Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Erschienen in:
Simple Alkoxide Based Precursor Systems Kapitel lesen Erstes Kapitel lesen

2013 | OriginalPaper | Buchkapitel

4. Single Source Precursor Approach

Hydrolysis Mechanisms in Organic Media

verfasst von : Vadim G. Kessler

Erschienen in: Chemical Solution Deposition of Functional Oxide Thin Films

Verlag: Springer Vienna

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

The chapter provides detailed analysis of reaction mechanisms for hydrolytic processes, leading to formation of metal oxides in organic media, and explains the role of such factors as hydrolysis ratio, complexation ratio, the nature of heteroligands, and the nature of constituents in chemically complex systems. It presents the MTSAL concept, describing the principles of micellar self-assembly for metal oxides in organic solvents and introduces the principles for construction and application of specially designed single source precursors (SSP). Advantages and disadvantages of SSP approach for the preparation of dense and porous films for different applications are described. The principles for the structure design and synthetic approaches to this class of compounds are outlined and illustrated for a large number of heterometallic and heteroleptic alkoxide complexes.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Vorheriges Kapitel Mixed Metallo-organic Precursor Systems
Nächstes Kapitel Aqueous Precursor Systems
Literatur
1.
Mazdiyasni KS, Dolloff RT, Smith JS II (1969) Preparation of high-purity submicron barium titanate powders. J Am Ceram Soc 52:523CrossRef
2.
Graham HC, Tallan NM, Mazdiyasni KS (1971) Electrical properties of high-purity polycrystalline barium titanate. J Am Ceram Soc 54:548CrossRef
3.
Schulz S (2002) In: Mingos DMP (ed) Structure and bonding, vol 103. Springer, Berlin, p 118
4.
Turova NY, Turevskaya EP, Kessler VG, Yanovskaya MI (1994) Oxoalkoxides – true precursors of complex oxides. J Sol-Gel Sci Technol 2:17CrossRef
5.
Kessler VG, Hubert-Pfalzgraf LG, Daniele S, Gleizes A (1994) Single-source precursors for BaTiO3: synthesis and characterization of β-diketonato alkoxides and molecular structure of Ba2Ti2(thd)4(μ3-OEt)2(μ-OEt)4(OEt)2(EtOH)2. Chem Mater 6:2336CrossRef
6.
Ribot F, Toledano P, Sanchez C (1991) Hydrolysis-condensation process of beta-diketonates-modified cerium(IV) isopropoxide. Chem Mater 3:759–765CrossRef
7.
Livage J, Henry M, Sanchez C (1988) Sol-gel chemistry of transition metal oxides. Progr Solid State Chem 18:259–341CrossRef
8.
Sanchez C, Livage J (1990) Sol-gel chemistry from metal alkoxide precursors. New J Chem 14:513
9.
Livage J, Sanchez C (1992) Sol-gel chemistry. J Non-Cryst Solids 145:11CrossRef
10.
Sanchez C, Livage J, Henry M, Babonneau F (1988) Chemical modification of alkoxide precursors. J Non-Cryst Solids 100:65–76CrossRef
11.
Babonneau F, Doeff S, Leaustic A, Sanchez C, Cartier C, Verdaguer M (1988) XANES and EXAFS study of titanium alkoxides. Inorg Chem 27:3166–3172CrossRef
12.
Fric H, Puchberger M, Schubert U (2006) Coordination of mono- and diamines to titanium and zirconium alkoxides. J Sol-Gel Sci Technol 40:155–162CrossRef
13.
Senouci A, Yaakouyb M, Huguenard C, Henry M (2004) Molecular templating using titanium(IV) (oxo)alkoxides and titanium(IV) (oxo)aryloxides. J Mater Chem 14:3215–3230CrossRef
14.
Spijksma GI, Seisenbaeva GA, Kessler VG, Blank DHA, Bouwmeester HJM, Fischer A (2009) The molecular composition of non-modified and acac-modified propoxide and butoxide precursors of zirconium and hafnium dioxides. J Sol-Gel Sci Technol 51:10–22CrossRef
15.
Evans WJ, Ansari MA, Ziller JW (1998) Isolation and structural characterization of the polymetallic zirconium alkoxide complexes, Zr3O(OCH2CMe3)9CI, Zr3O(OCMe3)9(OH), and Na4Zr6O2(OEt)24. Polyhedron 17:869–877CrossRef
16.
Turova NY, Turevskaya EP, Kessler VG, Yanovskaya AI (2002) The chemistry of metal alkoxides. Kluwer AP, Boston
17.
Veith M, Mathur S, Huch V, Decker T (1998) Tuning metal stoichiometry in heterometal alkoxides: first structurally characterised molecular precursor to BaZrO3. Eur J Inorg Chem 1998:1327CrossRef
18.
Seisenbaeva GA, Gohil S, Kessler VG (2004) Influence of heteroligands on the composition, structure and properties of homo- and heterometallic zirconium alkoxides. Decisive role of thermodynamic factors in their self-assembly. J Mater Chem 14:3177CrossRef
19.
Yanovsky AI, Yanovskaya MI, Limar VK, Kessler VG, Turova NY, Struchkov YT (1991) Synthesis and crystal structure of the double barium-titanium isopropoxide [Ba4Ti4(μ4-O)4(μ3-OR)8(OR)6(ROH)4][Ba4Ti4(μ4-O)4(μ3-OR)2(μ-OR)9(OR)5(ROH)3]. J Chem Soc Chem Commun 1991(22):1605CrossRef
20.
Pope MT (1983) Heteropoly and isopoly oxometalates, vol 8, Inorganic chemistry concepts. Springer, HamburgCrossRef
21.
Seisenbaeva GA, Baranov AI, Shcheglov PA, Kessler VG (2004) Isolation, X-ray single crystal and theoretical study of quinquevalent metal oxoisopropoxides, Nb6O8(iPrO)14(iPrOH)2 and Re4O6(OiPr)10. Inorg Chim Acta 357:468CrossRef
22.
Gigant K, Rammal A, Henry M (2001) Synthesis and molecular structures of some new titanium(IV) aryloxides. J Am Chem Soc 123:11632CrossRef
23.
Seisenbaeva GA, Suslova EV, Kritikos M, Kessler VG, Rapenne L, Andrieux M, Chassagneux F, Parola S (2004) Purposeful construction versus self-assembly in approaches to single source precursors of spinel materials. Synthesis, structure and stability studies of MIIAl2(acac)3(OiPr)4(OAc), MII = Mn, Co, Zn – a new class of heterometallic heteroleptic alkoxide complexes. J Mater Chem 14:3150CrossRef
24.
Wengrovius JH, Garbauskas MF, Williams EA, Going RC, Donahue PE, Smith JF (1986) Aluminum alkoxide chemistry revisited: synthesis, structures, and characterization of several aluminum alkoxide and siloxide complexes. J Am Chem Soc 108:982CrossRef
25.
Spijksma GI, Bouwmeester HJM, Blank DHA, Fischer A, Henry M, Kessler VG (2006) Chemistry of 2,2,6,6,-tetramethyl-3,5-heptanedione (Hthd) modification of zirconium and hafnium propoxide precursors. Inorg Chem 45:4938CrossRef
26.
Donat M, Seisenbaeva GA, Kessler VG (2008) Synthesis of highly sterically hindered niobium and tantalum alkoxides and their microhydrolysis in strongly basic medium. J Sol-Gel Sci Technol 48:61CrossRef
27.
Kessler VG, Spijksma GI, Seisenbaeva GA, Håkansson S, Blank DHA, Bouwmeester HJM (2006) New insight in the role of modifying ligands in the sol-gel processing of metal alkoxide precursor: a possibility to approach new classes of materials. J Sol-Gel Sci Technol 40:163CrossRef
28.
Fortner KC, Bigi JP, Brown SN (2005) Six-coordinate titanium complexes of a tripodal aminetris(phenoxide) ligand: synthesis, structure, and dynamics. Inorg Chem 44:2803CrossRef
29.
Boulmaâz S, Papiernik R, Hubert-Pfalzgraf LG, Septe B, Vaissermann J (1997) Chemical routes to oxides: alkoxide vs. alkoxide–acetate routes: synthesis, characterization, reactivity and polycondensation of MNb2(OAc)2(OPri)10(M = Mg, Cd, Pb) species. J Mater Chem 7:2053CrossRef
