Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Topics in Catalysis
Erschienen in: Topics in Catalysis 12-14/2017

10.04.2017 | Original Paper

Plasma-Assisted Dispersion of Bimetallic Ni–Co over Al2O3–ZrO2 for CO2 Reforming of Methane: Influence of Voltage on Catalytic Properties

verfasst von: Nader Rahemi, Mohammad Haghighi, Ali Akbar Babaluo, Somaiyeh Allahyari, Pooya Estifaee, Mahdi Fallah Jafari

Erschienen in: Topics in Catalysis | Ausgabe 12-14/2017

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Glow discharge plasma with different voltages (700, 1000 and 1300 V) has been applied for treatment of Ni–Co/Al2O3–ZrO2 catalyst. Physicochemical properties of the catalysts were investigated by XRD, FESEM, BET and FTIR. Based on characterization results, there was an optimum amount of voltage (1000 V) in which the most uniform morphology, highest surface area and the smallest particle size was observed. On contrary of two other catalysts, 1000 V-treated Ni–Co/Al2O3–ZrO2 catalyst showed amorphous structure for NiO which led to improved dispersion of active phase and strong metal–support interactions. In this catalyst particle size distribution was narrow and average particle size was reported to be 21.2 nm. Dry reforming of methane to syngas using synthesized Ni–Co/Al2O3–ZrO2 nanocatalysts illustrated highest catalyst reactivity in the case of 1000 V-treated Ni–Co/Al2O3–ZrO2 nanocatalyst. This catalyst exhibited 99% feed conversion while 700 and 1300 V-treated catalysts showed 91 and 95% feed conversions at 850 °C, respectively. The H2/CO ratio over 700, 1000 and 1300 V treated catalysts was 0.83, 0.98 and 0.88, respectively.
Vorheriger Artikel Ni Supported on LaFeO3 Perovskites for Methane Steam Reforming: On the Promotional Effects of Plasma Treatment in H2–Ar Atmosphere
Nächster Artikel Non-Thermal Plasma-Assisted Catalytic Dry Reforming of Methane and Carbon Dioxide Over G-C3N4-Based Catalyst

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Cheng D-G (2008) Plasma decomposition and reduction in supported metal catalyst preparation. Catal Surv Asia 12(2):145–151CrossRef
2.
Wang X, Zhou M, Jin X (2012) Application of glow discharge plasma for wastewater treatment. Electrochim Acta 83:501–512CrossRef
3.
Nguyen Dinh MT, Giraudon JM, Vandenbroucke AM, Morent R, De Geyter N, Lamonier JF (2016) Manganese oxide octahedral molecular sieve K-OMS-2 as catalyst in post plasma-catalysis for trichloroethylene degradation in humid air. J Hazard Mat 314:88–94CrossRef
4.
Khataee A, Gholami P, Vahid B (2016) Heterogeneous sono-Fenton-like process using nanostructured pyrite prepared by Ar glow discharge plasma for treatment of a textile dye. Ultrason Sonochem 29:213–225CrossRef
5.
Chung W-C, Chang M-B (2016) Review of catalysis and plasma performance on dry reforming of CH4 and possible synergistic effects. Renew Sustain Energy Rev 62:13–31CrossRef
6.
Li Z, Liu S, Chen Z (2009) Study on plasma discharge parameters in double-glow plasma surface alloying furnace. Vacuum 83 (5):801–804CrossRef
7.
Zou J-J, Liu C-J, Zhang Y-P (2006) Control of the metalsSupport interface of NiO-loaded photocatalysts via cold plasma treatment. Langmuir 22(5):2334–2339CrossRef
8.
Liu C, Li M, Wang J, Zhou X, Guo Q, Yan J, Li Y (2016) Plasma methods for preparing green catalysts: current status and perspective. Chin J Catal 37(3):340–348CrossRef
9.
Khataee A, Rad TS, Vahid B, Khorram S (2016) Preparation of zeolite nanorods by corona discharge plasma for degradation of phenazopyridine by heterogeneous sono-Fenton-like process. Ultrason Sonochem 33:37–46CrossRef
10.
Chen G, Georgieva V, Godfroid T, Snyders R, Delplancke-Ogletree M-P (2016) Plasma assisted catalytic decomposition of CO2. Appl Catal B 190:115–124CrossRef
11.
Jahanmiri A, Rahimpour MR, Mohamadzadeh Shirazi M, Hooshmand N, Taghvaei H (2012) Naphtha cracking through a pulsed DBD plasma reactor: effect of applied voltage, pulse repetition frequency and electrode material. Chem Eng J 191:416–425CrossRef
12.
Rahimpour MR, Jahanmiri A, Mohamadzadeh Shirazi M, Hooshmand N, Taghvaei H (2013) Combination of non-thermal plasma and heterogeneous catalysis for methane and hexadecane co-cracking: effect of voltage and catalyst configuration. Chem Eng J 219:245–253CrossRef
13.
Lee DH, Kim T (2013) Plasma-catalyst hybrid methanol-steam reforming for hydrogen production. Int J Hydrogen Energy 38(14):6039–6043CrossRef
14.
Pérez C, Pereiro R, Bordel N, Sanz-Medel A (1998) Effect of operation parameters on the sputtering and emission processes in radiofrequency glow discharge. A comparison with the direct-current mode. Spectrochim Acta Part B 53(11):1541–1551CrossRef
15.
Bachiller-Baeza B, Mateos-Pedrero C, Soria MA, Guerrero-Ruiz A, Rodemerck U, Rodríguez-Ramos I (2013) Transient studies of low-temperature dry reforming of methane over Ni–CaO/ZrO2–La2O3. Appl Catal B 129:450–459CrossRef
16.
Zeng S, Zhang L, Zhang X, Wang Y, Pan H, Su H (2012) Modification effect of natural mixed rare earths on Co/γ-Al2O3 catalysts for CH4/CO2 reforming to synthesis gas. Int J Hydrogen Energy 37(13):9994–10001CrossRef
17.
Takahashi Y, Yamazaki T (2012) Behavior of high-pressure CH4/CO2 reforming reaction over mesoporous Pt/ZrO2 catalyst. Fuel 102:239–246CrossRef
18.
Oyama ST, Hacarlioglu P, Gu Y, Lee D (2012) Dry reforming of methane has no future for hydrogen production: comparison with steam reforming at high pressure in standard and membrane reactors. Int J Hydrogen Energy 37(13):10444–10450CrossRef
19.
Cheekatamarla PK, Finnerty CM (2006) Reforming catalysts for hydrogen generation in fuel cell applications. J Power Sources 160(1):490–499CrossRef
20.
Wisniewski M, Boréave A, Gélin P (2005) Catalytic CO2 reforming of methane over Ir/Ce0.9Gd0.1O2–x. Catal Commun 6(9):596–600CrossRef
21.
Abdollahifar M, Haghighi M, Babaluo AA, Khajeh Talkhoncheh S (2016) Sono-synthesis and characterization of bimetallic Ni–Co/Al2O3–MgO nanocatalyst: effects of metal content on catalytic properties and activity for hydrogen production via CO2 reforming of CH4. Ultrason Sonochem 31:173–183CrossRef
22.
Yahyavi SR, Haghighi M, Shafiei S, Abdollahifar M, Rahmani F (2015) Ultrasound-assisted synthesis and physicochemical characterization of Ni–Co/Al2O3–MgO nanocatalysts enhanced by different amounts of MgO used for CH4/CO2 reforming. Energy Convers Manage 97:273–281CrossRef
23.
