HM (1992) Electrochemical reduction of carbon dioxide in water: analysis of reaction mechanism on ruthenium-titanium-oxide. J Electrochem Soc 139:1605–1610
35.
Spataru N, Tokuhiro K, Terashima C, Rao TN, Fujishima A (2003) Electrochemical reduction of carbon dioxide at ruthenium dioxide deposited on boron-doped diamond. J Appl Electrochem 33:1205–1210
36.
Russell WW, Miller GH (1950) Catalytic hydrogenation of carbon dioxide to higher hydrocarbons. J Am Chem Soc 72:2446–2454
37.
Aljabour A, Coskun H, Apaydin DH, Ozel F, Hassel AW, Stadler P, Sariciftci NS, Kus M (2018) Nanofibrous cobalt oxide for electrocatalysis of CO2 reduction to carbon monoxide and formate in an acetonitrile-water electrolyte solution. Appl Catal B 229:163–170
38.
Gao S, Jiao X, Sun Z, Zhang W, Sun Y, Wang C, Hu Q, Zu X, Yang F, Yang S (2016) Ultrathin Co3O4 layers realizing optimized CO2 electroreduction to formate. Angew Chem Int Ed 55:698–702
39.
Roche I, Scott K (2009) Carbon-supported manganese oxide nanoparticles as electrocatalysts for oxygen reduction reaction (orr) in neutral solution. J Appl Electrochem 39:197–204
40.
Zhang N, Li L, Chu Y, Zheng L, Sun S, Zhang G, He H, Zhao J (2019) High Pt utilization efficiency of electrocatalysts for oxygen reduction reaction in alkaline media. Catal Today 332:101–108
41.
Ju W, Bagger A, Hao G-P, Varela AS, Sinev I, Bon V, Cuenya BR, Kaskel S, Rossmeisl J, Strasser P (2017) Understanding activity and selectivity of metal-nitrogen-doped carbon catalysts for electrochemical reduction of CO2, Nature. Communications 8:944
42.
Möller T, Ju W, Bagger A, Wang X, Luo F, Thanh TN, Varela AS, Rossmeisl J, Strasser P (2019) Efficient CO2 to CO electrolysis on solid Ni–N–C catalysts at industrial current densities. Energy Environ Sci 12:640–647
43.
Pan F, Deng W, Justiniano C, Li Y (2018) Identification of champion transition metals centers in metal and nitrogen-codoped carbon catalysts for CO2 reduction. Appl Catal B 226:463–472
44.
Zhang B, Zhang J, Shi J, Tan D, Liu L, Zhang F, Lu C, Su Z, Tan X, Cheng X (2019) Manganese acting as a high-performance heterogeneous electrocatalyst in carbon dioxide reduction. Nat Commun 10:1–8
45.
Yu L, Zhong Q, Deng Z, Zhang S (2016) Enhanced NOx removal performance of amorphous Ce-Ti catalyst by hydrogen pretreatment. J Mol Catal A 423:371–378
46.
Yu L, Zhong Q, Zhang S (2014) The enhancement for SCR of NO by NH3 over the H2 or CO pretreated Ag/γ-Al2O3 catalyst. Phys Chem Chem Phys 16:12560–12566
47.
Li D, Yu Q, Li SS, Wan HQ, Liu LJ, Qi L, Liu B, Gao F, Dong L, Chen Y (2011) The remarkable enhancement of CO-pretreated CuO-Mn2O3/γ-Al2O3 supported catalyst for the reduction of NO with CO: the formation of surface synergetic oxygen vacancy. Chemistry 17:5668–5679
48.
Boronin A, Slavinskaya E, Danilova I, Gulyaev R, Amosov YI, Kuznetsov P, Polukhina I, Koscheev S, Zaikovskii V, Noskov A (2009) Investigation of palladium interaction with cerium oxide and its state in catalysts for low-temperature CO oxidation. Catal Today 144:201–211
49.
Chen D, Qu Z, Lv Y, Lu X, Chen W, Gao X (2015) Effect of oxygen pretreatment on the surface catalytic oxidation of HCHO on Ag/MCM-41 catalysts. J Mol Catal A 404:98–105
50.
Nguyen DL, Leroi P, Ledoux MJ, Pham-Huu C (2009) Influence of the oxygen pretreatment on the CO2 reforming of methane on Ni/β-SiC catalyst. Catal Today 141:393–396
51.
Devi LG, Kottam N, Murthy BN, Kumar SG (2010) Enhanced photocatalytic activity of transition metal ions Mn2+, Ni2+ and Zn2+ doped polycrystalline titania for the degradation of Aniline Blue under UV/solar light. J Mol Catal A 328:44–52
52.
Sharotri N, Sharma D, Sud D (2019) Experimental and theoretical investigations of Mn-N-co-doped TiO2 photocatalyst for visible light induced degradation of organic pollutants. J Mater Res Technol 8:3995–4009
53.
Sharotri N, Sud D (2017) Visible light responsive Mn-S-co-doped TiO2 photocatalyst—synthesis, characterization and mechanistic aspect of photocatalytic degradation. Sep Purif Technol 183:382–391
54.
Murthy M, Tubaki S, Lokesh S, Rangappa D (2017) Co, N-doped TiO2 coated r-GO as a photo catalyst for enhanced photo catalytic activity. Mater Today 4:11873–11881
55.
