Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Erschienen in:
Rare Earth, Rare Earth Luminescence, Luminescent Rare Earth Compounds, and Photofunctional Rare Earth Hybrid Materials Kapitel lesen Erstes Kapitel lesen

2017 | OriginalPaper | Buchkapitel

2. Photofunctional Rare Earth Hybrid Materials Based on Organically Modified Silica

verfasst von : Bing Yan

Erschienen in: Photofunctional Rare Earth Hybrid Materials

Verlag: Springer Singapore

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

This chapter mainly focuses on recent research progress in photofunctional rare earth hybrid materials based on organically modified silica, which are obtained through the special chemical linkage of organically modified silanes (ORMOSILs). The content mainly covers the hybrid materials based on aromatic carboxylic acid derivative-modified ORMOSILs, β-diketone and β-diketone analogue derivative-modified ORMOSILs, macrocyclic compound derivative-modified ORMOSILs, heterocyclic ligand derivative-modified ORMOSILs, and the hybrid materials with composite matrices through ORMOSILs. The emphasis is put on the recent research progress of our group.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Vorheriges Kapitel Rare Earth, Rare Earth Luminescence, Luminescent Rare Earth Compounds, and Photofunctional Rare Earth Hybrid Materials
Nächstes Kapitel Photofunctional Rare Earth Hybrid Materials Based on Organically Modified Mesoporous Silica
Literatur
1.
2.
Ciriminna R, Sciortino M, Alonzo G, de Schrijver A, Pagliaro M (2011) From molecules to systems: sol-gel microencapsulation in silica-based materials. Chem Rev 111:765–789CrossRef
3.
Ciriminna R, Fidalgo A, Pandarus V, Béland F, Ilharco LM, Pagliaro M (2013) The sol−gel route to advanced silica-based materials and recent applications. Chem Rev 113:6592−6620CrossRef
4.
Yan B (2012) Recent progress on photofunctional lanthanide hybrid materials. RSC Adv 2:9304–9324CrossRef
5.
Feng J, Zhang HJ (2013) Hybrid materials based on lanthanide organic complexes: a review. Chem Soc Rev 42:387–410CrossRef
6.
Wang YG, Wang L, Li HR, Liu P, Qin DS, Liu BY, Zhang WJ, Deng RP, Zhang HJ (2008) Synthesis and luminescence properties of hybrid organic–inorganic transparent titania thin film activated by in-situ formed lanthanide complexes. J Solid State Chem 181:562–566CrossRef
7.
Yan B, Sheng C, Guo L (2012) Lanthanide (Eu3+, Tb3+, Gd3+) hybrid system with functionalized diethylenetriamine pentaacetic acid ligand: coordination bonding assembly, luminescence and MRI contrast agent property. Inorg Chem Comm 18:43–46CrossRef
8.
Wang QM, Yan B (2004) From molecules to materials: a new way to construct luminescent chemical bonded hybrid systems based with ternary lanthanide complexes of 1,10-phenanthroline. Inorg Chem Comm 7:1124–1127CrossRef
9.
Wang QM, Yan B (2005) Optically hybrid lanthanide ions (Eu3+, Tb3+)-centered materials with novel functional di-urea linkages. Appl Organomet Chem 19:952–956CrossRef
10.
Yan B, Wang FF (2007) Molecular design and photo-physics of quaternary hybrid terbium centered systems with novel functional di-urea linkages of strong chemical bonds through hydrogen transfer addition. J Organomet Chem 692:2395–2401CrossRef
11.
Yan B (2014) Assembling photofunctional rare earth hybrid materials using organically modified siloxanes as linkers. J Chin Soc Rare Earths (in Chinese) 32:1–15
12.
Yan B, Sui YL (2006) Construction of hybrid material with double chemical bond from functional bridge ligand: molecular modification, lotus root-like micromorphology and strong luminescence. Opt Mater 28:1216–1221CrossRef
13.
Wang QM, Yan B (2005) A novel way to prepare luminescent terbium molecular-scale hybrid materials: modified heterocyclic ligands covalently bonded with silica. Cryst Growth Des 5:497–503CrossRef
14.
Wang QM, Yan B (2005) Construction of lanthanide luminescent molecular-based hybrid material using modified functional bridge chemical bonded with silica. J Photochem Photobiol A Chem 175:159–164CrossRef
15.
Yan B, Sui YL, Liu JL (2009) Photoluminescent hybrid thin films fabricated with lanthanide ions covalently bonded silica. J Alloys Compds 476:826–829CrossRef
16.
Wang QM, Yan B (2005) An unusual way to luminescent terbium molecular-level hybrid materials: modified methyl benzoic acid covalently bonded with silica as a bridge. J Mater Res 20:592–598CrossRef
17.
Yan B, Zhou B, Wang QM (2006) Luminescent lanthanide molecular-based hybrid materials bridged through novel urethane linkages. Appl Organomet Chem 20:835–839CrossRef
18.
Yan B, Zhao LM (2005) Construction of luminescent terbium inorganic/organic molecular-based hybrids from modified functional bridge ligand. Mater Lett 59:795–799CrossRef
19.
Zhao LM, Yan B (2006) The fabrication of rare earth covalent luminescent hybrid materials with potential molecular bridge by in situ sol-gel process. Mater Res Bull 41:1–9CrossRef
20.
Sui YL, Yan B (2006) Luminescent molecular hybrid system derived from 2-furancarboxylic acid and silylated monomer coordinated to rare earth ions. Appl Surf Sci 252:4306–4311CrossRef
21.
Zhao LM, Yan B (2006) Molecular-based smart hybrid material through in situ sol-gel process: artificial assembly of terbium with modified bridge ligand and luminescence. Coll Surf A 275:64–68CrossRef
22.
Yan B, Sui YL (2007) Fabrication and characterization of molecular hybrid materials with lanthanides covalently bonded in silica via sol-gel process. Mater Lett 61:3715–3718CrossRef
23.
Liu FY, Fu LS, Wang J, Liu Z, Li HR, Zhang HJ (2002) Luminescent hybrid films obtained by covalent grafting of terbium complex to silica network. Thin Solid Films 419:178–182CrossRef
24.
Wang QM, Yan B (2007) Molecular assembly and photophysical properties of a novel luminescent terbium hybrid material with modified carboxyl group of p-aminobenzoic acid as a functional bridge. Mater Lett 60:3420–3425CrossRef
25.
Wang QM, Yan B (2004) Novel luminescent molecular-based hybrid organic-inorganic terbium complex covalently bonded materials via sol-gel process. Inorg Chem Comm 7:747–750CrossRef
26.
Wang QM, Yan B (2004) Novel luminescent terbium molecular-based hybrids with modified meta-aminobenzoic acid covalently bonded with silica. J Mater Chem 15:2450–2454CrossRef
27.
Yan B, Lu HF (2009) Lanthanide-centered inorganic/organic hybrids from functionalized 2-pyrrolidinone-5-carboxylic acid bridge: covalently bonded assembly and luminescence. J Organomet Chem 694:2597–2603CrossRef
28.
Yan B, Lu HF (2009) Novel leaf-shaped hybrid micro-particles: chemically bonded self-assembly, microstructure and photoluminescence. J Photochem Photobiol A Chem 205:122–128CrossRef
29.
Wang QM, Yan B (2006) Terbium/zinc luminescent hybrid siloxane-oxide materials bridged by novel ureasils linkages. J Organomet Chem 691:545–550CrossRef
30.
Wang QM, Yan B (2006) Designing a family of luminescent hybrid materials by 3-(triethoxysilyl)-propyl isocyanate grafted 2-hydroxynicotinic acid bridge molecules. J Organomet Chem 691:3567–3573CrossRef
31.
Zhao LM, Yan B (2005) A novel path to luminescent hybrid molecular materials: modifying the hydroxyl group of 6-hydroxynicotinic acid by grafting to a silica network. Appl Organomet Chem 19:1060–1064CrossRef
32.
Yan B, Ma DJ (2006) From chemistry to materials, design and photophysics of functional terbium molecular hybrids from assembling covalent chromophore to alkoxysilanes through hydrogen transfer addition. J Solid State Chem 179:2059–2066CrossRef
33.
Yan B, Lu HF (2008) Lanthanide-centered covalently bonded hybrids through sulfide linkage: molecular assembly, physical characterization, and photoluminescence. Inorg Chem 47:5601–5611CrossRef
34.