Sharifi M, Haghighi M, Abdollahifar M (2015) Sono-dispersion of bimetallic Ni–Co over Zeolite Y used in conversion of greenhouse gases CH4/CO2 to high valued syngas. J Nat Gas Sci Eng 23:547–558CrossRef
24.
Sajjadi SM, Haghighi M, Rahmani F (2015) Syngas production from CO2-Reforming of CH4 over Sol-Gel Synthesized Ni–Co/Al2O3–MgO–ZrO2 nanocatalyst: effect of ZrO2 precursor on catalyst properties and performance. Química Nova 38 (4):459–465
25.
Sajjadi SM, Haghighi M, Rahmani F (2015) Sol-Gel synthesis of Ni–Co/Al2O3–MgO–ZrO2 nanocatalyst used in hydrogen production via reforming of CH4/CO2 greenhouse gases. J Nat Gas Sci Eng 22:9–21CrossRef
26.
Wang S, Lu GQ, Millar GJ (1996) Carbon dioxide reforming of methane to produce synthesis gas over metal-supported catalysts: state of the art. Energy Fuels 10(4):896–904CrossRef
27.
Zhang J, Wang H, Dalai AK (2007) Development of stable bimetallic catalysts for carbon dioxide reforming of methane. J Catal 249(2):300–310CrossRef
28.
Luisetto I, Tuti S, Di Bartolomeo E (2012) Co and Ni supported on CeO2 as selective bimetallic catalyst for dry reforming of methane. Int J Hydrogen Energy 37(21):15992–15999CrossRef
29.
Sutthiumporn K, Kawi S (2011) Promotional effect of alkaline earth over Ni–La2O3 catalyst for CO2 reforming of CH4: role of surface oxygen species on H2 production and carbon suppression. Int J Hydrogen Energy 36(22):14435–14446CrossRef
30.
Kang K-M, Kim H-W, Shim I-W, Kwak H-Y (2011) Catalytic test of supported Ni catalysts with core/shell structure for dry reforming of methane. Fuel Process Technol 92(6):1236–1243CrossRef
31.
Huang J, Ma R, Huang T, Zhang A, Huang W (2011) Carbon dioxide reforming of methane over Ni/Mo/SBA-15-La2O3 catalyst: Its characterization and catalytic performance. J Nat Gas Chem 20(5):465–470CrossRef
32.
Jin L, Li Y, Lin P, Hu H (2014) CO2 reforming of methane on Ni/γ-Al2O3 catalyst prepared by dielectric barrier discharge hydrogen plasma. Int J Hydrogen Energy 39(11):5756–5763CrossRef
33.
Zhang X, Sun W-j, Chu W (2013) Effect of glow discharge plasma treatment on the performance of Ni/SiO2 catalyst in CO2 methanation. J Fuel Chem Technol 41(1):96–101CrossRef
34.
Zheng X, Tan S, Dong L, Li S, Chen H (2014) LaNiO3@SiO2 core–shell nano-particles for the dry reforming of CH4 in the dielectric barrier discharge plasma. Int J Hydrogen Energy 39(22):11360–11367CrossRef
35.
Rahemi N, Haghighi M, Babaluo AA, Allahyari S, Jafari MF (2014) Syngas production from reforming of greenhouse gases CH4/CO2 over Ni–Cu/Al2O3 nanocatalyst: impregnated vs. plasma-treated catalyst. Energy Convers Manage 84:50–59CrossRef
36.
Rahemi N, Haghighi M, Babaluo AA, Jafari MF, Khorram S (2013) Non-thermal plasma assisted synthesis and physicochemical characterizations of Co and Cu doped Ni/Al2O3 nanocatalysts used for dry reforming of methane. Int J Hydrogen Energy 38(36):16048–16061CrossRef
37.
Estifaee P, Haghighi M, Babaluo AA, Rahemi N, Jafari MF (2014) The beneficial use of non-thermal plasma in synthesis of Ni/Al2O3–MgO nanocatalyst used in hydrogen production from reforming of CH4/CO2 greenhouse gases. J Power Sources 257:364–373CrossRef
38.
Rahemi N, Haghighi M, Babaluo AA, Jafari MF, Allahyari S (2013) The effect of the calcination temperature on the physicochemical properties and catalytic activity in the dry reforming of methane over a Ni–Co/Al2O3–ZrO2 nanocatalyst prepared by a hybrid impregnation-plasma method. Catal Sci Technol 3(12):3183–3191CrossRef
39.
Kannan S, Narayanan A, Swamy CS (1996) Effect of composition on the physicochemical properties of nickel aluminium hydrotalcites. J Mater Sci 31(9):2353–2360CrossRef
40.
Jamalzadeh Z, Haghighi M, Asgari N (2013) Synthesis, physicochemical characterizations and catalytic performance of Pd/carbon-zeolite and Pd/carbon-CeO2 nanocatalysts used for total oxidation of xylene at low temperatures. Front Environ Sci Eng 7 (3):365–381CrossRef
41.
Khoshbin R, Haghighi M, Asgari N (2013) Direct synthesis of dimethyl ether on the admixed nanocatalysts of CuO–ZnO–Al2O3 and HNO3-modified clinoptilolite at high pressures: surface properties and catalytic performance. Mater Res Bull 48(2):767–777CrossRef
42.
Aghamohammadi S, Haghighi M, Charghand M (2014) Methanol conversion to light olefins over nanostructured CeAPSO-34 catalyst: thermodynamic analysis of overall reactions and effect of template type on catalytic properties and performance. Mater Res Bull 50:462–475CrossRef
43.
