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2014 | OriginalPaper | Buchkapitel

Polymer-Based Micro/Nano Cantilever Electro-Mechanical Sensor Systems for Bio/Chemical Sensing Applications

verfasst von : Rajul S. Patkar, Manoj Kandpal, Neena Gilda, Prasenjit Ray, V. Ramgopal Rao

Erschienen in: Micro and Smart Devices and Systems

Verlag: Springer India

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Abstract

In this chapter, we present the status of polymer cantilever sensor platforms for biochemical sensing and energy harvesting applications. We introduce a novel process flow for polymer microstructure fabrication called the SPARE MEMS, which involves Spinning of sacrificial/structural layers, Patterning, Anchor formation and the final RElease of the device stack along with the anchor from the substrate. In this process the wafer is spared and is reusable. An organic/thin film FET embedded cantilever devices (CantiFETs) have been demonstrated using this process in order to reduce the noise levels and to achieve high deflection sensitivities. We have also used the SPARE MEMS process to fabricate a variety of other piezoresistive polymer cantilever devices with the highest reported deflection sensitivity (>100 parts-per-million/nm) to surface stress. Electronic circuit design approaches for the detection of ΔR down to sub parts-per-million level of resolution for piezoresistive cantilevers are also discussed. Using various surface coatings, development of sensor systems and sensor nodes for the detection of nitro-based explosive compounds, cardiac proteins, and environmental sensors are demonstrated. For powering the sensors, a novel piezoelectric polymer composite platform has been proposed.

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Literatur
1.
Zurück zum Zitat Ibbotson RH, Dunn RJ, Djakov V et al (2008) Polyimide microcantilever surface stress sensor using low-cost, rapidly-interchangeable, spring-loaded microprobe connections. Microelectron Eng 85:1314–1317CrossRef Ibbotson RH, Dunn RJ, Djakov V et al (2008) Polyimide microcantilever surface stress sensor using low-cost, rapidly-interchangeable, spring-loaded microprobe connections. Microelectron Eng 85:1314–1317CrossRef
2.
Zurück zum Zitat Huanga S, Zhanga X (2005) Application of polyimide sacrificial layers for the manufacturing of uncooled double-cantilever microbolometer. Presented at the MRS Fall Meeting, Boston, MA, 2005 Huanga S, Zhanga X (2005) Application of polyimide sacrificial layers for the manufacturing of uncooled double-cantilever microbolometer. Presented at the MRS Fall Meeting, Boston, MA, 2005
3.
Zurück zum Zitat Chen C-L, Lopez E, Makaram P et al (2007) Fabrication and evaluation of carbon nanotube-parylene functional composite films. Transducers and eurosensors’ the 14th international conference on solid-state sensors, actuators and microsystems, Lyon, France, 10–14 June 2007 Chen C-L, Lopez E, Makaram P et al (2007) Fabrication and evaluation of carbon nanotube-parylene functional composite films. Transducers and eurosensors’ the 14th international conference on solid-state sensors, actuators and microsystems, Lyon, France, 10–14 June 2007
4.
Zurück zum Zitat Shiraishia N, Ikehara T, Dao DV et al (2013) Fabrication and testing of polymer cantilevers for VOC sensors. Sens Actuators A 202:233–239CrossRef Shiraishia N, Ikehara T, Dao DV et al (2013) Fabrication and testing of polymer cantilevers for VOC sensors. Sens Actuators A 202:233–239CrossRef
5.
Zurück zum Zitat Kshirsagar A, Duttagupta SP, Gangal SA (2012) Optimization of poly(methyl methacrylate) as sacrificial layer for application in low temperature MEMS. 1st international symposium on physics and technology of sensors (ISPTS), pp 114–117 Kshirsagar A, Duttagupta SP, Gangal SA (2012) Optimization of poly(methyl methacrylate) as sacrificial layer for application in low temperature MEMS. 1st international symposium on physics and technology of sensors (ISPTS), pp 114–117
6.
Zurück zum Zitat Kale NS, Nag S, Pinto R et al (2009) Fabrication and characterization of a polymeric microcantilever with an encapsulated hotwire CVD polysilicon piezoresistor. J Microelectromech Syst 18(1):79–87 Kale NS, Nag S, Pinto R et al (2009) Fabrication and characterization of a polymeric microcantilever with an encapsulated hotwire CVD polysilicon piezoresistor. J Microelectromech Syst 18(1):79–87
7.
Zurück zum Zitat Seena V, Fernandes A, Pant Prita et al (2011) Polymer nanocomposite nanomechanical cantilever sensors: material characterization, device development and application in explosive vapour detection. Nanotechnology 22:295501CrossRef Seena V, Fernandes A, Pant Prita et al (2011) Polymer nanocomposite nanomechanical cantilever sensors: material characterization, device development and application in explosive vapour detection. Nanotechnology 22:295501CrossRef
8.
Zurück zum Zitat Ray P, Rao VR (2013) ZnO nanowire embedded strain sensing cantilever: a new ultra-sensitive technology platform. J Microelectromech Syst 22(5):995–997 Ray P, Rao VR (2013) ZnO nanowire embedded strain sensing cantilever: a new ultra-sensitive technology platform. J Microelectromech Syst 22(5):995–997
9.
Zurück zum Zitat Kandpal M, Sharan C, Poddar P et al (2012) Photopatternable nano-composite (SU-8/ZnO) thin films for piezo-electric applications. Appl Phys Lett 101:104102–104105CrossRef Kandpal M, Sharan C, Poddar P et al (2012) Photopatternable nano-composite (SU-8/ZnO) thin films for piezo-electric applications. Appl Phys Lett 101:104102–104105CrossRef
10.
Zurück zum Zitat Sutter M, Ergeneman O, Zurcher J et al (2011) A photopatternable superparamagnetic nanocomposite: material characterization and fabrication of microstructures. Sens Actuators B 156:433–443 Sutter M, Ergeneman O, Zurcher J et al (2011) A photopatternable superparamagnetic nanocomposite: material characterization and fabrication of microstructures. Sens Actuators B 156:433–443
11.
Zurück zum Zitat Prashanthi K, Naresh M, Seena V et al (2012) A novel photoplastic piezoelectric nanocomposite for MEMS applications. J MEMS Lett 21:259–261CrossRef Prashanthi K, Naresh M, Seena V et al (2012) A novel photoplastic piezoelectric nanocomposite for MEMS applications. J MEMS Lett 21:259–261CrossRef
12.
Zurück zum Zitat Nemani KV, Moodie KL, Brennick JB et al (2013) In vitro and in vivo evaluation of SU-8 biocompatibility. Mater Sci Eng C 33:4453–4459 Nemani KV, Moodie KL, Brennick JB et al (2013) In vitro and in vivo evaluation of SU-8 biocompatibility. Mater Sci Eng C 33:4453–4459
13.
Zurück zum Zitat Boisen A, Dohn S, Keller SS et al (2011) Cantilever like micromechanical sensors. Rep Prog Phys 74:036101 Boisen A, Dohn S, Keller SS et al (2011) Cantilever like micromechanical sensors. Rep Prog Phys 74:036101
15.
Zurück zum Zitat Fletcher PC (2006) Piezoresistive geometry for maximizing microcantilever array sensitivity. Master of engineering thesis Fletcher PC (2006) Piezoresistive geometry for maximizing microcantilever array sensitivity. Master of engineering thesis
16.
Zurück zum Zitat Hosseinzadegan H, Todd C, Lal A et al Graphene has ultra-high gauge factor. The SonicMEMS Laboratory, School of Electrical and Computer Engineering Cornell University, Ithaca, NY, USA Hosseinzadegan H, Todd C, Lal A et al Graphene has ultra-high gauge factor. The SonicMEMS Laboratory, School of Electrical and Computer Engineering Cornell University, Ithaca, NY, USA
17.
Zurück zum Zitat Safari A (1994) Development of piezoelectric composites for transducers. J Phys III Fr 4:1129–1149 Safari A (1994) Development of piezoelectric composites for transducers. J Phys III Fr 4:1129–1149
18.