Wen X-J, Niu C-G, Ruan M, Zhang L, Zeng G-M (2017) AgI nanoparticles-decorated CeO2 microsheets photocatalyst for the degradation of organic dye and tetracycline under visible-light irradiation. J Colloid Interface Sci 497:368–377
56.
Kong L, Jiang Z, Lai HH, Nicholls RJ, Xiao T, Jones MO, Edwards PP (2012) Unusual reactivity of visible-light-responsive AgBr–BiOBr heterojunction photocatalysts. J Catal 293:116–125
57.
Chang Y-H, Liu C-M, Chen C, Cheng H-E (2012) The effect of geometric structure on photoluminescence characteristics of 1-D TiO2 nanotubes and 2-D TiO2 films fabricated by atomic layer deposition. J Electrochem Soc 159:D401–D405
58.
Mathew S, kumar Prasad A, Benoy T, Rakesh P, Hari M, Libish T, Radhakrishnan P, Nampoori V, Vallabhan C (2012) UV-visible photoluminescence of TiO2 nanoparticles prepared by hydrothermal method. J Fluores 22:1563–1569
59.
Nakajima H, Mori T, Watanabe M (2004) Influence of platinum loading on photoluminescence of TiO2 powder. J Appl Phys 96:925–927
60.
Shi J, Chen J, Feng Z, Chen T, Lian Y, Wang X, Li C (2007) Photoluminescence characteristics of TiO2 and their relationship to the photoassisted reaction of water/methanol mixture. J Phys Chem C 111:693–699
61.
Uddin MT, Nicolas Y, Olivier Cl, Toupance T, Müller MM, Kleebe H-J, Rachut K, Ziegler Jr, Klein A, Jaegermann W (2013) Preparation of RuO2/TiO2 mesoporous heterostructures and rationalization of their enhanced photocatalytic properties by band alignment investigations. J Phys Chem C 117:22098–22110
62.
Harichandran G, Amalraj SD, Shanmugam P (2014) Synthesis and characterization of phosphate anchored MnO2 catalyzed solvent free synthesis of xanthene laser dyes. J Mol Catal A 392:31–38
63.
Xu J, Gao P, Zhao T (2012) Non-precious Co3O4 nano-rod electrocatalyst for oxygen reduction reaction in anion-exchange membrane fuel cells. Energy Environ Sci 5:5333–5339
64.
Hasan MR, Hamid SBA, Basirun WJ, Suhaimy SHM, Mat ANC (2015) A sol–gel derived, copper-doped, titanium dioxide–reduced graphene oxide nanocomposite electrode for the photoelectrocatalytic reduction of CO2 to methanol and formic acid. RSC Adv 5:77803–77813
65.
Subrahmanyam M, Kaneco S, Alonso-Vante N (1999) A screening for the photo reduction of carbon dioxide supported on metal oxide catalysts for C1 – C3 selectivity. Appl Catal B 23:169–174
66.
Sasirekha N, Basha SJS, Shanthi K (2006) Photocatalytic performance of Ru doped anatase mounted on silica for reduction of carbon dioxide. Appl Catal B 62:169–180
Metadaten
Titel
Photoelectrochemical reduction of CO2 over Ru/Mn/Co trimetallic catalysts supported anatase TiO2 under visible light irradiation
verfasst von
Ahmad Nazeer Che Mat
Wan Jefrey Basirun
Nor Asrina Sairi
Muhammad Shahid Mehmood
Publikationsdatum
09.03.2020
Verlag
Springer US
Erschienen in
Journal of Sol-Gel Science and Technology / Ausgabe 2/2020
Print ISSN: 0928-0707
Elektronische ISSN: 1573-4846
DOI
https://doi.org/10.1007/s10971-020-05277-0

Weitere Artikel der Ausgabe 2/2020

Journal of Sol-Gel Science and Technology 2/2020 Zur Ausgabe

Original Paper: Fundamentals of sol–gel and hybrid materials processing

One-step synthesis of pure γ-FeNi alloy by reaсtive sol–gel combustion route: mechanism and properties

Original Paper: Industrial and technological applications of sol-gel and hybrid materials

Experimental investigation of partially hydrolyzed polyacrylamide–hexamine–pyrocatechol polymer gel for permeability modification

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Synthesis, characterization, and significant photochemical performances of delafossite AgFeO2 nanoparticles

Original Paper: Nano-structured materials (particles, fibers, colloids, composites, etc.)

Facile fabrication of Fe-doped Si–C–N ceramic microspheres with flower-like morphology and the infrared extinction property

Brief Communication: Nanostructured materials (particles, fibers, colloids, composites, etc.)

Facile hydrothermal synthesis of CuCo2O4/AC/PANI nanocomposites

Original Paper: Nano- and macroporous materials (aerogels, xerogels, cryogels, etc.)

Analysis and characterization of etched silica aerogels

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise