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2016 | OriginalPaper | Buchkapitel

24. Polymer Electrets and Ferroelectrets as EAPs: Fundamentals

verfasst von : Ingrid Graz, Axel Mellinger

Erschienen in: Electromechanically Active Polymers

Verlag: Springer International Publishing

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Abstract

Electrets are dielectric materials capable of quasi-permanently storing electric charges at their surface or in their bulk. This chapter presents a brief history of electret research, followed by a classification and introduction of the most important electret materials. The chapter also discusses ferroelectrets and recent developments in charge stability.

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Literatur
Zurück zum Zitat Ahlheim M, Lehr F (1994) Electrooptically active polymers. Non‐linear optical polymers prepared from maleic anhydride copolymers by polymer analogous reactions. Macromol Chem Phys 195:361–373CrossRef Ahlheim M, Lehr F (1994) Electrooptically active polymers. Non‐linear optical polymers prepared from maleic anhydride copolymers by polymer analogous reactions. Macromol Chem Phys 195:361–373CrossRef
Zurück zum Zitat Bauer S (2006) Piezo-, pyro-and ferroelectrets: soft transducer materials for electromechanical energy conversion. IEEE Trans Dielectr Electr Insul 5:953–962 Bauer S (2006) Piezo-, pyro-and ferroelectrets: soft transducer materials for electromechanical energy conversion. IEEE Trans Dielectr Electr Insul 5:953–962
Zurück zum Zitat Bauer S, Gerhard-Multhaupt R et al (2004) Ferroelectrets: soft electroactive foams for transducers. Phys Today 57(2):37–43CrossRef Bauer S, Gerhard-Multhaupt R et al (2004) Ferroelectrets: soft electroactive foams for transducers. Phys Today 57(2):37–43CrossRef
Zurück zum Zitat Bauer-Gogonea S, Bauer S (2001) Polymer electrets for electronics, sensors, and photonics. In: Nalwa HS (ed) Handbook of advanced electronic and photonic materials and devices. Academic, Burlington, pp 185–231CrossRef Bauer-Gogonea S, Bauer S (2001) Polymer electrets for electronics, sensors, and photonics. In: Nalwa HS (ed) Handbook of advanced electronic and photonic materials and devices. Academic, Burlington, pp 185–231CrossRef
Zurück zum Zitat Broadhurst MG, Davis GT et al (1978) Piezoelectricity and pyroelectricity in PVDF a model. J Appl Phys 49(10):4992–4997CrossRef Broadhurst MG, Davis GT et al (1978) Piezoelectricity and pyroelectricity in PVDF a model. J Appl Phys 49(10):4992–4997CrossRef
Zurück zum Zitat Brodribb JD, O’Colmain D et al (1975) The theory of photon-stimulated current spectroscopy. J Phys D 8:856–862CrossRef Brodribb JD, O’Colmain D et al (1975) The theory of photon-stimulated current spectroscopy. J Phys D 8:856–862CrossRef
Zurück zum Zitat Curie J, Curie P (1880) Développement par compression de l’ electricité polaire dans les cristaux hémiedres a faces inclines. Bull Soc Minerol Fr 3:90–93 Curie J, Curie P (1880) Développement par compression de l’ electricité polaire dans les cristaux hémiedres a faces inclines. Bull Soc Minerol Fr 3:90–93
Zurück zum Zitat Farona MF (1996) Benzocyclobutenes in polymer chemistry. Prog Polym Sci 21(3):505–555CrossRef Farona MF (1996) Benzocyclobutenes in polymer chemistry. Prog Polym Sci 21(3):505–555CrossRef
Zurück zum Zitat Gray S (1732) A letter concerning the electricity of water, from Mr. Stephen Gray to Cromwell Mortimer, MD Secr. RS. Philos Trans R Soc Lond Ser A 37:285CrossRef Gray S (1732) A letter concerning the electricity of water, from Mr. Stephen Gray to Cromwell Mortimer, MD Secr. RS. Philos Trans R Soc Lond Ser A 37:285CrossRef