Zurück zum Zitat Shekhawat G, Tark S-H, Dravid VP (2006) MOSFET-embedded microcantilevers for measuring deflection in biomolecular sensors. Science 311(5767):1592–1595CrossRef Shekhawat G, Tark S-H, Dravid VP (2006) MOSFET-embedded microcantilevers for measuring deflection in biomolecular sensors. Science 311(5767):1592–1595CrossRef
19.
Zurück zum Zitat Seena V, Nigam A, Pant P et al (2012) Organic cantiFET: a nanomechanical polymer cantilever sensor with integrated OFET. J Microelectromech Syst 21(2):294–301 Seena V, Nigam A, Pant P et al (2012) Organic cantiFET: a nanomechanical polymer cantilever sensor with integrated OFET. J Microelectromech Syst 21(2):294–301
20.
Zurück zum Zitat Ray P, Rao VR (2013) Al-doped ZnO thin-film transistor embedded micro-cantilever as a piezoresistive sensor. Appl Phys Lett 102:064101 Ray P, Rao VR (2013) Al-doped ZnO thin-film transistor embedded micro-cantilever as a piezoresistive sensor. Appl Phys Lett 102:064101
21.
Zurück zum Zitat Rasmussen PA, Thaysen J, Hansen O et al (2003) Optimised cantilever biosensor with piezoresistive read-out. Ultramicroscopy 97:371–376CrossRef Rasmussen PA, Thaysen J, Hansen O et al (2003) Optimised cantilever biosensor with piezoresistive read-out. Ultramicroscopy 97:371–376CrossRef
22.
Zurück zum Zitat Ray P, Seena V, Khare RA et al (2010) MRS proceedings, vol 1299. Cambridge University Press, Boston, Massachusetts Ray P, Seena V, Khare RA et al (2010) MRS proceedings, vol 1299. Cambridge University Press, Boston, Massachusetts
23.
Zurück zum Zitat Huang MH, Wu Y, Feick H et al (2001) Catalytic growth of zinc oxide nanowires by vapor transport. Adv Mater 13(2):113CrossRef Huang MH, Wu Y, Feick H et al (2001) Catalytic growth of zinc oxide nanowires by vapor transport. Adv Mater 13(2):113CrossRef
24.
Zurück zum Zitat Donald AN (2011) Semiconductor physics and device. McGraw-Hill, New York, p 320 Donald AN (2011) Semiconductor physics and device. McGraw-Hill, New York, p 320
25.
Zurück zum Zitat Nagata T, Ahmet P, Yoo YZ et al (2006) Schottky metal library for ZNO-based UV photodiode fabricated by the combinatorial ion beam-assisted deposition. Appl Surf Sci 252(7):2503–2506CrossRef Nagata T, Ahmet P, Yoo YZ et al (2006) Schottky metal library for ZNO-based UV photodiode fabricated by the combinatorial ion beam-assisted deposition. Appl Surf Sci 252(7):2503–2506CrossRef
26.
Zurück zum Zitat Newnham RE, Skinner DP, Cross LE (1978) Connectivity and piezeoelectric-pyroelectric composites. Mater Res Bull 13:525–536CrossRef Newnham RE, Skinner DP, Cross LE (1978) Connectivity and piezeoelectric-pyroelectric composites. Mater Res Bull 13:525–536CrossRef
27.
Zurück zum Zitat Teh WH, Durig U, Drechsler U et al (2005) Effect of low numerical-aperture femtosecond two-photon absorption on (SU-8) resist for ultrahigh-aspect-ratio micro stereo lithography. J Appl Phys 97:054907–054911CrossRef Teh WH, Durig U, Drechsler U et al (2005) Effect of low numerical-aperture femtosecond two-photon absorption on (SU-8) resist for ultrahigh-aspect-ratio micro stereo lithography. J Appl Phys 97:054907–054911CrossRef
28.
Zurück zum Zitat Ge J, Zeng X, Tao X, Li X et al (2010) Preparation and characterization of PS-PMMA/ZnO nanocomposite films with novel properties of high transparency and UV-shielding capacity. J Appl Polym Sci 118:1507–1512 Ge J, Zeng X, Tao X, Li X et al (2010) Preparation and characterization of PS-PMMA/ZnO nanocomposite films with novel properties of high transparency and UV-shielding capacity. J Appl Polym Sci 118:1507–1512
29.