Allahyari S, Haghighi M, Ebadi A, Hosseinzadeh S (2014) Effect of irradiation power and time on ultrasound assisted co-precipitation of nanostructured CuO–ZnO–Al2O3 over HZSM-5 used for direct conversion of syngas to DME as a green fuel. Energy Convers Manage 83:212–222CrossRef
44.
Allahyari S, Haghighi M, Ebadi A, Qavam Saeedi H (2014) Direct synthesis of dimethyl ether as a green fuel from syngas over nanostructured CuO–ZnO–Al2O3/HZSM-5 catalyst: influence of irradiation time on nanocatalyst properties and catalytic performance. J Power Sources 272:929–939CrossRef
45.
Lacombe S, Geantet C, Mirodatos C (1995) Oxidative coupling of methane over lanthana catalysts: I. identification and role of specific active-sites. J Catal 151(2):439–452CrossRef
46.
Yosefi L, Haghighi M, Allahyari S, Ashkriz S (2015) Effect of ultrasound irradiation and Ni-loading on properties and performance of CeO2-doped Ni/clinoptilolite nanocatalyst used in polluted air treatment. Process Safety Environ Prot 95:26–37CrossRef
47.
Jeevanandam P, Koltypin Y, Gedanken A (2002) Preparation of nanosized nickel aluminate spinel by a sonochemical method. Mater Sci Eng 90(1–2):125–132CrossRef
48.
Khoshbin R, Haghighi M (2013) A comparative study on the dispersion of CuO–ZnO–Al2O3 nanoparticles over HZSM-5 via Batch Co-precipitation, semibatch Co-precipitation and combined Co-precipitation-ultrasound methods. Chem Solid Mater 1(1):1–16
49.
Abdollahifar M, Haghighi M, Babaluo AA (2014) Syngas production via dry reforming of methane over Ni/Al2O3–MgO nanocatalyst synthesized using ultrasound energy. J Ind Eng Chem 20(4):1845–1851CrossRef
50.
Charghand M, Haghighi M, Aghamohammadi S (2014) The beneficial use of ultrasound in synthesis of nanostructured Ce-doped SAPO-34 used in methanol conversion to light olefins. Ultrason Sonochem 21(5):1827–1838CrossRef
51.
Sajjadi SM, Haghighi M, Rahmani F (2014) Dry reforming of greenhouse gases CH4/CO2 over MgO-promoted Ni-Co/Al2O3-ZrO2 nanocatalyst: effect of MgO addition via sol-gel method on catalytic properties and hydrogen yield. J Sol-Gel Sci Technol 70(1):111–124CrossRef
52.
Miyata S (1975) The syntheses of hydrotalcite-like compounds and their structures and physico-chemical properties I: the systems Mg2+–Al3+–NO3–, Mg2+–Al3+–Cl–, Mg2+–Al3+–ClO4–, Ni2+–Al3+-Cl– and Zn2+–Al3+–Cl–. Clay Clay Miner 23:369–375CrossRef
53.
Asgari N, Haghighi M, Shafiei S (2013) Synthesis and physicochemical characterization of nanostructured Pd/Ceria-Clinoptilolite catalyst used for P-Xylene abatement from waste gas streams at low temperature. J Chem Technol Biotechnol 88(4):690–703CrossRef
54.
Khoshbin R, Haghighi M (2012) Urea–nitrate combustion synthesis and physicochemical characterization of CuO–ZnO–Al2O3 Nanoparticles over HZSM-5. Chin J Inorg Chem 28(9):1967–1978
55.
Khoshbin R, Haghighi M (2014) Direct conversion of syngas to dimethyl ether as a green fuel over ultrasound-assisted synthesized CuO–ZnO–Al2O3/HZSM-5 nanocatalyst: effect of active phase ratio on physicochemical and catalytic properties at different process conditions. Catal Sci Technol 4(6):1779–1792CrossRef
56.
Edwards JH, Maitra AM (1995) The chemistry of methane reforming with carbon dioxide and its current and potential applications. Fuel Process Technol 42(2–3):269–289CrossRef
Metadaten
Titel
Plasma-Assisted Dispersion of Bimetallic Ni–Co over Al2O3–ZrO2 for CO2 Reforming of Methane: Influence of Voltage on Catalytic Properties
verfasst von
Nader Rahemi
Mohammad Haghighi
Ali Akbar Babaluo
Somaiyeh Allahyari
Pooya Estifaee
Mahdi Fallah Jafari
Publikationsdatum
10.04.2017
Verlag
Springer US
Erschienen in
Topics in Catalysis / Ausgabe 12-14/2017
Print ISSN: 1022-5528
Elektronische ISSN: 1572-9028
DOI
https://doi.org/10.1007/s11244-017-0749-5

Weitere Artikel der Ausgabe 12-14/2017

Topics in Catalysis 12-14/2017 Zur Ausgabe

Original Paper

Hybrid Plasma-Catalytic Oxidation of VOCs with NiMn/Montmorillonite: Plasma and Catalyst Considerations

Original Paper

Effect of Persulfate on the Degradation of Acid Orange 7 (AO7) by Dielectric Barrier Discharge Plasma

Original Paper

Plasma Synthesis of Ni2P from Mixtures of NiCl2 and Hypophosphites

Original Paper

Atmospheric Discharge Plasma Enhanced Preparation of Pd/TiO2 Catalysts for Acetylene Selective Hydrogenation

Original Paper

CO Dissociation on Ni/SiO2: The Formation of Different Carbon Materials

Original Paper

Glass Beads Packed DBD-Plasma Assisted Dry Reforming of Methane

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise