Skip to main content
Erschienen in: Journal of Polymer Research 4/2016

01.04.2016 | Original Paper

Reversible crosslinked low density polyethylenes: structure and thermal properties

verfasst von: H. Saci, S. Bouhelal, B. Bouzarafa, D. López, M. Fernández-García

Erschienen in: Journal of Polymer Research | Ausgabe 4/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

In the present study, low density polyethylene (LDPE) has been crosslinked at 170 °C with three different systems by a) using peroxide, b) peroxide and accelerator and c), peroxide, accelerator and sulfur. The effect of chemical crosslinking on LDPE structure has been investigated using torque measurements, Fourier transform infrared spectroscopy (FTIR), wide angle X-ray diffraction (WAXS), thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). Therefore, effects of each crosslinking system on the structural and thermal properties of the material in terms of crystallinity, thermal transitions and stability have been discussed. The reversible crosslinking of LDPE allow the recyclability of polyolefins, increasing the thermal properties.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Literatur
5.
Zurück zum Zitat Jana RN, Nando GB (2003) Thermogravimetric analysis of blends of low-density polyethylene and poly(dimethyl siloxane) rubber: the effects of compatibilizers. J Appl Polym Sci 90(3):635–642. doi:10.1002/app.12599 CrossRef Jana RN, Nando GB (2003) Thermogravimetric analysis of blends of low-density polyethylene and poly(dimethyl siloxane) rubber: the effects of compatibilizers. J Appl Polym Sci 90(3):635–642. doi:10.​1002/​app.​12599 CrossRef
7.
Zurück zum Zitat Basfar AA, Idriss Ali KM, Mofti SM (2003) UV stability and radiation-crosslinking of linear low density polyethylene and low density polyethylene for greenhouse applications. Polym Degrad Stab 82(2):229–234. doi:10.1016/S0141-3910(03)00216-7 CrossRef Basfar AA, Idriss Ali KM, Mofti SM (2003) UV stability and radiation-crosslinking of linear low density polyethylene and low density polyethylene for greenhouse applications. Polym Degrad Stab 82(2):229–234. doi:10.​1016/​S0141-3910(03)00216-7 CrossRef
14.
Zurück zum Zitat Anbarasan R, Babot O, Maillard B (2004) Crosslinking of high-density polyethylene in the presence of organic peroxides. J Appl Polym Sci 93(1):75–81. doi:10.1002/app.20390 CrossRef Anbarasan R, Babot O, Maillard B (2004) Crosslinking of high-density polyethylene in the presence of organic peroxides. J Appl Polym Sci 93(1):75–81. doi:10.​1002/​app.​20390 CrossRef
16.
Zurück zum Zitat Suyama S, Ishigaki H, Watanabe Y, Nakamura T (1995) Crosslinking of polyethylene by dicumyl peroxide in the presence of 2,4-diphenyl-4-methyl-1-pentene. Polym J 27(4):371–375. doi:10.1295/polymj.27.371 CrossRef Suyama S, Ishigaki H, Watanabe Y, Nakamura T (1995) Crosslinking of polyethylene by dicumyl peroxide in the presence of 2,4-diphenyl-4-methyl-1-pentene. Polym J 27(4):371–375. doi:10.​1295/​polymj.​27.​371 CrossRef
19.
Zurück zum Zitat Salehi SMA, Mirjalili G, Amrollahi J (2004) Effects of high-energy electron beam on low-density polyethylene materials containing EVA. J Appl Polym Sci 92(2):1049–1052. doi:10.1002/app.20079 CrossRef Salehi SMA, Mirjalili G, Amrollahi J (2004) Effects of high-energy electron beam on low-density polyethylene materials containing EVA. J Appl Polym Sci 92(2):1049–1052. doi:10.​1002/​app.​20079 CrossRef
21.
Zurück zum Zitat Kuan H-C, Kuan J-F, Ma C-CM, Huang J-M (2005) Thermal and mechanical properties of silane-grafted water crosslinked polyethylene. J Appl Polym Sci 96(6):2383–2391. doi:10.1002/app.21694 CrossRef Kuan H-C, Kuan J-F, Ma C-CM, Huang J-M (2005) Thermal and mechanical properties of silane-grafted water crosslinked polyethylene. J Appl Polym Sci 96(6):2383–2391. doi:10.​1002/​app.​21694 CrossRef
22.
Zurück zum Zitat Sirisinha K, Chuaythong P (2014) Reprocessable silane-crosslinked polyethylene: property and utilization as toughness enhancer for high-density polyethylene. J Mater Sci 49(14):5182–5189. doi:10.1007/s10853-014-8226-z CrossRef Sirisinha K, Chuaythong P (2014) Reprocessable silane-crosslinked polyethylene: property and utilization as toughness enhancer for high-density polyethylene. J Mater Sci 49(14):5182–5189. doi:10.​1007/​s10853-014-8226-z CrossRef
