nach oben

Journal of Polymer Research

Erschienen in:

01.09.2022 | Original Paper

Reinforcing effects of carbon nanotubes on graphene/trans-1,4-polyisoprene/natural rubber composites

verfasst von: Li Chen, Guangshui Yu, Tao Zhuang, Xiujiang Pang

Erschienen in: Journal of Polymer Research | Ausgabe 9/2022

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

To investigate the effects of carbon nanotubes (CNTs) on the performances of graphene (Gr)/trans-1,4-polyisoprene (TPI)/natural rubber (NR) composites, CNTs/Gr/TPI/NR vulcanizates were fabricated via the partial replacement of Gr with CNTs. The results displayed that partially substituting CB with Gr or hybrid in a Gr/CNTs ratio of 2 enabled the TPI/NR composites to embrace simultaneously improved wet-skid resistance, lowered rolling resistance as well as heat buildup (HBU), which is conducive to prepare energy efficient tire rubber. The hybrids of Gr with CNTs raised the crosslinking densities of TPI/NR vulcanizates, and elevated the tensile strength, tear strength, modulus at 300%, hardness, and wear resistance of TPI/NR composites more efficiently than Gr only. Besides, hybrids with higher Gr/CNTs ratio aided in retaining or lifting the resilience of TPI/NR vulcanizate, and raising the thermal conductivities of vulcanizates at 20 and 150℃. So, the partial substitution of CB with Gr/CNTs hybrids in proper ratio is supposed to upgrade the overall properties of TPI/NR vulcanizates.

Vorheriger Artikel Smart electrospun mats of poly(vinylidene fluoride) with thermochromic pigment

Nächster Artikel Effect of molecular structure of PEG/PCL multiblock copolymers on the morphology and interfacial properties of PLA/PCL blends

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Tarachiwin L, Sakdapipanich J, Ute K, Kitayama T, Tanaka Y (2006) Structural characterization of α-terminal group of natural rubber. 2. Decomposition of branch-points by phospholipase and chemical treatments. Biomacromolecules 6(4):1858–1863. https://doi.org/10.1021/bm058004p

Tanaka Y, Mori M, Ute K, Hatada K (1990) Structure and biosynthesis mechanism of rubber from fungi. Rubber Chem Technol 63(1):1–7. https://doi.org/10.5254/1.3538238CrossRef

Dong B, Liu C, Lu YL, Wu YP (2015) Synergistic effects of carbon nanotubes and carbon black on the fracture and fatigue resistance of natural rubber composites. J Appl Polym Sci 132(25):42075. https://doi.org/10.1002/app.42075CrossRef

Wu Y, Yao K, Nie H, He A (2018) Confirmation on the compatibility between cis-1,4-polyisoprene and trans-1,4-polyisoprene. Polymer 153:271–276. https://doi.org/10.1016/j.polymer.2018.08.031CrossRef

Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58. https://doi.org/10.1038/354056a0CrossRef

Geim AK (2009) Graphene: status and prospects. Science 324(5934):1530–1534. https://doi.org/10.1126/science.1158877

Nakaramontri Y, Pichaiyut S, Wisunthorn S, Nakason C (2017) Hybrid carbon nanotubes and conductive carbon black in natural rubber composites to enhance electrical conductivity by reducing gaps separating carbon nanotube encapsulates. Eur Polym J 90:467–484. https://doi.org/10.1016/j.eurpolymj.2017.03.029CrossRef

George N, Venugopal B, John H, Mathiazhagan A, Joseph R (2019) Nanosilica decorated multiwalled carbon nanotubes (CS hybrids) in natural rubber latex. Polymer 161:170–180. https://doi.org/10.1016/j.polymer.2018.12.014CrossRef

Gao H, Liu H, Song C, Hu G (2019) Infusion of graphene in natural rubber matrix to prepare conductive rubber by ultrasound-assisted supercritical CO2 method. Chem Eng J 368:1013–1021. https://doi.org/10.1016/j.cej.2019.03.026CrossRef

10.

Bokobza L, Rahmani M, Belin C, Bruneel JL, EI Bounia NE (2008) Blends of carbon blacks and multiwall carbon nanotubes as reinforcing fillers for hydrocarbon rubbers. J Polym Sci Part B Polym Phys 46(18):1939–1951. https://doi.org/10.1002/polb.21529CrossRef

11.

Yang G, Liao Z, Yang Z, Tang Z, Guo B (2015) Effects of substitution for carbon black with graphene oxide or graphene on the morphology and performance of natural rubber/carbon black composites. J Appl Polym Sci 132(15):41832. https://doi.org/10.1002/app.41832CrossRef

12.

Medupin RO, Abubakre OK, Abdulkareem AS, Muriana RA, Abdulrahman AS (2019) Carbon Nanotube Reinforced Natural Rubber Nanocomposite for Anthropomorphic Prosthetic Foot Purpose. Sci Rep 9:20146. https://doi.org/10.1038/s41598-019-56778-0CrossRefPubMedPubMedCentral

13.

Yang H, Yuan L, Yao X, Zheng Z, Fang D (2020) Monotonic strain sensing behavior of self-assembled carbon nanotubes/graphene silicone rubber composites under cyclic loading. Compos Sci Technol 200:108474. https://doi.org/10.1016/j.compscitech.2020.108474CrossRef

14.

Zhou X, Wang L, Cao X, Yin Q, Weng G (2019) Crack resistance improvement of rubber blend by a filler network of graphene. J Appl Polym Sci 136(17):47278(1–7). https://doi.org/10.1002/app.47278

15.

Dong B, Zhang L, Wu Y (2017) Influences of different dimensional carbon-based nanofillers on fracture and fatigue resistance of natural rubber composites. Polym Test 63:281–288. https://doi.org/10.1016/j.polymertesting.2017.08.035CrossRef

16.