Yan B, Qian K, Lu HF (2009) Chemically bonded metallic (Eu, Tb, Zn) hybrid materials through sulfide linkage: molecular construction, physical characterization and photophysical properties. J Organomet Chem 694:3160–3166
35.
Yan B, Wang XL, Qian K, Lu HF (2010) Coordination bonding assembly, characterization and photophysical properties of lanthanide (Eu, Tb)/zinc centered hybrid materials through sulfide bridge. J Photochem Photobiol A Chem 212:75–80CrossRef
36.
Lu HF, Yan B (2006) Attractive sulfonamide bridging bonds constructing lanthanide centered photoactive covalent hybrids. J Non-cryst Sol 352:5331–5336CrossRef
37.
Qian K, Yan B (2010) Lanthanide/zinc centered photoactive hybrids with functional sulfonamide linkage: coordination bonding assembly, characterization and photophysical properties. Polyhedron 29:226–231CrossRef
38.
Yan B, Wang QM (2008) Two luminescent molecular hybrids composed of bridged Eu(III)-beta-diketone chelates covalently trapped in silica and titanate gels. Cryst Growth Des 8:1484–1489CrossRef
39.
Yan B, Kong LL, Zhou B (2009) A luminescent covalently bonded rare earth hybrid material by functionalized trifluoacetylacetone linkage. J Non-Cryst Sol 355:1281–1284CrossRef
40.
Wang Y, Wang YG, Cao PP, Li YN, Li HR (2011) Rectangular-plate like organosilica microcrystals based on silylated β-diketone and lanthanide ions. CrystEngComm 13:177–181CrossRef
41.
Chen XF, Zhang PN, Wang TR, Li HR (2014) The first europium(III) β-diketonate complex functionalized polyhedral oligomeric silsesquioxane. Chem Eur J 20:2551–2556CrossRef
42.
Guo XM, Guo HD, Fu LS, Zhang HJ, Carlos LD, Deng RP, Yu JB (2008) Synthesis and photophysical properties of novel organic–inorganic hybrid materials covalently linked to a europium complex. J Photochem Photobiol A Chem 200:318–324CrossRef
43.
Guo XM, Guo HD, Fu LS, Carlos LD, Ferreira RAS, Sun LN, Deng RP, Zhang HJ (2009) Novel near-infrared luminescent hybrid materials covalently linking with lanthanide [Nd(III), Er(III), Yb(III), and Sm(III)] complexes via a primary β-diketone ligand: synthesis and photophysical studies. J Phys Chem C 113:12538–12545CrossRef
44.
Sun LN, Qiu YN, Liu T, Zhang JZ, Dang S, Feng J, Wang ZJ, Zhang HJ, Shi LY (2013) Near infrared and visible luminescence from xerogels covalently grafted with lanthanide [Sm3+, Yb3+, Nd3+, Er3+, Pr3+, Ho3+] β-diketonate derivatives using visible light excitation. ACS Appl Mater Interf 5:9585–9593CrossRef
45.
Wang YH, Li B, Zhang LM, Zuo QH, Liu LN, Li P (2010) Improved photoluminescence properties of a novel europium(III) complex covalently grafted to organically modified silicates. J Coll Interf Sci 349:505–511CrossRef
46.
Guo L, Yan B, Liu JL (2011) Photofunctional Eu3+/Tb3+hybrids through sulfoxide linkages: coordination bonds construction, characterization and luminescence. Dalton Trans 40:4933–4940CrossRef
47.
Lu HF, Yan B (2008) Covalently assembly and photophysical properties of novel lanthanide centered hybrid materials by functionalized thioacylureas bridge. J Photochem Photobiol A Chem 197:351–358CrossRef
48.
Liu JL, Yan B (2008) Lanthanide (Eu3+, Tb3+) centered hybrid materials using modified functional bridge chemical bonded with silica: molecular design, physical characterization, and photophysical properties. J Phys Chem B 112:10898–10907CrossRef
49.
Yan B, Wang QM, Ma DJ (2009) Molecular construction, characterization, and photophysical properties of supramolecular lanthanide-calix[4]arene covalently bonded hybrid systems. Inorg Chem 48:36–44CrossRef
50.
Lu HF, Yan B, Liu JL (2009) Functionalization of calix[4]arene as a molecular bridge to assemble luminescent chemically bonded rare earth hybrid systems. Inorg Chem 48:3966–3975CrossRef
51.
Liu JL, Yan B, Guo L (2011) Lanthanide-centered organic-inorganic hybrids through a functionalized aza-crown ether bridge: coordination bonding assembly, microstructure and multicolor luminescence. Dalton Trans 40:1961–1968CrossRef
52.
