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Erschienen in: Journal of Nanoparticle Research 3/2023

01.03.2023 | Research paper

Size-selective preparation of gold nanoparticles stabilized on chitosan using the matrix-transfer method

verfasst von: Nazgul Assan, Yuta Uetake, Hidehiro Sakurai

Erschienen in: Journal of Nanoparticle Research | Ausgabe 3/2023

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Abstract

This paper describes the size-selective preparation of gold nanoparticles stabilized on chitosan. The exchange of the matrix from the size-selectively prepared Au:PVPs(K-15) to chitosan (chit) proceeded by the mixing of Au:PVPs(K-15) and chitosan in an immiscible two-phasic solvent system to produce Au:chits, where 2-PrOH acts as a mediator. The size dependency of the catalytic activity of the thus-prepared Au:chits is investigated using a homocoupling reaction of phenylboronic acid under aerobic conditions to find that 2.3 nm-sized Au:chit exhibited the best catalytic activity, but the smaller-sized (1.4 nm) catalyst is better for the product selectivity.

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Metadaten
Titel
Size-selective preparation of gold nanoparticles stabilized on chitosan using the matrix-transfer method
verfasst von
Nazgul Assan
Yuta Uetake
Hidehiro Sakurai
Publikationsdatum
01.03.2023
Verlag
Springer Netherlands
Erschienen in
Journal of Nanoparticle Research / Ausgabe 3/2023
Print ISSN: 1388-0764
Elektronische ISSN: 1572-896X
DOI
https://doi.org/10.1007/s11051-023-05700-x

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