Flory PJ (1950) Statistical mechanics of swelling of network structures. J Chem Phys 18(1):108–111. https://doi.org/10.1063/1.1747424CrossRef

17.

Li FY, Yan N, Zhan YH, Fei GX, Xia HS (2013) Probing the reinforcing mechanism of graphene and graphene oxide in natural rubber. J Appl Polym Sci 129(4):2342–2351. https://doi.org/10.1002/app.38958CrossRef

18.

Zhang J, Xue Z (2011) A comparative study on the properties of Eucommia ulmoides gum and synthetic trans-1,4-polyisoprene. Polym Test 30(7):753–759. https://doi.org/10.1016/j.polymertesting.2011.06.010CrossRef

19.

Ponnamma D, Ramachandran R, Hussain S, Rajaraman R, Amarendra G, Varughese KT, Thomas S (2015) Free-volume correlation with mechanical and dielectric properties of natural rubber/multi walled carbon nanotubes composites. Compos Part A Appl Sci Manuf 77:164–171. https://doi.org/10.1016/j.compositesa.2015.06.023CrossRef

20.

Yang SY, Lin WN, Huang YL, Tien HW, Wang JY, Ma CCM, Li SM, Wang YS (2011) Synergetic effects of graphene platelets and carbon nanotubes on the mechanical and thermal properties of epoxy composites. Carbon 49(3):793–803. https://doi.org/10.1016/j.carbon.2010.10.014CrossRef

21.

Yue L, Pircheraghi G, Monemian SA, Manas-Zloczower I (2014) Epoxy composites with carbon nanotubes and graphene nanoplatelets - Dispersion and synergy effects. Carbon 78:268–278. https://doi.org/10.1016/j.carbon.2014.07.003CrossRef

22.

Guo H, Jerrams S, Xu Z, Zhou Y, Jiang L, Zhang L, Liu L, Wen S (2020) Enhanced fatigue and durability of carbon black/natural rubber composites reinforced with graphene oxide and carbon nanotubes. Eng Fract Mech 223:106764. https://doi.org/10.1016/j.engfracmech.2019.106764CrossRef

23.

Kang I, Heung YY, Kim JH, Lee JW, Gollapudi R, Subramaniam S, Narasimhadevara S, Hurd D, Kirikera GR, Shanov V, Schulz MJ, Shi D, Boerio J, Mall S, Ruggles-Wren M (2006) Introduction to carbon nanotube and nanofiber smart materials. Compos Part B-Eng 37(6):382–394. https://doi.org/10.1016/j.compositesb.2006.02.011CrossRef

24.

Lu Y, Yang J, Yin D, Tan M, Wang J (2008) Synthesis and aging properties of reactive antioxidant NAPM in natural rubber vulcanizates. J Appl Polym Sci 108(1):576–582. https://doi.org/10.1002/app.27042CrossRef

25.

Bhattacharyya S, Sinturel C, Bahloul O, Saboungi ML, Thomas S, Salvetat JP (2008) Improving reinforcement of natural rubber by networking of activated carbon nanotubes. Carbon 46(7):1037–1045. https://doi.org/10.1016/j.carbon.2008.03.011CrossRef

26.

Bhattacharya M, Bhowmick AK (2010) Synergy in carbon black-filled natural rubber nanocomposites. Part I: Mechanical, dynamic mechanical properties, and morphology. J Mater Sci 45:6126–6138. https://doi.org/10.1007/s10853-010-4699-6CrossRef

27.

Wei X, Luo T (2019) Chain length effect on thermal transport in amorphous polymers and a structure−thermal conductivity relation. Phys Chem Chem Phys 21(28):15523–15530. https://doi.org/10.1039/C9CP02397FCrossRefPubMed

28.

Xiao Y, Wang W, Lin T, Chen X, Zhang Y, Yang J, Wang Y, Zhou Z (2016) Largely enhanced thermal conductivity and high dielectric constant of poly (vinylidene fluoride)/boron nitride composites achieved by adding a few carbon nanotubes. J Phys Chem C 120(12):6344–6355. https://doi.org/10.1021/acs.jpcc.5b12651CrossRef

29.

Seol JH, Jo I, Moore AL, Lindsay L, Aitken ZH, Pettes MT, Li X, Yao Z, Huang R, Broido D, Mingo N, Ruoff RS, Shi L (2010) Two-dimensional phonon transport in supported graphene. Science 328(5975):213–216. https://doi.org/10.1126/science.1184014CrossRefPubMed

Titel: Reinforcing effects of carbon nanotubes on graphene/trans-1,4-polyisoprene/natural rubber composites
verfasst von: Li Chen
Guangshui Yu
Tao Zhuang
Xiujiang Pang
Publikationsdatum: 01.09.2022
Verlag: Springer Netherlands
Erschienen in: Journal of Polymer Research / Ausgabe 9/2022
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI: https://doi.org/10.1007/s10965-022-03231-y

Premium Partner

Marktübersichten

Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.

Zur Marktübersicht

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Springer Professional "Technik"

Weitere Artikel der Ausgabe 9/2022

Photo-responsive and recyclable graphene/thermosetting polyurethane shape memory composites for self-powered mechanosensor

Gamma irradiation synthesis of pectin- based biohydrogels for removal of lead cations from simulated solutions

UV protection by the inclusion of the methoxybenzophenone moieties into the backbone chain of the polyurethane structure

Interfacial aggregation behavior of triblock terpolymers

Free-radical copolymerization of biological medium-chain-length poly-3-hydroxyalkanoate with poly-methyl acrylate under ultrasonication

Synthesis and properties of polyimides from a diamine containing side diphenylphosphine oxide and trifluoromethyl groups

Premium Partner

Marktübersichten