Guo L, Yan B (2011) Bear-infrared luminescent hybrid materials using modified functional lanthanide (Nd3+, Yb3+) porphyrins complexes chemical bonded with silica. Inorg. Chem Comm 14:1833–1837
53.
Guo L, Fu LS, Ferreira RAS, Carlos LD, Yan B (2012) Photofunctional hybrid silica microspheres covalently functionalized with metalloporphyrins. J Solid State Chem 194:9–14CrossRef
54.
Liu JL, Yan B, Guo L (2010) Photoactive ternary lanthanide-centered hybrids with Schiff-base functionalized polysilsesquioxanes bridges and N-heterocylic ligands. Eur J Inorg Chem 2290–2296
55.
Li HR, Lin J, Zhang HJ, Li HC, Fu LS, Meng QG (2001) Novel, covalently bonded hybrid materials of europium (terbium) complexes with silica. Chem Comm 1212–1213
56.
Li HR, Lin NN, Wang Y, Feng Y, Gan QY, Zhang HJ, Dong QL, Chen YH (2009) Construction and photoluminescence of monophase hybrid materials derived from a urea-based bis-silylated bpyridine. Eur J Inorg Chem 519–523
57.
Carlos LD, Chi Man MW, Bartlett JR (2012) Luminescent coatings from bpyridine-based bridged silsesquioxanes containing Eu3+ and Tb3+ salts. J Mater Chem 22:13279–13285CrossRef
58.
Li HR, Lin J, Zhang HJ, Fu LS, Meng QG, Wang SB (2002) Preparation and luminescence properties of hybrid materials containing europium(III) complexes covalently bonded to a silica matrix. Chem Mater 14:3651–3655CrossRef
59.
Lenaerts P, Storms A, Mullens J, D’Haen J, Gorller-Walrand C, Binnemans K, Driesen K (2005) Thin films of highly luminescent lanthanide complexes covalently linked to an organic-inorganic hybrid material via 2-2ubstituted imidazo[4,5-f]-1,10-phenanthroline groups. Chem Mater 17:5194–5201CrossRef
60.
Bo SH, Liu XH, Zhen Z (2008) Preparation and luminescence properties of hybrid materials containing lanthanide complexes covalently bonded to a terpyridine-functionalized silica matrix. J Lumin 128:1725–1730CrossRef
61.
Tong BH, Wang SJ, Jiao J, Ling FR, Meng XZ, Wang B (2007) Novel luminescent lanthanide complexes covalently linked to a terpyridine-functionalized silica network. J Photochem Photobiol A Chem 191:74–79CrossRef
62.
Guo L, Yan B (2010) Chemically bonding assembly, physical characterization, and photophysical properties of lanthanide hybrids from a functional thiazole bridge. Eur J Inorg Chem 1267–1274
63.
Wang QM, Yan B (2006) Molecular assembly of red and green nanophosphors from amine-functionalized covalent linking hybrids with emitting centers Eu3+and Tb3+ions. J Photochem Photobiol A Chem 178:70–75CrossRef
64.
Lu HF, Yan B (2008) Lanthanide-centered luminescent hybrid micro sphere-particles obtained by sol-gel method. J Photochem Photobiol A Chem 194:136–142CrossRef
65.
Liu JL, Yan B (2010) Rare earth (Eu3+, Tb3+) hybrids through amide bridge: chemically bonded self-assembly and photophysical properties. J Organomet Chem 695:580–587CrossRef
66.
Yan B, Zhou B, Wang QM (2007) Novel hybrid materials with covalent bonding and rare earth ions-induced enhancing luminescence of bridged 9-amino acridine. J Lumin 126:556–560CrossRef
67.
Yan B, Qiao XF (2007) Photophysical properties of terbium molecular-based hybrids assembled with novel ureasil linkages. Photochem Photobiol 83:971–978CrossRef
68.
Yan B, Qian K, Lu HF (2007) Molecular assembly and photophysical properties of quaternary molecular hybrid materials with chemical bond. Photochem Photobiol 83:1481–1490CrossRef
69.
Yan B, Qian K (2009) Chemically bonded hybrid systems from functionalized hydroxypyridine molecular bridge: characterization and photophysical properties. Photochem Photobiol 85:1278–1285CrossRef
70.
Yan B, Qian K (2009) Novel chemically bonded Tb/Zn hybrid sphere particles: molecular assembly, microstructure, and photoluminescence. J Photochem Photobiol A Chem 207:217–223CrossRef
71.
Sui YL, Yan B (2006) Fabrication and photoluminescence of molecular hybrid films based on the complexes of 8-hydroxyquinoline with different metal ions via sol–gel process. J Photochem Photobiol A Chem 182:1–6CrossRef