Zurück zum Zitat Graz I, Kaltenbrunner M et al (2006) Flexible ferroelectret field-effect transistor for large-area sensor skins and microphones. Appl Phys Lett 89:073501CrossRef Graz I, Kaltenbrunner M et al (2006) Flexible ferroelectret field-effect transistor for large-area sensor skins and microphones. Appl Phys Lett 89:073501CrossRef
Zurück zum Zitat Harris S, Mellinger A (2014) Towards a better understanding of dielectric barrier discharges in ferroelectrets: Paschen breakdown fields in micrometer sized voids. J Appl Phys 115:163302CrossRef Harris S, Mellinger A (2014) Towards a better understanding of dielectric barrier discharges in ferroelectrets: Paschen breakdown fields in micrometer sized voids. J Appl Phys 115:163302CrossRef
Zurück zum Zitat Hattori T, Takahashi T et al (1996) Piezoelectric and ferroelectric properties of polyurea‐5 thin films prepared by vapor deposition polymerization. J Appl Phys 79:1713CrossRef Hattori T, Takahashi T et al (1996) Piezoelectric and ferroelectric properties of polyurea‐5 thin films prepared by vapor deposition polymerization. J Appl Phys 79:1713CrossRef
Zurück zum Zitat Heaviside O (1885) Electromagnetic induction and its propagation, electrization and electrification. Natural electrets. Electrician :230–231 Heaviside O (1885) Electromagnetic induction and its propagation, electrization and electrification. Natural electrets. Electrician :230–231
Zurück zum Zitat Hu Z, von Seggern H (2006) Breakdown-induced polarization buildup in porous fluoropolymer sandwiches: a thermally stable piezoelectret. J Appl Phys 99:024102CrossRef Hu Z, von Seggern H (2006) Breakdown-induced polarization buildup in porous fluoropolymer sandwiches: a thermally stable piezoelectret. J Appl Phys 99:024102CrossRef
Zurück zum Zitat Huang C, West JE et al (2007) Organic field‐effect transistors and unipolar logic gates on charged electrets from spin‐on organosilsesquioxane resins. Adv Funct Mater 17:142–153CrossRef Huang C, West JE et al (2007) Organic field‐effect transistors and unipolar logic gates on charged electrets from spin‐on organosilsesquioxane resins. Adv Funct Mater 17:142–153CrossRef
Zurück zum Zitat Jean-Mistral C, Vu Cong T et al (2012) Advances for dielectric elastomer generators: replacement of high voltage supply by electret. Appl Phys Lett 101:162901CrossRef Jean-Mistral C, Vu Cong T et al (2012) Advances for dielectric elastomer generators: replacement of high voltage supply by electret. Appl Phys Lett 101:162901CrossRef
Zurück zum Zitat Kawai H (1969) The piezoelectricity of poly (vinylidene fluoride). Jpn J Appl Phys 8:975–976 Kawai H (1969) The piezoelectricity of poly (vinylidene fluoride). Jpn J Appl Phys 8:975–976
Zurück zum Zitat Kennedy AP, Babb DA et al (1995) Perfluorocyclobutane aromatic ether polymers. II. Thermal/oxidative stability and decomposition of a thermoset polymer. J Polym Sci A Polym Chem 33(11):1859–1865CrossRef Kennedy AP, Babb DA et al (1995) Perfluorocyclobutane aromatic ether polymers. II. Thermal/oxidative stability and decomposition of a thermoset polymer. J Polym Sci A Polym Chem 33(11):1859–1865CrossRef
Zurück zum Zitat Kirjavainen K (1986) Electromechanical film and procedure for manufacturing the same. European Patent Application 0,182,764 Kirjavainen K (1986) Electromechanical film and procedure for manufacturing the same. European Patent Application 0,182,764
Zurück zum Zitat Lindner M, Bauer-Gogonea S et al (2002) Dielectric barrier microdischarges: mechanism for the charging of cellular piezoelectric polymers. J Appl Phys 91:5283CrossRef Lindner M, Bauer-Gogonea S et al (2002) Dielectric barrier microdischarges: mechanism for the charging of cellular piezoelectric polymers. J Appl Phys 91:5283CrossRef