24.
Zurück zum Zitat Hlangothi SP, Krupa I, Djoković V, Luyt AS (2003) Thermal and mechanical properties of cross-linked and uncross-linked linear low-density polyethylene–wax blends. Polym Degrad Stab 79(1):53–59. doi:10.1016/S0141-3910(02)00238-0 CrossRef Hlangothi SP, Krupa I, Djoković V, Luyt AS (2003) Thermal and mechanical properties of cross-linked and uncross-linked linear low-density polyethylene–wax blends. Polym Degrad Stab 79(1):53–59. doi:10.​1016/​S0141-3910(02)00238-0 CrossRef
30.
Zurück zum Zitat Bouhelal S, Lewis KW (2009) Method to make reversibly cross-linked isotactic polypropylene. US7517942B1. US7517942B1 Bouhelal S, Lewis KW (2009) Method to make reversibly cross-linked isotactic polypropylene. US7517942B1. US7517942B1
31.
Zurück zum Zitat Khellaf S, Khoffi F, Tabet H, Lallam A, Bouhelal S, Cagiao ME, Benachour D, BaltáCalleja FJ (2012) Study of iPP crosslinking by means of dynamic and steady rheology measurements. J Appl Polym Sci 124(4):3184–3191. doi:10.1002/app.34996 CrossRef Khellaf S, Khoffi F, Tabet H, Lallam A, Bouhelal S, Cagiao ME, Benachour D, BaltáCalleja FJ (2012) Study of iPP crosslinking by means of dynamic and steady rheology measurements. J Appl Polym Sci 124(4):3184–3191. doi:10.​1002/​app.​34996 CrossRef
32.
Zurück zum Zitat Bouhelal S, Cagiao ME, Khellaf S, Benachour D, Baltá Calleja FJ (2008) Structure and properties of new reversibly crosslinked iPP/LDPE blends. J Appl Polym Sci 109(2):795–804. doi:10.1002/app.28194 CrossRef Bouhelal S, Cagiao ME, Khellaf S, Benachour D, Baltá Calleja FJ (2008) Structure and properties of new reversibly crosslinked iPP/LDPE blends. J Appl Polym Sci 109(2):795–804. doi:10.​1002/​app.​28194 CrossRef
33.
Zurück zum Zitat Bouhelal S, Cagiao ME, Benachour D, Calleja FJB (2007) Structure modification of isotactic polypropylene through chemical crosslinking: toughening mechanism. J Appl Polym Sci 103(5):2968–2976. doi:10.1002/app.25406 CrossRef Bouhelal S, Cagiao ME, Benachour D, Calleja FJB (2007) Structure modification of isotactic polypropylene through chemical crosslinking: toughening mechanism. J Appl Polym Sci 103(5):2968–2976. doi:10.​1002/​app.​25406 CrossRef
34.
Zurück zum Zitat ASTM D2765-01 (2001) Standard test methods for determination of gel content and swell ratio of crosslinked ethylene plastics. ASTM International, West Conshohocken, http://www.astm.org ASTM D2765-01 (2001) Standard test methods for determination of gel content and swell ratio of crosslinked ethylene plastics. ASTM International, West Conshohocken, http://​www.​astm.​org
35.
Zurück zum Zitat The infrared spectra atlas of monomers and polymers (1983) Saddler Research Laboratories. Lewiston, NY The infrared spectra atlas of monomers and polymers (1983) Saddler Research Laboratories. Lewiston, NY
37.
Zurück zum Zitat Mishra JK, Raychowdhury S, Das CK (2000) Effect of interchain crosslinking on the shrinkability of the blends consisting of grafted low-density polyethylene and carboxylated nitrile rubber. Mater Lett 46(4):212–218. doi:10.1016/S0167-577X(00)00172-5 CrossRef Mishra JK, Raychowdhury S, Das CK (2000) Effect of interchain crosslinking on the shrinkability of the blends consisting of grafted low-density polyethylene and carboxylated nitrile rubber. Mater Lett 46(4):212–218. doi:10.​1016/​S0167-577X(00)00172-5 CrossRef
39.
Zurück zum Zitat Patterson AL (1939) The scherrer formula for X-Ray Particle Size determination. Phys Rev 56(10):978–982CrossRef Patterson AL (1939) The scherrer formula for X-Ray Particle Size determination. Phys Rev 56(10):978–982CrossRef
Metadaten
Titel
Reversible crosslinked low density polyethylenes: structure and thermal properties
verfasst von
H. Saci
S. Bouhelal
B. Bouzarafa
D. López
M. Fernández-García
Publikationsdatum
01.04.2016
Verlag
Springer Netherlands
Erschienen in
Journal of Polymer Research / Ausgabe 4/2016
Print ISSN: 1022-9760
Elektronische ISSN: 1572-8935
DOI
https://doi.org/10.1007/s10965-016-0965-x

Weitere Artikel der Ausgabe 4/2016

Journal of Polymer Research 4/2016 Zur Ausgabe

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen.