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2023 | Buch

Self-Adjoint Extension Schemes and Modern Applications to Quantum Hamiltonians

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This book introduces and discusses the self-adjoint extension problem for symmetric operators on Hilbert space. It presents the classical von Neumann and Krein–Vishik–Birman extension schemes both in their modern form and from a historical perspective, and provides a detailed analysis of a range of applications beyond the standard pedagogical examples (the latter are indexed in a final appendix for the reader’s convenience).

Self-adjointness of operators on Hilbert space representing quantum observables, in particular quantum Hamiltonians, is required to ensure real-valued energy levels, unitary evolution and, more generally, a self-consistent theory. Physical heuristics often produce candidate Hamiltonians that are only symmetric: their extension to suitably larger domains of self-adjointness, when possible, amounts to declaring additional physical states the operator must act on in order to have a consistent physics, and distinct self-adjoint extensions describe different physics. Realising observables self-adjointly is the first fundamental problem of quantum-mechanical modelling.

The discussed applications concern models of topical relevance in modern mathematical physics currently receiving new or renewed interest, in particular from the point of view of classifying self-adjoint realisations of certain Hamiltonians and studying their spectral and scattering properties. The analysis also addresses intermediate technical questions such as characterising the corresponding operator closures and adjoints. Applications include hydrogenoid Hamiltonians, Dirac–Coulomb Hamiltonians, models of geometric quantum confinement and transmission on degenerate Riemannian manifolds of Grushin type, and models of few-body quantum particles with zero-range interaction.

Graduate students and non-expert readers will benefit from a preliminary mathematical chapter collecting all the necessary pre-requisites on symmetric and self-adjoint operators on Hilbert space (including the spectral theorem), and from a further appendix presenting the emergence from physical principles of the requirement of self-adjointness for observables in quantum mechanics.

Inhaltsverzeichnis

Frontmatter

Theory

Frontmatter
Chapter 1. Generalities on Symmetric and Self-Adjoint Operators on Hilbert Space
Abstract
This chapter of preliminaries collects all the necessary theoretical pre-requisites from Hilbert space operator theory, and self-adjoint operator theory in particular, for systematic reference throughout the monograph. At the price of not presenting proofs, which can be easily tracked down across standard textbooks, we outline all such pre-requisites in logical order (the omitted proofs would indeed unfold each one relying on the previous ones) and in a straightforwardly searchable form, across all the basic generalities on symmetric and self-adjoint operators on Hilbert space (including the spectral theorem).
Matteo Gallone, Alessandro Michelangeli
Chapter 2. Classical Self-Adjoint Extension Schemes
Abstract
This chapter presents the two classical self-adjoint extension theories a la von Neumann and a la Kreı̆n, Višik, and Birman. We start with the discussion of the Friedrichs extension, which is in fact an independent quadratic form construction, and after that we present the theory of the Cayley transform for symmetric operators, on which von Neumann’s extension scheme was originally based and is indeed presented here. We also supplement this with the reinterpretation made by N. Dunford and J. T. Schwartz, where the emphasis is rather put on the abstract boundary value problem. Next, we discuss the Kreı̆n transform of positive operators and its role in Kreı̆n’s theory of self-adjoint extensions, that parallels the role of the Cayley transform in von Neumann’s extension theory. We then present in its entirety Kreı̆n’s extension theory of symmetric semi-bounded operators, following the original work by Kreı̆n, and also discussing the Ando-Nishio variant for the characterisation of the Kreı̆n-von Neumann extension. After this, the Višik-Birman parametrisation of self-adjoint extensions is analysed in its original form and in its more typical modern re-parametrisation, and all its fundamental ancillary results are discussed on invertibility of the extensions, their semi-boundedness, their spectrum, and Kreı̆n formula type resolvent identities. A detour on that sub-class of extensions that retain the same Friedrichs lower bound concludes such a review.
Matteo Gallone, Alessandro Michelangeli

Applications

Frontmatter
Chapter 3. Hydrogenoid Spectra with Central Perturbations
Abstract
In this first chapter of ‘modern applications’ we analyse the self-adjoint realisations of hydrogenoid Hamiltonians with central, point-like perturbation and their spectral properties. On the one hand this is a classical subject, in that the self-adjoint extension problem was completed long ago by means of von Neumann’s extension scheme, but on the other hand it displays a degree of present-day topicality as a playground for the application of the Kreı̆n-Višik-Birman scheme. This point of view has been recently studied in Gallone and Michelangeli (Rep Math Phys 84:215–243, 2019), which is the reference the whole chapter is modelled on. Re-doing the analysis within this scheme, indeed, shows in which respects the latter approach is cleaner and provides more directly and naturally the characterisation of the models and their spectral content, and moreover the discussion of this Chapter allows for a useful comparison between the von Neumann and the Kreı̆n-Višik-Birman approach.
Matteo Gallone, Alessandro Michelangeli
Chapter 4. Dirac-Coulomb Hamiltonians for Heavy Nuclei
Abstract
The Dirac electron moving in the Coulomb field bound to a nucleus was among the first non-trivial and central models in the early days of quantum mechanics. The striking effectiveness of the Sommerfeld fine structure formula in providing the energy levels of the system gave this model the highest profile. Whereas the essential self-adjointness of the minimal operator could be established perturbatively for sufficiently small magnitudes of the Coulomb coupling, it had been known for decades, in explicit form at least since the 1970s, that for sufficiently large couplings a multitude of distinct self-adjoint realisations is available. Almost the entirety of the interest was then focussed on the existence of a distinguished Dirac-Coulomb self-adjoint Hamiltonian, characterised by being the only one with finite expectations, separately, of the kinetic part and of the potential part. Only in very recent times were the other self-adjoint realisations identified, first within the von Neumann extension scheme, and subsequently within the Kreı̆n-Višik-Birman scheme. This Chapter, modelled on the recent works (Gallone and Michelangeli, Anal Math Phys 9:585–616, 2019; J Math Phys 59:062108, 19, 2018) presents this second approach and develops the spectral theory for each of the self-adjoint extensions.
Matteo Gallone, Alessandro Michelangeli
Chapter 5. Quantum Particle on Grushin Structures

The study of a quantum particle on degenerate Riemannian manifolds, and the problem of the purely geometric confinement away from the singularity locus of the metric, as opposite to the dynamical transmission across the singularity, has recently attracted a considerable amount of attention in relation to Grushin structures and to the induced confining effective potentials on cylinder, cone, and plane, as well as, more generally, on two-step two-dimensional almost-Riemannian structures, or also generalisations to almost-Riemannian structures in any dimension and of any step, and even to sub-Riemannian geometries, provided that certain geometrical assumptions on the singular set are taken. On a related note, a satisfactory interpretation of the heat-confinement in the Grushin cylinder is known in terms of Brownian motions. Underlying such analyses there is a natural problem of control of essential self-adjointness or lack thereof, whence also a natural problem of identification, classification, and analysis of self-adjoint extensions, for the minimally defined Laplace-Beltrami operator on manifold. Such questions are discussed in this Chapter for the planar, and, more extensively, the cylindric realisation of a Grushin-type structure, where both the self-adjointness characterisation (Sects. 5.4–5.12) and the spectral analysis (Sects. 5.13 and 5.14) are carried on by means of the Kreı̆n-Višik-Birman extension scheme. The whole chapter is modelled on the recent works (Gallone et al., Z. Angew. Math. Phys. 70, Art. 158, 17, 2019; E. Pozzoli, Quantum confinement in α-Grushin planes, in Mathematical Challenges of Zero-Range Physics, ed. by A. Michelangeli. Springer INdAM Series (Springer, Berlin, 2021), pp. 229–237;M. Gallone, A. Michelangeli, E. Pozzoli, Quantum geometric confinement and dynamical transmission in Grushin cylinder (2020). arXiv:2003.07128; M. Gallone, A. Michelangeli, J. Phys. A Math. Theor. 2021; M. Gallone, A. Michelangeli, E. Pozzoli, Heat equation with inverse-square potential of bridging type across two half-lines (2021). arXiv:2112.01255).

Matteo Gallone, Alessandro Michelangeli
Chapter 6. Models of Zero-Range Interaction for the Bosonic Trimer at Unitarity

Models of particles coupled by a non-trivial interaction whose spatial range is zero represent one of the deepest modern applications in quantum mechanics of self-adjoint extension theory. This is also a field that combines a long history of well-established results with really hard problems that are still open. This is even more so in view of the rather intriguing circumstance that recent experimental advances have made the subject highly topical in theoretical and experimental cold atom physics, in parallel with the purely mathematical investigation, a scenario where formal physical heuristics produce beautiful results and conjectures that still need be demonstrated in full mathematical rigour. Self-adjoint extension theory kicks in to identify physically meaningful self-adjoint realisations of formal Hamiltonians, and then to study their spectral properties. Mathematically this is often particularly challenging because in this context one is not dealing with ordinary Schrödinger operators with usual structure of kinetic plus potential part: indeed, the ‘interaction potential’ is rather to be thought of as some sort of delta-like profile (with the important warning, as specified later, that in two and three dimensions these are not and cannot be Dirac deltas), thus a large amount of techniques that are specific from Schrödinger operator theory are not directly applicable. While giving multiple references to a growing and active literature, this chapter is focussed on a specific class of zero-range models, in fact on one of the most relevant and instructive ‘building blocks’, namely a system of three identical bosons with non-trivial contact interaction, keeping the recent work (A. Michelangeli, Rev. Math. Phys. 33, 2150010, 101, 2021) as main reference. There is also a pedagogical motivation for choosing such bosonic playground: as these models are naturally unbounded from below, it turns out that a clever combination of both von Neumann and Kreı̆n-Višik-Birman extension schemes is required.

Matteo Gallone, Alessandro Michelangeli
Backmatter
Metadaten
Titel
Self-Adjoint Extension Schemes and Modern Applications to Quantum Hamiltonians
verfasst von
Matteo Gallone
Alessandro Michelangeli
Copyright-Jahr
2023
Electronic ISBN
978-3-031-10885-3
Print ISBN
978-3-031-10884-6
DOI
https://doi.org/10.1007/978-3-031-10885-3

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