Zurück zum Zitat Małecki JA (1999) Linear decay of charge in electrets. Phys Rev B 59:9954–9960CrossRef Małecki JA (1999) Linear decay of charge in electrets. Phys Rev B 59:9954–9960CrossRef
Zurück zum Zitat McFee JH, Bergman JR Jr et al (1972) Pyroelectric and nonlinear optical properties of poled polyvinylidene fluoride films. Ferroelectrics 3(1):305–313CrossRef McFee JH, Bergman JR Jr et al (1972) Pyroelectric and nonlinear optical properties of poled polyvinylidene fluoride films. Ferroelectrics 3(1):305–313CrossRef
Zurück zum Zitat Mellinger A, Camacho González F et al (2003) Ultraviolet-induced discharge currents and reduction of the piezoelectric coefficient in cellular polypropylene films. Appl Phys Lett 82:254–256CrossRef Mellinger A, Camacho González F et al (2003) Ultraviolet-induced discharge currents and reduction of the piezoelectric coefficient in cellular polypropylene films. Appl Phys Lett 82:254–256CrossRef
Zurück zum Zitat Mellinger A, Camacho González F et al (2004) Photostimulated discharge in electret polymers: an alternative approach for investigating deep traps. IEEE Trans Dielectr Electr Insul 11:218–226CrossRef Mellinger A, Camacho González F et al (2004) Photostimulated discharge in electret polymers: an alternative approach for investigating deep traps. IEEE Trans Dielectr Electr Insul 11:218–226CrossRef
Zurück zum Zitat Meunier M, Quirke N et al (2001) Molecular modeling of electron traps in polymer insulators: chemical defects and impurities. J Chem Phys 115:276–288CrossRef Meunier M, Quirke N et al (2001) Molecular modeling of electron traps in polymer insulators: chemical defects and impurities. J Chem Phys 115:276–288CrossRef
Zurück zum Zitat Mopsik FI, Broadhurst MG (1975) Molecular dipole electrets. J Appl Phys 46(10):4204CrossRef Mopsik FI, Broadhurst MG (1975) Molecular dipole electrets. J Appl Phys 46(10):4204CrossRef
Zurück zum Zitat Neugschwandtner GS, Schwoediauer R et al (2001) Piezo-and pyroelectricity of a polymer-foam space-charge electret. J Appl Phys 89:4503–4511CrossRef Neugschwandtner GS, Schwoediauer R et al (2001) Piezo-and pyroelectricity of a polymer-foam space-charge electret. J Appl Phys 89:4503–4511CrossRef
Zurück zum Zitat Norwood RA, Findakly T et al (1992) Optical polymers and multifunctional materials. In: Hornak LA (ed) Polymers for lightwave and integrated optics. Marcel Dekker, New York, pp 287–320 Norwood RA, Findakly T et al (1992) Optical polymers and multifunctional materials. In: Hornak LA (ed) Polymers for lightwave and integrated optics. Marcel Dekker, New York, pp 287–320
Zurück zum Zitat Qiu X (2010) Patterned piezo-, pyro-, and ferroelectricity of poled polymer electrets. J Appl Phys 108:011101CrossRef Qiu X (2010) Patterned piezo-, pyro-, and ferroelectricity of poled polymer electrets. J Appl Phys 108:011101CrossRef
Zurück zum Zitat Qiu X, Mellinger A et al (2007) Barrier discharges in cellular polypropylene ferroelectrets: how do they influence the electromechanical properties? J Appl Phys 101:104112CrossRef Qiu X, Mellinger A et al (2007) Barrier discharges in cellular polypropylene ferroelectrets: how do they influence the electromechanical properties? J Appl Phys 101:104112CrossRef
Zurück zum Zitat Qiu X, Holländer L et al (2013) Patterned piezo-, pyro-, and ferroelectricity of poled polymer electrets. J Appl Phys 89:4503 Qiu X, Holländer L et al (2013) Patterned piezo-, pyro-, and ferroelectricity of poled polymer electrets. J Appl Phys 89:4503
Zurück zum Zitat Riande E, Saiz E (1992) Dipole moments and birefringence of polymers. Prentice Hall, Englewood Cliffs Riande E, Saiz E (1992) Dipole moments and birefringence of polymers. Prentice Hall, Englewood Cliffs