Zurück zum Zitat Liu JM, Pan B, Chan HLW et al (2002) Piezoelectric coefficient measurement of piezoelectric thin films: an overview. Mater Chem Phys 75:12–18 Liu JM, Pan B, Chan HLW et al (2002) Piezoelectric coefficient measurement of piezoelectric thin films: an overview. Mater Chem Phys 75:12–18
30.
Zurück zum Zitat Kalinin V, Rar A, Jesse S (2006) A decade of piezoresponse force microscopy: progress, challenges, and opportunities. IEEE Trans Ultrason Ferroelectr Freq Control 53:2226–2252 Kalinin V, Rar A, Jesse S (2006) A decade of piezoresponse force microscopy: progress, challenges, and opportunities. IEEE Trans Ultrason Ferroelectr Freq Control 53:2226–2252
31.
Zurück zum Zitat Zhao MH, Wang ZL, Mao SX (2004) Piezoelectric characterization of individual zinc oxide nanobelt probed by piezoresponse force microscope. Nano Lett 4:587–590CrossRef Zhao MH, Wang ZL, Mao SX (2004) Piezoelectric characterization of individual zinc oxide nanobelt probed by piezoresponse force microscope. Nano Lett 4:587–590CrossRef
32.
Zurück zum Zitat Agrawal R, Espinosa DH (2011) Giant piezoelectric size effects in zinc oxide and gallium nitride nanowires: a first principles investigation. Nano Lett 11:786–790CrossRef Agrawal R, Espinosa DH (2011) Giant piezoelectric size effects in zinc oxide and gallium nitride nanowires: a first principles investigation. Nano Lett 11:786–790CrossRef
33.
Zurück zum Zitat Dai S, Gharbi M, Sharma P, Park HS (2011) Surface piezoelectricity: size effects in nanostructures and the emergence of piezoelectricity in non-piezoelectric materials. J Appl Phys 110:104305–104307 Dai S, Gharbi M, Sharma P, Park HS (2011) Surface piezoelectricity: size effects in nanostructures and the emergence of piezoelectricity in non-piezoelectric materials. J Appl Phys 110:104305–104307
34.
Zurück zum Zitat Senesac L, Thundat TG (2008) Nanosensors for explosive detection. Mater Today 11(3):28–36CrossRef Senesac L, Thundat TG (2008) Nanosensors for explosive detection. Mater Today 11(3):28–36CrossRef
35.
Zurück zum Zitat Longo G, Alonso-Sarduy L, Rio LM et al (2013) Rapid detection of bacterial resistance to antibiotics using AFM cantilevers as nanomechanical sensors. Nat Nanotechnol 8(7):522–526CrossRef Longo G, Alonso-Sarduy L, Rio LM et al (2013) Rapid detection of bacterial resistance to antibiotics using AFM cantilevers as nanomechanical sensors. Nat Nanotechnol 8(7):522–526CrossRef
36.
Zurück zum Zitat Kosaka PM, Tamayo J, Ruz JJ et al (2013) Tackling reproducibility in microcantilever biosensors: a statistical approach for sensitive and specific end-point detection of immunoreactions. Analyst 138:863–872 Kosaka PM, Tamayo J, Ruz JJ et al (2013) Tackling reproducibility in microcantilever biosensors: a statistical approach for sensitive and specific end-point detection of immunoreactions. Analyst 138:863–872
37.
Zurück zum Zitat Lang HP, Baller MK, Berger R et al (1999) An artificial nose based on a micromechanical cantilever array. Anal Chim Acta 393:59–65CrossRef Lang HP, Baller MK, Berger R et al (1999) An artificial nose based on a micromechanical cantilever array. Anal Chim Acta 393:59–65CrossRef
38.
Zurück zum Zitat Sen X, Mutharasan R (2009) Cantilever biosensors in drug discovery. Inf Healthc 4(12):1237–1251 Sen X, Mutharasan R (2009) Cantilever biosensors in drug discovery. Inf Healthc 4(12):1237–1251
39.
Zurück zum Zitat Reddy CVB, Khaderbad MA, Gandhi S et al (2012) Piezoresistive SU-8 cantilever with Fe(III)porphyrin coating for CO sensing. IEEE Trans Nanotechnol 11(4):701–706 Reddy CVB, Khaderbad MA, Gandhi S et al (2012) Piezoresistive SU-8 cantilever with Fe(III)porphyrin coating for CO sensing. IEEE Trans Nanotechnol 11(4):701–706
40.
Zurück zum Zitat Joshi M, Pinto R, Rao VR, Mukherji S (2007) Silanization and antibody immobilization on SU-8. Appl Surf Sci 25(6):3127–3132 Joshi M, Pinto R, Rao VR, Mukherji S (2007) Silanization and antibody immobilization on SU-8. Appl Surf Sci 25(6):3127–3132
41.
Zurück zum Zitat Joshi M, Kale N, Lal R, Rao VR, Mukherji S (2007) A novel dry method for surface modification of SU-8 for immobilization of biomolecules in bio-MEMS. Biosens Bioelectron 22:2429–2435 Joshi M, Kale N, Lal R, Rao VR, Mukherji S (2007) A novel dry method for surface modification of SU-8 for immobilization of biomolecules in bio-MEMS. Biosens Bioelectron 22:2429–2435
42.
Zurück zum Zitat Nag S, Kale NS, Rao V et al (2009) An ultra-sensitive delta R/R measurement system for biochemical sensors using piezo resistive micro-cantilevers. Conf Proc IEEE Eng Med Biol Soc 2009:3794–3797 Nag S, Kale NS, Rao V et al (2009) An ultra-sensitive delta R/R measurement system for biochemical sensors using piezo resistive micro-cantilevers. Conf Proc IEEE Eng Med Biol Soc 2009:3794–3797
43.
Zurück zum Zitat Sangtong S, Thanachayanont A (2007) Low-voltage CMOS instrumentation amplifier for piezoresistive transducer. ETRI J 29(1):70–78CrossRef Sangtong S, Thanachayanont A (2007) Low-voltage CMOS instrumentation amplifier for piezoresistive transducer. ETRI J 29(1):70–78CrossRef
44.
Zurück zum Zitat Ferrari V, Ghisla A, Vajna ZK et al (2007) ASIC front-end interface with frequency and duty cycle output for resistive-bridge sensors. Elsevier Sci Direct Sens Actuators A 138:112–119 Ferrari V, Ghisla A, Vajna ZK et al (2007) ASIC front-end interface with frequency and duty cycle output for resistive-bridge sensors. Elsevier Sci Direct Sens Actuators A 138:112–119
45.
Zurück zum Zitat Gilda NA, Nag S, Patil S et al (2013) Current excitation method for ∆R measurement in piezo-resistive sensors with a 0.3-ppm resolution. IEEE Trans Instrum Meas 61(3):767–774 Gilda NA, Nag S, Patil S et al (2013) Current excitation method for ∆R measurement in piezo-resistive sensors with a 0.3-ppm resolution. IEEE Trans Instrum Meas 61(3):767–774
46.
Zurück zum Zitat Gilda NA, Patil S, Seena V et al (2011) Piezoresistive 6-MNA coated microcantilevers with signal conditioning circuits for electronic nose. ASSCC 2011, pp 121–124 Gilda NA, Patil S, Seena V et al (2011) Piezoresistive 6-MNA coated microcantilevers with signal conditioning circuits for electronic nose. ASSCC 2011, pp 121–124
47.
Zurück zum Zitat Gilda NA, Surya S, Joshi S et al (2011) A low-cost, ultra-sensitive hand-held system for explosive detection using piezo-resistive micro-cantilevers. ISOCC 2011, pp 325–328 Gilda NA, Surya S, Joshi S et al (2011) A low-cost, ultra-sensitive hand-held system for explosive detection using piezo-resistive micro-cantilevers. ISOCC 2011, pp 325–328
Metadaten
Titel
Polymer-Based Micro/Nano Cantilever Electro-Mechanical Sensor Systems for Bio/Chemical Sensing Applications
verfasst von
Rajul S. Patkar
Manoj Kandpal
Neena Gilda
Prasenjit Ray
V. Ramgopal Rao
Copyright-Jahr
2014
Verlag
Springer India
DOI
https://doi.org/10.1007/978-81-322-1913-2_24

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