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1990 | Buch

Reviews of Environmental Contamination and Toxicology

Continuation of Residue Reviews

herausgegeben von: George W. Ware, Herbert N. Niggs, Arthur Bevenue

Verlag: Springer New York

Buchreihe : Reviews of Environmental Contamination and Toxicology

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Über dieses Buch

International concern in scientific, industrial, and governmental communities over traces of xenobiotics in foods and in both abiotic and biotic environments has justified the present triumvirate of specialized publications in this field: com­ prehensive reviews, rapidly published research papers and progress reports, and archival documentations. These three international publications are integrated and scheduled to provide the coherency essential for nonduplicative and current progress in a field as dynamic and complex as environmental contamination and toxicology. This series is reserved exclusively for the diversified literature on "toxic" chemicals in our food, our feeds, our homes, recreational and working surroundings, our domestic animals, our wildlife and ourselves. Tremendous efforts worldwide have been mobilized to evaluate the nature, presence, magni­ tude, fate, and toxicology of the chemicals loosed upon the earth. Among the sequelae of this broad new emphasis is an undeniable need for an articulated set of authoritative publications, where one can find the latest important world liter­ ature produced by these emerging areas of science together with documentation of pertinent ancillary legislation. Research directors and legislative or administrative advisers do not have the time to scan the escalating number of technical publications that may contain articles important to current responsibility. Rather, these individuals need the background provided by detailed reviews and the assurance that the latest infor­ mation is made available to them, all with minimal literature searching.

Inhaltsverzeichnis

Frontmatter
Solubilities of Pesticide Chemicals in Water Part I: Environmental Physical Chemistry
Abstract
In 1968 Gunther, Westlake, and Jaglan compiled and published data on the water solubility of 738 pesticide chemicals. That pioneering review noted that there were “glaring inconsistencies and lamentable gaps in the literature commonly available to research workers and others interested in even approximate solubility data.” For 63% of the chemicals either no data were available or the information was of a purely qualitative nature, for example, a statement to the effect that the chemical was “relatively insoluble” (Gunther et al. 1968). In the two decades since that review there has been considerable improvement in the quantity and quality of reported data and a deeper understanding has emerged of the relationships between solubility and other physical-chemical properties, notably octanol-water partition coefficient K ow (Chiou et al. 1977, 1982, Mackay et al. 1980, Miller et al. 1985) and other environmentally relevant partition coefficients such as those between air and water (Mackay and Shiu 1981), and water and organic carbon (Karickhoff et al. 1979) or lipid phases (Kenaga 1980a,b, Briggs 1981, Mackay 1982, Chiou 1985, Seiber 1987). Further, the role that physical-chemical properties play in determining pesticide fate in the environment is now much clearer (Biggar and Seiber 1987). Methods for assessing or predicting chemical behavior have been improved by exploiting the greater availability of computers and computer models. Such assessments routinely require information on water solubility, not only for agricultural chemicals but also for chemicals in general commercial use.
W. Y. Shiu, K. C. Ma, D. Mackay, J. N. Seiber, R. D. Wauchope
Solubilities of Pesticide Chemicals in Water Part II: Data Compilation
Abstract
As discussed in Part I of this two-part series (Shiu et al. 1990) Gunther, Westlake, and Jaglan compiled and published data on the water solubility of 738 pesticide chemicals in 1968. They noted “glaring inconsistencies and lamentable gaps in the literature commonly available to research workers and others interested in even approximate solubility data.” For many chemicals either no data were available or the information was only qualitative. In Part I the environmental physical chemistry of solubility was reviewed. In this second part we discuss data sources and methods of solubility measurement and present a compilation of solubility data for 884 pesticide chemicals.
W. Y. Shiu, K. C. Ma, D. Mackay, J. N. Seiber, R. D. Wauchope
Backmatter
Metadaten
Titel
Reviews of Environmental Contamination and Toxicology
herausgegeben von
George W. Ware
Herbert N. Niggs
Arthur Bevenue
Copyright-Jahr
1990
Verlag
Springer New York
Electronic ISBN
978-1-4612-3434-0
Print ISBN
978-1-4612-8010-1
DOI
https://doi.org/10.1007/978-1-4612-3434-0