Zurück zum Zitat Rollik D, Bauer S et al (1999) Separate contributions to the pyroelectricity in poly (vinylidene fluoride) from the amorphous and crystalline phases, as well as from their interface. J Appl Phys 85:3282–3288CrossRef Rollik D, Bauer S et al (1999) Separate contributions to the pyroelectricity in poly (vinylidene fluoride) from the amorphous and crystalline phases, as well as from their interface. J Appl Phys 85:3282–3288CrossRef
Zurück zum Zitat Savolainen A, Kirjavainen K et al (1989) Electrothermomechanical film: part 1. Design and characteristics. J Macromol Sci A 26(2–3):583–591CrossRef Savolainen A, Kirjavainen K et al (1989) Electrothermomechanical film: part 1. Design and characteristics. J Macromol Sci A 26(2–3):583–591CrossRef
Zurück zum Zitat Sessler GM (ed) (1987) Electrets, 2nd edn. Springer, Berlin Sessler GM (ed) (1987) Electrets, 2nd edn. Springer, Berlin
Zurück zum Zitat Sessler GM, Hillenbrand J (1999) Electromechanical response of cellular electret films. Appl Phys Lett 75:3405–3407CrossRef Sessler GM, Hillenbrand J (1999) Electromechanical response of cellular electret films. Appl Phys Lett 75:3405–3407CrossRef
Zurück zum Zitat Sessler GM, West JE (1962) Self-biased condenser microphone with high capacitance. J Acoust Soc Am 34(11):1787–1788CrossRef Sessler GM, West JE (1962) Self-biased condenser microphone with high capacitance. J Acoust Soc Am 34(11):1787–1788CrossRef
Zurück zum Zitat Sessler GM, Das-Gupta DK et al (1992) Piezo and pyroelectricity in electrets caused by charges, dipoles or both? IEEE Trans Electr Insul 27:872–897CrossRef Sessler GM, Das-Gupta DK et al (1992) Piezo and pyroelectricity in electrets caused by charges, dipoles or both? IEEE Trans Electr Insul 27:872–897CrossRef
Zurück zum Zitat Sessler GM, Yang GM et al (1997) Electret properties of cycloolefin copolymers. In: Annual report, conference on electrical insulation and dielectric phenomena, IEEE service center, Piscataway, pp 467–470 Sessler GM, Yang GM et al (1997) Electret properties of cycloolefin copolymers. In: Annual report, conference on electrical insulation and dielectric phenomena, IEEE service center, Piscataway, pp 467–470
Zurück zum Zitat Singer KD, Sohn JE et al (1986) Second harmonic generation in poled polymer films. Appl Phys Lett 49(5):248–250CrossRef Singer KD, Sohn JE et al (1986) Second harmonic generation in poled polymer films. Appl Phys Lett 49(5):248–250CrossRef
Zurück zum Zitat Stockmayer WH (1967) Dielectric dispersion in solutions of flexible polymers. Pure Appl Chem 15(3–4):539–554 Stockmayer WH (1967) Dielectric dispersion in solutions of flexible polymers. Pure Appl Chem 15(3–4):539–554
Zurück zum Zitat Teyssedre G, Laurent C et al (2001) Deep trapping centers in crosslinked polyethylene investigated by molecular modeling and luminescence techniques. IEEE Trans Dielectr Electr Insul 8:744–752CrossRef Teyssedre G, Laurent C et al (2001) Deep trapping centers in crosslinked polyethylene investigated by molecular modeling and luminescence techniques. IEEE Trans Dielectr Electr Insul 8:744–752CrossRef
Zurück zum Zitat Van Turnhout J (1975) Use of polymers for electrets. J Electrost 1(2):147–163CrossRef Van Turnhout J (1975) Use of polymers for electrets. J Electrost 1(2):147–163CrossRef
Zurück zum Zitat Van Turnhout J (1999) Thermally stimulated discharge of electrets. In: Sessler GM (ed) Electrets, vol 1, 3. Laplacian Press, Morgan Hill, pp 81–215 Van Turnhout J (1999) Thermally stimulated discharge of electrets. In: Sessler GM (ed) Electrets, vol 1, 3. Laplacian Press, Morgan Hill, pp 81–215
Zurück zum Zitat Vasudevan P, Nalwa HS et al (1979) Pyroelectricity in thiourea formaldehyde polymer. J Appl Phys 50:4324CrossRef Vasudevan P, Nalwa HS et al (1979) Pyroelectricity in thiourea formaldehyde polymer. J Appl Phys 50:4324CrossRef
Zurück zum Zitat Wang S, Lin ZH et al (2013) Motion charged battery as sustainable flexible-power-unit. ACS Nano 7(12):11263–11271CrossRef Wang S, Lin ZH et al (2013) Motion charged battery as sustainable flexible-power-unit. ACS Nano 7(12):11263–11271CrossRef
Zurück zum Zitat Wegener M, Bauer S (2005) Microstorms in cellular polymers: a route to soft piezoelectric transducer materials with engineered macroscopic dipoles. ChemPhysChem 6(6):1014–1025CrossRef Wegener M, Bauer S (2005) Microstorms in cellular polymers: a route to soft piezoelectric transducer materials with engineered macroscopic dipoles. ChemPhysChem 6(6):1014–1025CrossRef
Zurück zum Zitat Xia Z, Gerhard-Multhaupt R (1999) High surface-charge stability of porous polytetrafluoroethylene electret films at room and elevated temperatures. J Phys D Appl Phys 32:L83–L85CrossRef Xia Z, Gerhard-Multhaupt R (1999) High surface-charge stability of porous polytetrafluoroethylene electret films at room and elevated temperatures. J Phys D Appl Phys 32:L83–L85CrossRef
Zurück zum Zitat Xia Z, Wedel A et al (2003) Charge Storage and its dynamics in porous polytetrafluorethylene (PTFE) film electrets. IEEE Trans Dielectr Electr Insul 10:102–108CrossRef Xia Z, Wedel A et al (2003) Charge Storage and its dynamics in porous polytetrafluorethylene (PTFE) film electrets. IEEE Trans Dielectr Electr Insul 10:102–108CrossRef
Zurück zum Zitat Xu HS, Cheng ZY et al (2001) Ferroelectric and electromechanical properties of poly(vinylidene-fluoride-trifluoroethylene-chlorotrifluoroethylene) terpolymer. Appl Phys Lett 78:2360–2362CrossRef Xu HS, Cheng ZY et al (2001) Ferroelectric and electromechanical properties of poly(vinylidene-fluoride-trifluoroethylene-chlorotrifluoroethylene) terpolymer. Appl Phys Lett 78:2360–2362CrossRef
Zurück zum Zitat Yue L, Wang X et al (2013) Study on evolution of deep charge traps in polyimide irradiated by low-energy protons using photo-stimulated discharge technique. J Phys D Appl Phys 46:145502CrossRef Yue L, Wang X et al (2013) Study on evolution of deep charge traps in polyimide irradiated by low-energy protons using photo-stimulated discharge technique. J Phys D Appl Phys 46:145502CrossRef
Zurück zum Zitat Zhang X, Hillenbrand J et al (2006) Thermally stable fluorocarbon ferroelectrets with high piezoelectric coefficient. Appl Phys A 84:139–142CrossRef Zhang X, Hillenbrand J et al (2006) Thermally stable fluorocarbon ferroelectrets with high piezoelectric coefficient. Appl Phys A 84:139–142CrossRef
Zurück zum Zitat Zhang X, Hillenbrand J et al (2007) Ferroelectrets with improved thermal stability made from fused fluorocarbon layers. J Appl Phys 101:054114-1 Zhang X, Hillenbrand J et al (2007) Ferroelectrets with improved thermal stability made from fused fluorocarbon layers. J Appl Phys 101:054114-1
Zurück zum Zitat Zhang X, Zhang X et al (2014) Low-cost, large-area, stretchable piezoelectric films based on irradiation-crosslinked poly (propylene). Macromol Mater Eng 299:290–295CrossRef Zhang X, Zhang X et al (2014) Low-cost, large-area, stretchable piezoelectric films based on irradiation-crosslinked poly (propylene). Macromol Mater Eng 299:290–295CrossRef
Metadaten
Titel
Polymer Electrets and Ferroelectrets as EAPs: Fundamentals
verfasst von
Ingrid Graz
Axel Mellinger
Copyright-Jahr
2016
DOI
https://doi.org/10.1007/978-3-319-31530-0_24

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