30.
Mueller A, Krickemeyer E, Boegge H, Schmidtmann M, Peters F, Menke C, Meyer J (1997) An unusual polyoxomolybdate: giant wheels linked to chains. Angew Chem Int Ed 36:484CrossRef
31.
Mueller A, Krickemeyer E, Boegge H, Schmidtmann M, Beugholt M, Das SK, Peters F (1999) Giant ring-shaped building blocks linked to form a layered cluster network with nanosized channels: [Mo124 VIMo28 VO429(μ 3-O)28H14(H2O)66.5]16−. Chem Eur J 5:1496CrossRef
32.
Mueller A, Shah SQN, Boegge H, Schmidtmann M (1999) Molecular growth from a Mo176 to a Mo248 cluster. Nature 397:48CrossRef
33.
Mueller A, Das SK, Fedin VP, Krickemeyer E, Beugholt C, Boegge H, Schmidtmann M, Hauptfleisch B (1999) Rapid and simple isolation of the crystalline molybdenum-blue compounds with discrete and linked nanosized ring-shaped anions: Na15[MoVI 126MoV 28O462H14(H2O)70]0.5 [MoVI 124MoV 28O457H14(H2O)68]0.5 ca. 400 H2O and Na22[MoVI 118MoV 28O442H14(H2O)58] ca. 250 H2O. Z Anorg Allg Chem 625:1187CrossRef
34.
Muller A, Todea AM, Boegge H, van Slageren J, Dressel M, Stammler A, Rusu M (2006) Formation of a “less stable” polyanion directed and protected by electrophilic internal surface functionalities of a capsule in growth: [{Mo6O19}2− ⊂ {MoVI 72FeIII 30O252(ac)20(H2O)92}]4−. Chem Commun 29:3066CrossRef
35.
Goutailler G, Guillard C, Daniele S, Hubert-Pfalzgraf LG (2003) Low temperature and aqueous sol–gel deposit of photocatalytic active nanoparticulate TiO2. J Mater Chem 13:342CrossRef
36.
Werndrup P, Verdenelli M, Chassagneux F, Parola S, Kessler VG (2004) Powders and dense thin films of late transition metal oxide nanocomposites from structurally characterized single-source precursors. J Mater Chem 14:344CrossRef
37.
Kessler G, Seisenbaeva GA, Unell M, Håkansson S (2008) Chemically triggered biodelivery using metal-organic sol-gel synthesis. Angew Chem 47:8506CrossRef
38.
Lundqvist MJ, Nilsing M, Persson P, Lunell S (2006) DFT study of bare and dye-sensitized TiO2 clusters and nanocrystals. Int J Quantum Chem 106:3214CrossRef
39.
Persson P, Gebhardt JCM, Lunell S (2003) The smallest possible nanocrystals of semiionic oxides. J Phys Chem B 107:3336CrossRef
40.
Uddin MJ, Cesano F, Bonino F, Bordiga S, Spoto G, Scarano D, Zecchina A (2007) Photoactive TiO2 films on cellulose fibres: synthesis and characterization. J Photochem Photobiol A 189:286CrossRef
41.
Pati RK, Lee IC, Gaskell KJ, Ehrman SH (2009) Precipitation of nanocrystalline CeO2 using triethanolamine. Langmuir 25:67CrossRef
42.
Epifani M, Andreu T, Magana CR, Arbiol J, Siciliano P, D’Arienzo M, Scotti R, Morazzoni F, Morante JR (2009) The chloroalkoxide route to transition metal oxides. Synthesis of V2O5 thin films and powders from a vanadium chloromethoxide. Chem Mater 21:1618CrossRef
43.
Epifani M, Pellicer E, Arbiol J, Morante JR (2009) Metal oxide nanocrystals from the injection of metal oxide sols in a coordinating environment: principles, applicability, and investigation of the synthesis variables in the case study of CeO2 and SnO2. Chem Mater 21:862CrossRef
44.
Bradley DC, Chakravarti BN, Chatterjee AK (1958) Niobium and tantalum mixed alkoxides. J Chem Soc 1958:99CrossRef
45.
Kessler VG, Nikitin KV, Belokon’ AI (1998) A new argument in favor of the ether elimination mechanism: formation of acetals on action of molybdenum alkoxides on carbonyl compounds. Polyhedron 17:2309CrossRef