72.
Sun LN, Dang S, Yu JB, Feng J, Shi LY, Zhang HJ (2010) Near-infrared luminescence from visible-light-sensitized hybrid materials covalently linked with tris(8-hydroxyquinolinate)-lanthanide [Er(III), Nd(III), and Yb(III)] derivatives. J Phys Chem B 114:16393–16397CrossRef
73.
Liu JL, Yan B (2008) Molecular construction and photophysical properties of luminescent covalently bonded lanthanide hybrid materials obtained by grafting organic ligands containing 1,2,4-triazole on silica by mercapto modification. J Phys Chem C 112:14168–14178CrossRef
74.
Liu JL, Yan B (2009) Molecular assembly, physical characterization and photophysical properties of ternary lanthanide hybrids containing functional 1,2,4-triazole and 1,10-phenanthroline. J Photochem Photobiol A Chem 206:32–39CrossRef
75.
Lu HF, Wang H, Feng SY (2010) A new way to construct luminescent functionalized silicon hybrid material derived from methyldichlorosilane. J Photochem Photobiol A Chem 210:48–53CrossRef
76.
Lu HF, Wang XC, Wang H, Feng SY (2010) Molecular design and photophysical properties of acylamido side functionalized polysiloxanes with lanthanide ions as luminescent centers. J Photochem Photobiol A Chem 215:46–51CrossRef
77.
Nobre SS, Cattoen X, Sa Ferreira RA, Carcel C, Bermudez VD, Chi Man MW, Carlos LD (2010) Eu3+-assisted short-range ordering of photoluminescent bridged silsesquioxanes. Chem Mater 22:3599–3609CrossRef
78.
Lin NN, Li HR, Wang YG, Feng Y, Qin DS, Gan QY, Chen SD (2008) Luminescent triazine-containing bridged polysilsesquioxanes activated by lanthanide ions. Eur J Inorg Chem 4781–4785
79.
Liu P, Li HR, Wang YG, Liu BY, Zhang WJ, Wang YJ, Yan WD, Zhang HJ, Schubert U (2008) Europium complexes immobilization on titania via chemical modification of titanium alkoxide. J Mater Chem 18:735–737CrossRef
80.
Li HR, Liu P, Wang YG, Zhang L, JB Y, Zhang HJ, Liu BY, Schubert U (2009) Preparation and luminescence properties of hybrid titania immobilized with lanthanide complexes. J Phys Chem C 113:3945–3949CrossRef
81.
Guo L, Fu LS, Ferreira RAS, Carlos LD, Li QP, Yan B (2011) Novel lanthanide luminescent materials based on multifunctional complexes of 2-sulfanylpyridine-3-carboxylic acid and silica/titania hosts. J Mater Chem 21:15600–15607CrossRef
82.
Guo L, Yan B (2010) New luminescent lanthanide centered Si-O-Ti organic–inorganic hybrid material using sulfoxide linkage. Inorg Chem Comm 13:358–360CrossRef
83.
Guo L, Yan B (2011) Photoluminescent lanthanide inorganic-organic hybrid systems with different metallic alkoxides components through 2-pyrazinecarboxylate linkage. J Photochem Photobiol A Chem 224:141–146CrossRef
84.
Yan B, Wang C, Liu JL, Guo L (2011) Photoactive europium hybrids of β-diketone-modified polysilsesquioxane bridge linking Si-O-B(Ti)-O xerogels. Eur J Inorg Chem 879–887
85.
Yan B, Wang C, Guo L, Liu JL (2010) Photophysical properties of Eu(III) center covalently immobilized in Si-O-B and Si-O-Ti composite gels. Photochem Photobiol 86:499–506CrossRef
86.
Yan B, Wang C (2011) Luminescent Eu3+/Tb3+immobilized in 5-amino-iso-phthalate functionalized hybrid gels through di-urea bridge. Inorg Chem Comm 14:1494–1497CrossRef
87.
Wang C, Yan B (2011) Rare earth (Eu3+, Tb3+) entered composite gels Si-O-M (M = B, Ti) through hexafluoroacetyl -acetone building block: sol-gel preparation, characterization and photoluminescence. Mater Res Bull 46:2515–2522CrossRef
Metadaten
Titel
Photofunctional Rare Earth Hybrid Materials Based on Organically Modified Silica
verfasst von
Bing Yan
Copyright-Jahr
2017
Verlag
Springer Singapore
Buch
Photofunctional Rare Earth Hybrid Materials

Print ISBN: 978-981-10-2956-1

Electronic ISBN: 978-981-10-2957-8

Copyright-Jahr: 2017

DOI
https://doi.org/10.1007/978-981-10-2957-8_2

Neuer Inhalt

    Bildnachweise