46.
Kessler VG, Seisenbaeva GA, Pazik R, Strek W (2008) Heteroleptic metal alkoxide “oxoclusters” as molecular models for the sol–gel synthesis of perovskite nanoparticles for bio-imaging applications. Dalton Trans 26:3412
47.
Pazik R, Seisenbaeva GA, Gohil S, Wiglusz R, Kepinski L, Strek W, Kessler VG (2010) Simple and efficient synthesis of a Nd:LaAlO3 NIR nanophosphor from rare earth alkoxo-monoaluminates Ln2Al2(OiPr)12(iPrOH)2 single source precursors by Bradley reaction. Inorg Chem 49:2684CrossRef
48.
Jensen GV, Bremholm M, Lock N, Deen GR, Jensen TR, Iversen BB, Niederberger M, Pedersen JS, Birkedal H (2010) Anisotropic crystal growth kinetics of anatase TiO2 nanoparticles synthesized in a nonaqueous medium. Chem Mater 22:6044CrossRef
49.
Westin G, Wijk M, Moustiakimov M, Kritikos M (1998) Alkoxide precursors for Er-containing glasses and ceramics. J Sol-Gel Sci Technol 13:125CrossRef
50.
Spijksma GI, Huiskes C, Benes NE, Kruidhof H, Blank DHA, Kessler VG, Bouwmeester HJM (2006) Microporous zirconia-titania composite membranes derived from diethanolamine-modified precursors. Adv Mater 18:2165CrossRef
51.
Yanovskaya MI, Turevskaya EP, Kessler VG, Obvintseva IE, Turova NY (1992) Application of metal alkoxides in the synthesis of oxides. Integr Ferroelectrics 1:343CrossRef
52.
Kirby KW (1988) Alkoxide synthesis techniques for BaTiO3. Mater Res Bull 23:881CrossRef
53.
Solayappan N, Joshi V, DeVilbiss A, Bacon J, Cuchiaro J, McMillan LD, Paz de Araujo CA (1998) Chemical solution deposition (CSD) and characterization of ferroelectric and dielectric thin films. ISIF Monterey. http://​www.​symetrixcorp.​com/​Pub009.​pdf. Accessed 4 Mar 1998
54.
Katayama S, Yoshinaga I, Yamada N, Nagai T (1996) Low-temperature synthesis of Ba(Mg1/3 Ta2/3)O3 ceramics from Ba-Mg-Ta alkoxide precursor. J Am Ceram Soc 79:2059CrossRef
55.
Pązik R, Hreniak D, Stręk W, Kessler VG, Seisenbaeva GA (2008) Photoluminescence investigations of Eu3+ doped BaTiO3 nanopowders fabricated using heterometallic tetranuclear alkoxide complexes. J Alloys Comp 451:557CrossRef
56.
Andrieux M, Gasquères C, Legros C, Gallet I, Herbst-Ghysel M, Condat M, Kessler VG, Seisenbaeva GA, Heintz O, Poissonnet S (2007) Perovskite thin films grown by direct liquid injection MOCVD. Appl Surf Sci 253:9091CrossRef
57.
Brethon A, Hubert-Pfalzgraf LG, Daran JC (2006) Interplay between lead carboxylate and Ti or Zr isopropoxides in solution routes to perovskites: synthesis, molecular structures and reactivity of single source non-oxo Pb–Zr and Pb–Ti carboxylatoalkoxides supported by 2-ethylhexanoate ligands. Dalton Trans 1:250CrossRef
58.
Brethon A, Hubert-Pfalzgraf LG (2006) Influence of the lead carboxylate on the molecular composition of its solutions with zirconium and titanium isopropoxides or n-butoxides: 2-ethylhexanoate vs acetate, a way to stabilize the first Pb-Zr carboxylatoalkoxides of 1:1 stoichiometry. J Sol-Gel Sci Technol 39:159CrossRef
59.
Chaudhary YS, Bhatta UM, Khushalani D (2008) Octyl-β-D-glucopyranoside mediated synthesis of nanocrystalline BaTiO3 using a single-source precursor. J Mater Res 23:842CrossRef
60.
Campion JF, Payne DA, Chae HK, Mauria JK, Wilsoa SR (1991) Synthesis of bimetallic barium titanium alkoxides as precursors for electrical ceramics. Molecular structure of the new barium titanium oxide alkoxide Ba4Ti13(μ3-O)12(μ5-O)6(μ1-η1–OCH2CH2OCH3)12(μ1, μ3-η2–OCH2CH2OCH3)12. Inorg Chem 30:3244CrossRef
61.
Mathur S, Shen H, Lecerf N, Kjekshus A, Fjellvåg H, Goya GF (2002) Nanocrystalline orthoferrite GdFeO3 from a novel heterobimetallic precursor. Adv Mater 14:1405CrossRef
62.
Mathur S, Shen H, Rapalaviciute R, Kareiva A, Donia N (2004) Kinetically controlled synthesis of metastable YAlO3 through molecular level design. J Mater Chem 14:3259CrossRef
63.
Veith M, Haas M, Huch V (2005) Single source precursor approach for the sol − gel synthesis of nanocrystalline ZnFe2O4 and zinc − iron oxide composites. Chem Mater 17:95CrossRef
64.
Kapoor PN, Uma S, Rodriguez S, Klabunde K (2005) Aerogel processing of MTi2O5 (M = Mg, Mn, Fe, Co, Zn, Sn) compositions using single source precursors: synthesis, characterization and photocatalytic behavior. J Mol Catal A 229:145CrossRef
65.
Seisenbaeva GA, Suslova EV, Kritikos M, Rapenne L, Andrieux M, Chassagneux F, Parola S, Kessler VG (2004) Purposeful construction versus self-assembly in approaches to single source precursors of spinel materials. Synthesis, structure and stability studies of MIIAl2(acac)3(OiPr)4(OAc), MII = Mn, Co, Zn – a new class of heterometallic heteroleptic alkoxide complexes. J Mater Chem 14:3150CrossRef
66.
Parola S, Seisenbaeva GA, Kessler VG (2004) Preparation of powders and films of NiAl2O4 spinel from a structurally characterized molecular precursor, NiAl2(acac)4(OiPr)4. J Sol-Gel Sci Technol 31:63CrossRef
67.
Armelao L, Bottaro G, Crociani L, Seraglia R, Tondello E, Zanella P (2008) A versatile single-source precursor for the synthesis of LaCoO3 films. Mater Lett 62:1179CrossRef
68.
Spijksma GI, Bouwmeester HJM, Blank DHA, Kessler VG (2004) Molecular design approach to a stable heterometallic zirconium-titanium alkoxide – potential precursor of mixed-oxide ceramics. Inorg Chem Comm 7:953CrossRef
69.
Spijksma GI, Kloo L, Bouwmeester HJM, Blank DHA, Kessler VG (2007) Nona-coordinated MO6N3 centers M = Zr, Hf as a stable building block for the construction of heterometallic alkoxide precursors. Inorg Chim Acta 360:2045CrossRef
70.
Kreiter R, Rietkerk MDA, Bonekamp BC, van Veen HM, Kessler VG, Vente JF (2008) Sol-gel routes for microporous zirconia and titania membranes. J Sol-Gel Sci Technol 48:203CrossRef
71.
Kessler VG (2003) Molecular structure design and synthetic approaches to the heterometallic alkoxide complexes (soft chemistry approach to inorganic materials by the eyes of a crystallographer). Chem Commun 1213
72.
Kessler VG (2004) Geometrical molecular structure design concept in approach to homo- and heterometallic precursors of advanced materials in sol–gel technology. J Sol-Gel Sci Technol 32:11CrossRef
73.
74.
Tahir AA, Mazhar M, Hamid M, Wijayantha KGU, Molloy KC (2009) Photooxidation of water by NiTiO3 deposited from single source precursor [Ni2Ti2(OEt)2(μ-OEt)6(acac)4] by AACVD. Dalton Trans 19:3674CrossRef
75.
Kessler VG, Gohil S, Parola S (2003) Interaction of some divalent metal acetylacetonates with Al, Ti, Nb and Ta isopropoxides. Factors influencing the formation and stability of heterometallic alkoxide complexes. Dalton 4:544CrossRef
Metadaten
Titel
Single Source Precursor Approach
verfasst von
Vadim G. Kessler
Copyright-Jahr
2013
Verlag
Springer Vienna
Buch
Chemical Solution Deposition of Functional Oxide Thin Films

Print ISBN: 978-3-211-99310-1

Electronic ISBN: 978-3-211-99311-8

Copyright-Jahr: 2013

DOI
https://doi.org/10.1007/978-3-211-99311-8_4

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise